Home Cart 0 Sign in  

[ CAS No. 51608-60-7 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 51608-60-7
Chemical Structure| 51608-60-7
Structure of 51608-60-7 * Storage: {[proInfo.prStorage]}
Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Quality Control of [ 51608-60-7 ]

Related Doc. of [ 51608-60-7 ]

Alternatived Products of [ 51608-60-7 ]

Product Details of [ 51608-60-7 ]

CAS No. :51608-60-7 MDL No. :MFCD00964117
Formula : C14H13NO2S Boiling Point : -
Linear Structure Formula :- InChI Key :HVCKVBQOKOFBFH-UHFFFAOYSA-N
M.W : 259.32 Pubchem ID :2755668
Synonyms :

Safety of [ 51608-60-7 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 51608-60-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 51608-60-7 ]
  • Downstream synthetic route of [ 51608-60-7 ]

[ 51608-60-7 ] Synthesis Path-Upstream   1~6

  • 1
  • [ 51608-60-7 ]
  • [ 63160-12-3 ]
YieldReaction ConditionsOperation in experiment
96% With C26H36N4OS; 3-chloro-benzenecarboperoxoic acid In ethanol at -40℃; for 24 h; General procedure: The corresponding imine (0.20 mmol), catalyst 2f (0.024 mmol) were dissolved in xylene (4.0 mL) at room temperature, and the mixture was stirred at room temperature for 5 min. Then, m-CPBA (purity 85percent, 0.24 mmol) was added at −40°C, stirring continued for the time indicated in Table 4, and the crude mixture was purified by flash chromatography on silica gel (petroleum ether/ethyl acetate=7:1) to provide the corresponding oxaziridines 3a–o.
95% With N-benzyl-N,N,N-triethylammonium chloride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In chloroform; water at 0℃; for 2 h; To a mixed solution of saturated aqueous sodium bicarbonate (12 ml) and chloroform (10 ml), benzyltriethylammonium chloride (290 mg, 1.27 mmol) and N-benzylidene-4-toluenesulfonamide (Reference Example 144) (3.00 g, 11.6 mmol) were added, and a solution of m-chloroperbenzoic acid (2.58 g, 12.7 mmol) in chloroform (24 ml) was added dropwise thereto at 0°C with stirring. Thereafter, the resultant was stirred at the same temperature for 2 hours, and the mixture was gradually heated to room temperature. The reaction solution was extracted with chloroform, the organic layer was washed with saturated aqueous sodium bicarbonate, an aqueous solution of 5percent sodium bisulfite, and brine, dried (over potassium carbonate), and then concentrated under a reduced pressure. Hexane was added to the residue, the resulting slurry was filtered and washed, and a title compound (3.03 g,11.0 mmol, 95percent) was obtained as a white powder. 1H-NMR (400 MHz, CDCl3) δ: 2.50 (3H, s), 5.45 (1H, s), 7.40-7.47 (7H, m), 7.93 (2H, d, J = 8.4 Hz). ESI-MS: m/z = 276 (M+H+).
Reference: [1] Tetrahedron, 2016, vol. 72, # 4, p. 512 - 517
[2] Chemical Communications, 2010, vol. 46, # 6, p. 922 - 924
[3] Patent: EP2009006, 2008, A1, . Location in patent: Page/Page column 93-94
[4] Journal of Organic Chemistry, 2011, vol. 76, # 12, p. 4894 - 4904
[5] Chemistry - An Asian Journal, 2013, vol. 8, # 5, p. 883 - 887
[6] Organic Letters, 2016, vol. 18, # 19, p. 4940 - 4943
[7] Journal of the Chemical Society, Chemical Communications, 1977, p. 25 - 26
[8] Patent: JP2017/52729, 2017, A, . Location in patent: Paragraph 0029
  • 2
  • [ 51608-60-7 ]
  • [ 63160-12-3 ]
Reference: [1] Organic Letters, 2005, vol. 7, # 24, p. 5493 - 5496
[2] Chemistry - A European Journal, 2015, vol. 21, # 29, p. 10530 - 10536
  • 3
  • [ 5724-03-8 ]
  • [ 51608-60-7 ]
  • [ 456-03-1 ]
Reference: [1] Advanced Synthesis and Catalysis, 2009, vol. 351, # 16, p. 2657 - 2666
  • 4
  • [ 64340-79-0 ]
  • [ 51608-60-7 ]
  • [ 3277-26-7 ]
Reference: [1] Angewandte Chemie - International Edition, 2000, vol. 39, # 11, p. 1958 - 1960
  • 5
  • [ 67-56-1 ]
  • [ 51608-60-7 ]
  • [ 73183-34-3 ]
  • [ 1370281-63-2 ]
  • [ 1195-66-0 ]
Reference: [1] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[2] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[3] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[4] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[5] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[6] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[7] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
[8] Chemical Communications, 2012, vol. 48, # 31, p. 3769 - 3771
  • 6
  • [ 51608-60-7 ]
  • [ 14769-73-4 ]
Reference: [1] Journal of Molecular Catalysis A: Chemical, 2015, vol. 409, p. 85 - 93
Same Skeleton Products
Historical Records