[ CAS No. 5326-39-6 ]

Name: 5326-39-6|1-Iodo-4-methyl-2-nitrobenzene|97%
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Product Details of [ 5326-39-6 ]

CAS No. :	5326-39-6	MDL No. :	MFCD00024196
Formula :	C₇H₆INO₂	Boiling Point :	299.3°C at 760 mmHg
Linear Structure Formula :	-	InChI Key :	-
M.W :	263.03 g/mol	Pubchem ID :	138455
Synonyms :

Safety of [ 5326-39-6 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P280-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H332-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 5326-39-6 ]

Upstream synthesis route of [ 5326-39-6 ]
Downstream synthetic route of [ 5326-39-6 ]

[ 5326-39-6 ] Synthesis Path-Upstream 1~10

1
[ 5326-39-6 ]
[ 35674-27-2 ]

Reference： [1] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421

2
[ 27329-27-7 ]
[ 5326-39-6 ]

Yield	Reaction Conditions	Operation in experiment
53%	With 2.9-dimethyl-1,10-phenanthroline; oxygen; copper (I) acetate; silver sulfate; sodium iodide In dimethyl sulfoxide at 160℃; for 24 h; Schlenk technique	Silak reaction tube equipped with a magnetic stirrer was charged with 6.2 mg of silver sulfate,21.8 mg of copper acetate, 12.5 mg of 2,9-dimethyl-1,10-o-phenanthroline,36.2 mg of 2-nitro-4-methylbenzoic acid and 45 mg of sodium iodide4 mL of dimethyl sulfoxide. Heat 160 ° C in the presence of oxygenReaction for 24 hours. After the reaction was completed, distilled water was added to quench the reaction,Extraction with ethyl acetate 3 times, each time 10mL,The combined organic phases were concentrated to give 27.9 mg of 2-nitro-4-methyliodobenzene,The yield is 53percent.

Reference： [1] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803
[2] Patent: CN107325002, 2017, A, . Location in patent: Paragraph 0091
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421

3
[ 89-62-3 ]
[ 5326-39-6 ]

Reference： [1] Angewandte Chemie - International Edition, 2011, vol. 50, # 32, p. 7354 - 7358
[2] Justus Liebigs Annalen der Chemie, 1871, vol. 158, p. 344
[3] Chemische Berichte, 1906, vol. 39, p. 269
[4] Canadian Journal of Chemistry, 2005, vol. 83, # 3, p. 213 - 219
[5] Organic Letters, 2009, vol. 11, # 18, p. 4036 - 4039
[6] Organic Letters, 2010, vol. 12, # 8, p. 1696 - 1699
[7] Advanced Synthesis and Catalysis, 2010, vol. 352, # 18, p. 3355 - 3363
[8] Journal of Organic Chemistry, 2012, vol. 77, # 9, p. 4420 - 4424
[9] Tetrahedron, 2017, vol. 73, # 34, p. 5072 - 5081

4
[ 624-31-7 ]
[ 99-99-0 ]
[ 5326-39-6 ]
[ 41252-97-5 ]

Reference： [1] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1988, p. 1281 - 1286

5
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[ 99-99-0 ]
[ 1608-47-5 ]
[ 32704-08-8 ]
[ 32704-10-2 ]
[ 5326-39-6 ]
[ 41252-97-5 ]

Reference： [1] Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 11, p. 2029 - 2035[2] Zhurnal Organicheskoi Khimii, 1988, vol. 24, # 11, p. 2251 - 2258

6
[ 624-31-7 ]
[ 99-99-0 ]
[ 5326-39-6 ]
[ 41252-97-5 ]

Reference： [1] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1988, p. 1281 - 1286

7
[ 624-31-7 ]
[ 99-99-0 ]
[ 1608-47-5 ]
[ 32704-08-8 ]
[ 32704-10-2 ]
[ 5326-39-6 ]
[ 41252-97-5 ]

Reference： [1] Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 11, p. 2029 - 2035[2] Zhurnal Organicheskoi Khimii, 1988, vol. 24, # 11, p. 2251 - 2258

8
[ 5326-39-6 ]
[ 556-63-8 ]
[ 27329-27-7 ]

Reference： [1] Organic Letters, 2003, vol. 5, # 23, p. 4269 - 4272

9
[ 5326-39-6 ]
[ 13194-69-9 ]

Reference： [1] Angewandte Chemie - International Edition, 2011, vol. 50, # 32, p. 7354 - 7358
[2] American Chemical Journal, 1910, vol. 44, p. 131[3] Chem. Zentralbl., 1910, vol. 81, # II, p. 877
[4] Journal of the Chemical Society, 1926, p. 2038
[5] Chemische Berichte, 1906, vol. 39, p. 269
[6] Collection of Czechoslovak Chemical Communications, 1979, vol. 44, # 9, p. 2677 - 2688
[7] Advanced Synthesis and Catalysis, 2010, vol. 352, # 18, p. 3355 - 3363
[8] Journal of Organic Chemistry, 2012, vol. 77, # 9, p. 4420 - 4424

10
[ 5326-39-6 ]
[ 160003-66-7 ]

Reference： [1] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421

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[ CAS No. 5326-39-6 ]

Quality Control of [ 5326-39-6 ]

Related Doc. of [ 5326-39-6 ]

Product Details of [ 5326-39-6 ]

Safety of [ 5326-39-6 ]

Application In Synthesis of [ 5326-39-6 ]

[ 5326-39-6 ] Synthesis Path-Upstream 1~10

[ 5326-39-6 ] Synthesis Path-Downstream 1~26

Related Functional Groups of [ 5326-39-6 ]

Nitroes

Aryls

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Related Functional Groups of
[ 5326-39-6 ]