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CAS No. : | 54010-75-2 | MDL No. : | MFCD00013229 |
Formula : | C2F6O6S2Zn | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | CITILBVTAYEWKR-UHFFFAOYSA-L |
M.W : | 363.55 | Pubchem ID : | 104671 |
Synonyms : |
|
Num. heavy atoms : | 17 |
Num. arom. heavy atoms : | 0 |
Fraction Csp3 : | 1.0 |
Num. rotatable bonds : | 2 |
Num. H-bond acceptors : | 12.0 |
Num. H-bond donors : | 0.0 |
Molar Refractivity : | 31.59 |
TPSA : | 131.16 Ų |
GI absorption : | Low |
BBB permeant : | No |
P-gp substrate : | Yes |
CYP1A2 inhibitor : | No |
CYP2C19 inhibitor : | No |
CYP2C9 inhibitor : | No |
CYP2D6 inhibitor : | No |
CYP3A4 inhibitor : | No |
Log Kp (skin permeation) : | -8.06 cm/s |
Log Po/w (iLOGP) : | -46.97 |
Log Po/w (XLOGP3) : | 0.64 |
Log Po/w (WLOGP) : | 4.78 |
Log Po/w (MLOGP) : | -0.34 |
Log Po/w (SILICOS-IT) : | 2.23 |
Consensus Log Po/w : | -7.93 |
Lipinski : | 0.0 |
Ghose : | None |
Veber : | 0.0 |
Egan : | 0.0 |
Muegge : | 2.0 |
Bioavailability Score : | 0.55 |
Log S (ESOL) : | -2.37 |
Solubility : | 1.57 mg/ml ; 0.00432 mol/l |
Class : | Soluble |
Log S (Ali) : | -2.97 |
Solubility : | 0.39 mg/ml ; 0.00107 mol/l |
Class : | Soluble |
Log S (SILICOS-IT) : | -0.1 |
Solubility : | 290.0 mg/ml ; 0.798 mol/l |
Class : | Soluble |
PAINS : | 0.0 alert |
Brenk : | 3.0 alert |
Leadlikeness : | 1.0 |
Synthetic accessibility : | 2.34 |
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P280-P305+P351+P338-P310 | UN#: | 3261 |
Hazard Statements: | H314 | Packing Group: | Ⅱ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | at 25℃; for 2.33333 h; Reflux | Triflic acid (0.056mol) was added drop wise to a suspension of zinc carbonate (0.02 mol)in dry methanol (20 ml) at room temperature. During the addition, CO2 was evolved. Thereaction mixture was stirred at 25°C for 20 min. and then refluxed for 2 h. The clear solution wascooled to 25°C and concentrated under reduced pressure. The resulting white powder was driedat 125°C for 2 h to afford Zn(OTf)2 (98percent yield). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
98% | Stage #1: at 25℃; for 0.333333 h; Stage #2: for 2 h; Reflux |
Triflic acid (0.056mol) was added drop wise to a suspension of zinc carbonate (0.02 mol) in dry methanol (20 ml) at room temperature. During the addition, CO2 was evolved. The reaction mixture was stirred at 25°C for 20 min. and then refluxed for 2 h. The clear solution was cooled to 25°C and concentrated under reduced pressure. The resulting white powder was dried at 125°C for 2 h to afford Zn(OTf)2 (98percent yield). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In water | ||
In water |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In [D3]acetonitrile at 89.84℃; for 24h; Inert atmosphere; Sealed tube; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
75% | In dichloromethane for 3h; | 3.1 2.3.1. [Zn(Haap)2(OTf)2] (1) A solution of Zn(OTf)2 (0.067 g, 0.18 mmol) in 1 mL CH2Cl2 was added to a stirred solution of Haap (0.050 g, 0.37 mmol) in 2 mL CH2Cl2. The white suspension was stirred for 3 h and the solvent was removed under vacuum. The white powder was collected and washed with Et2O (5 mL Χ 3). Vapor diffusion of Et2O into a methanol solution of the product led to the formation of colorless crystals suitable for X-ray crystallographic characterization (0.093 g, 75% yield). Anal. Calc. for C16H16F6N4O8S2Zn: C, 30.22; H, 2.54; N, 8.81. Found: C, 30.36; H, 2.62; N, 8.65%. FT-IR: 1672 (C=O), 1621, 1538 (C-N), 1480, 1435, 1376, 1343, 1284, 1228 (C-F), 1188, 1160 (S=O), 1069, 1031, 971, 864, 786, 763, 633, 612, 573, 584, 516, 422 cm-1. 1H NMR (methanol-d4, 298 K): δ = 8.52-7.38 (m, 4 H), 2.39 (s, 3H) ppm. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | In methanol; propan-1-ol for 360h; | 2.2 Synthesis of Compound 1⊃G[{Zn2(L)4(OTf)4}.2(DCM).x(G)2]n (1⊃G) DCM solution of the ligand (21.023mg, 1mL) was taken into a glass tube, onto that 1-propanol (1mL) was carefully layered and over the 1-propanol layer, solution of Zn (OTf)2 (36.353mg, 1mL) inMeOH was very carefully layered. Block shaped yellow crystals suitable for X-ray studies were obtained after 15 days in 70% yield. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | With triethylamine In dichloromethane; acetonitrile for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
for 2h; | 2.3.4 [Zn(4-pina)(DMF)4](OTf)2}n (4) A solution of Zn(OTf )2 (0.090 g, 0.25 mmol) in 1 mL of DMF was added to a stirred solution of 4-pina (0.050 g, 0.25 mmol) in 1 mL of DMF. The colorless solution was stirred for 2.0 h and 20 mL of Et2O was added to the mixture. The resulting white oil-like solid was washed with Et2O (5 mL × 3). Dissolving the white powder in DMF and vapor diffusion of Et2O into the colorless solution at room temperature led to colorless needles suitable for X-ray crystallographic characterization (0.128 g, 59.9% yield). Anal. Calcd for C25H37N7O11F6S2Zn: C, 35.12; H, 4.36; N, 11.47. Found: C, 35.38; H, 4.19; N, 11.09. FT-IR (cm -1): 1695, 1643, 1593, 1504, 1419, 1378, 1333, 1245, 1222, 1157, 1113, 1066, 1027, 850, 760, 677, 635, 594, 572, 551, 516, 435. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
75% | In acetonitrile at 70℃; for 24h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
87% | Stage #1: pyridin-4-ylboronic acid hydrate; 2,6-diformyl-4-bromophenol dioxime; zinc trifluoromethanesulfonate In methanol at 50℃; for 0.25h; Stage #2: tetraethylammonium hydroxide In methanol; acetonitrile at 20℃; for 0.166667h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
52% | Stage #1: sodium 4,4''-difluoro-[1,1':3',1''-terphenyl]-2'-carboxylate; zinc trifluoromethanesulfonate In tetrahydrofuran for 1h; Stage #2: dichloromethane; N,N'-bis(3-aminopropyl)-1,2-diamine at 20℃; for 1h; | Synthesis of [Zn(O2CAr4F-Ph)2(TAD)] (1). Zinc trifluoromethanesulfonate(Zn(OTf )2, 0.547 g, 1.51 mmol) wasadded to a solution of NaO2CAr4F-Ph (1.00 g, 3.01 mmol)in 40 mL of tetrahydrofuran for 1 h. The volatile fractionwas removed under reduced pressure, and the residue wasdissolved in 9 mL of dichloromethane. The insoluble solidwas removed via filtration. The filtrate was then treatedwith TAD (0.524 g, 3.01 mmol) and stirred at room temperaturefor 1 h (Scheme 1). The insoluble portion wasremoved via filtration through a celite cake and colorlessblock-shaped crystals were collected from a diffusion systemof the filtrate and diethyl ether. Yield(0.673 g, 52.0%). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
79% | Stage #1: (-)-N-methylephedrine; zinc trifluoromethanesulfonate With triethylamine In toluene at 25℃; for 3h; Inert atmosphere; Stage #2: Benzyl propargyl ether In toluene at 25℃; for 0.583333h; Inert atmosphere; Stage #3: (R)-2,3-cyclohexylideneglyceraldehyde In toluene at 25℃; for 2.5h; Inert atmosphere; | (R)-4-(Benzyloxy)-1-[(R)-1,4-dioxaspiro[4.5]decan-2-yl]but-2-yn-1-ol (7) A 250 mL flask was charged with Zn(OTf)2 (6.73 g, 18.48 mmol) andheated to 120 °C under high vacuum for 14 h. After cooling to r.t., anhydtoluene (50 mL) followed by (-)-N-methylephedrine (3.68 g,20.54 mmol) and Et3N (3.2 mL, 22.59 mmol) were added and the resultantinhomogeneous mixture was stirred for 3 h at r.t. under argon.Alkyne 9 (3 g, 20.54 mmol) dissolved in anhyd toluene (15 mL) wasadded over 5 min and then the reaction mixture was stirred for 30min. Next, the aldehyde 8 (3.49 g, 20.54 mmol) (dissolved in approximately5 mL of anhyd toluene) was added over 3 min. After 2.5 h, TLC(30% EtOAc-hexane) showed the absence of aldehyde. The mixturewas diluted with Et2O and quenched with sat. aq NH4Cl. The aqueousphase was extracted with Et2O (3 ×). The combined organic phaseswere washed with brine and dried (Na2SO4). After evaporation of thevolatiles, column chromatography (hexane-EtOAc, 7:3) afforded thealcohol 7 (5.11 g, 17.38 mmol, 79%) as a colorless liquid; [α]D20 +2.32(c 0.35, CHCl3). The Mosher esters 7a and 7b (see below) were preparedby the known procedure.6IR (neat): 3423, 2935, 2858, 1450, 1364, 1098, 929, 741, 699 cm-1.1H NMR (500 MHz, CDCl3): δ = 7.38-7.27 (m, 5 H), 4.59 (s, 2 H), 4.38-4.33 (m, 1 H), 4.22-4.17 (m, 3 H), 4.10 (dd, J = 8.8, 6.5 Hz, 1 H), 4.10(dd, J = 8.8, 5.1 Hz, 1 H), 2.50 (br s, 1 H), 1.71-1.50 (m, 8 H), 1.49-1.33(m, 2 H).13C NMR (125 MHz, CDCl3): δ = 137.2, 128.4 (2 C), 128.0 (2 C), 127.9,111.1, 83.7, 82.2, 78.3, 71.6, 65.7, 64.4, 57.3, 36.5, 34.6, 25.0, 23.9,23.7.MS (ESI): m/z = 339 [M + Na]+.ESI-HRMS: m/z [M + H]+ calcd for C19H25O4: 317.1747; found:317.1745. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
82% | In acetonitrile at 70℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | With [Cp*Rh(OAc)2]2; oxygen; acetic acid In 1,2-dichloro-ethane at 100℃; for 24h; Schlenk technique; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | In ethyl acetate at 20℃; for 3h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
79% | In ethyl acetate at 20℃; for 3h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In acetone at 20 - 25℃; for 168h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
73% | In ethyl acetate for 0.5h; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In acetone at 20 - 25℃; for 168h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | In ethyl acetate for 0.5h; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
63% | In N,N-dimethyl-formamide at 75℃; for 18h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
63% | In N,N-dimethyl-formamide at 75℃; for 18h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | In N,N-dimethyl-formamide at 75℃; for 18h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
72% | In N,N-dimethyl-formamide at 75℃; for 18h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
55.3% | In water; at 120℃; for 72h;Sealed tube; Autoclave; | A mixture of Zn(SO3CF3)2 (0.012 g, 0.03 mmol), L (0.020 g, 0.06 mmol) and 20 mL distilled water was sealed in a 25 mL stainless reactor with a Teflon liner and heated at 120 C for three days. Rufous crystals of 3 were obtained (0.016 g, 55.3% yield based on L). Anal. calcd for C44H30F6N6O6S2Zn·2H2O: C, 51.90; H, 3.37; N, 8.25. Found: C, 51.78; H, 3.37; N, 8.20. TG-DTA determination: (ZnO%+ZnSO4%) = 11.0; calc by formula C44H30F6N6O6S2Zn: ZnO% = 8.29, ZnSO4% = 16.44. 1H NMR (400 MHz, DMSO-d6): δ 7.47-7.56 (m, 4H), 7.76 (dq, J = 14.2, 7.1 Hz, 6H), 7.98 (d, J = 4.4 Hz, 4H), 8.30 (t, J = 7.7 Hz, 4H), 8.44 (d, J = 7.4 Hz, 4H), 9.17 (d, J = 8.1 Hz, 4H), 9.41 (s, 4H). IR (KBr disc) (cm-1): 3066 (w), 1614 (vs, νpyridyl-H), 1551 (m, νaryl-H), 1476 (s, νpyridyl-H), 1415 (s, νpyridyl-H), 1264 (vs, νtrifluoromethane sulfonate), 1152 (s), 1029 (s), 887 (w), 799 (m), 765 (m), 636 (s). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | In N,N-dimethyl-formamide; at 85℃; for 96h;Sealed tube; | Zn (CF3SO3) 2 (0.2 mmol, 0.2 M mother liquor in 1 mL DMF), HaIM (0.2 mmol, 0.2 M mother liquor in 1 mL DMF) And HcbIM (0.3 mmol, 0.2 M mother liquor in 1.5 mL DMF) was sealed in a 4 mL glass vial and heated at 85 to 96 h. The clear hexagonal tabular crystals were collected and washed with anhydrous DMF (3 x 4 ml). (Yield: 15% based on Zn). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
40% | In chloroform; acetone at 20℃; for 336h; | [Zn(4-pmntd)2(CF3SO3)2]n·x(solvent) (5). A buffer layer of a solution of acetone (2 mL) wascarefully layered over a solution of 4-pmntd (6 mg, 0.0125 mmol) in CHCl3 (10 mL). Then asolution of Zn(CF3SO3)2 (5 mg, 0.0125 mmol) in acetone (2 mL) was layered over the bufferlayer. The solution were left to stand for 2 weeks at room temperature, and yellow blockcrystals appeared in 20% yield. IR (KBr, cm-1): 3089w, 2924w, 1708s, 1668vs, 1621m,1582m, 1510m, 1455m, 1430m, 1374m, 1344s, 1282m, 1248s, 1178m, 1113s, 1068w, 1004m,998m, 880w, 802m, 769m, 638w, 570m. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-(2-chloroethyl)morpholine hydrochride; In acetonitrile; at 20℃; for 16h;Sonication; Molecular sieve; Darkness; | General procedure: An aldehyde (30 mmol), Zn(OTf)2 (13 mg, 35 mmol), and (N-Chloroethyl)morpholine HCl 6.5 mg, 35 mmol) were added to a 1dram vial. The dry solvent, acetonitrile (1mL), was added to the vial. Afterwards dipicolylamine (7 muL 35 mmol) was added to the vial and the vial was sonicated. Once the solution was transparent molecular sieves were added to the solution along with the respective alcohol (175 mmol). The assemblies were incubated for 16 h at room temperature in the dark. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-(2-chloroethyl)morpholine hydrochride; In acetonitrile; at 20℃; for 16h;Sonication; Molecular sieve; Darkness; | General procedure: An aldehyde (30 mmol), Zn(OTf)2 (13 mg, 35 mmol), and (N-Chloroethyl)morpholine HCl 6.5 mg, 35 mmol) were added to a 1dram vial. The dry solvent, acetonitrile (1mL), was added to the vial. Afterwards dipicolylamine (7 muL 35 mmol) was added to the vial and the vial was sonicated. Once the solution was transparent molecular sieves were added to the solution along with the respective alcohol (175 mmol). The assemblies were incubated for 16 h at room temperature in the dark. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-(2-chloroethyl)morpholine hydrochride; In acetonitrile; at 20℃; for 16h;Sonication; Molecular sieve; Darkness; | General procedure: An aldehyde (30 mmol), Zn(OTf)2 (13 mg, 35 mmol), and (N-Chloroethyl)morpholine HCl 6.5 mg, 35 mmol) were added to a 1dram vial. The dry solvent, acetonitrile (1mL), was added to the vial. Afterwards dipicolylamine (7 muL 35 mmol) was added to the vial and the vial was sonicated. Once the solution was transparent molecular sieves were added to the solution along with the respective alcohol (175 mmol). The assemblies were incubated for 16 h at room temperature in the dark. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-(2-chloroethyl)morpholine hydrochride; In acetonitrile; at 20℃; for 16h;Sonication; Molecular sieve; Darkness; | General procedure: An aldehyde (30 mmol), Zn(OTf)2 (13 mg, 35 mmol), and (N-Chloroethyl)morpholine HCl 6.5 mg, 35 mmol) were added to a 1dram vial. The dry solvent, acetonitrile (1mL), was added to the vial. Afterwards dipicolylamine (7 muL 35 mmol) was added to the vial and the vial was sonicated. Once the solution was transparent molecular sieves were added to the solution along with the respective alcohol (175 mmol). The assemblies were incubated for 16 h at room temperature in the dark. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-(2-chloroethyl)morpholine hydrochride; In acetonitrile; at 20℃; for 16h;Sonication; Molecular sieve; Darkness; | General procedure: An aldehyde (30 mmol), Zn(OTf)2 (13 mg, 35 mmol), and (N-Chloroethyl)morpholine HCl 6.5 mg, 35 mmol) were added to a 1dram vial. The dry solvent, acetonitrile (1mL), was added to the vial. Afterwards dipicolylamine (7 muL 35 mmol) was added to the vial and the vial was sonicated. Once the solution was transparent molecular sieves were added to the solution along with the respective alcohol (175 mmol). The assemblies were incubated for 16 h at room temperature in the dark. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 4-(2-chloroethyl)morpholine hydrochride; In acetonitrile; at 20℃; for 16h;Sonication; Molecular sieve; Darkness; | General procedure: An aldehyde (30 mmol), Zn(OTf)2 (13 mg, 35 mmol), and (N-Chloroethyl)morpholine HCl 6.5 mg, 35 mmol) were added to a 1dram vial. The dry solvent, acetonitrile (1mL), was added to the vial. Afterwards dipicolylamine (7 muL 35 mmol) was added to the vial and the vial was sonicated. Once the solution was transparent molecular sieves were added to the solution along with the respective alcohol (175 mmol). The assemblies were incubated for 16 h at room temperature in the dark. |
Tags: 54010-75-2 synthesis path| 54010-75-2 SDS| 54010-75-2 COA| 54010-75-2 purity| 54010-75-2 application| 54010-75-2 NMR| 54010-75-2 COA| 54010-75-2 structure
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P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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