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Chemical Structure| 5672-89-9

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Abendroth, John M. ; Herb, Konstantin ; Janitz, Erika ; Zhu, Tianqi ; Volker, Laura A. ; Degen, Christian L.

Abstract: Nuclear magnetic resonance (NMR) imaging with shallow nitrogen-vacancy (NV) centers in diamond offers an exciting route toward sensitive and localized chemical characterization at the nanoscale. Remarkable progress has been made to combat the degradation in coherence time and stability suffered by near-surface NV centers using suitable chemical surface termination. However, approaches that also enable robust control over adsorbed molecule density, orientation, and binding configuration are needed. We demonstrate a diamond surface preparation for mixed nitrogen-and oxygen-termination that simultaneously improves NV center coherence times for < 10 nm-deep emitters and enables direct and recyclable chemical functionalization via amine-reactive cross-linking. Using this approach, we probe single NV centers embedded in nanopillar waveguides to perform F-19 NMR sensing of covalently bound fluorinated molecules with detection on the order of 100 molecules. This work signifies an important step toward nuclear spin localization and structure interrogation at the single-molecule level.

Keywords: nitrogen-vacancy (NV) center ; quantum sensing ; magnetometry ; nuclear magnetic resonance (NMR) ; ammonia plasma ; surface functionalization

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Product Details of [ 5672-89-9 ]

CAS No. :5672-89-9
Formula : C6H4F3NO4
M.W : 211.10
SMILES Code : O=C(N1OC(C(F)(F)F)=O)CCC1=O
MDL No. :MFCD00595252
InChI Key :NIANZCQUVKPGSF-UHFFFAOYSA-N
Pubchem ID :10867564

Safety of [ 5672-89-9 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302+H312-H315-H318-H411
Precautionary Statements:P273-P280-P301+P312+P330-P302+P352+P312-P305+P351+P338+P310
Class:9
UN#:3077
Packing Group:
 

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