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Chemical Structure| 57842-27-0 Chemical Structure| 57842-27-0

Structure of 57842-27-0

Chemical Structure| 57842-27-0

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Product Details of [ 57842-27-0 ]

CAS No. :57842-27-0
Formula : C7H5BF4S2
M.W : 240.05
SMILES Code : F[B-](F)(F)F.C12=CC=CC=C1[S+]=CS2
MDL No. :MFCD00070613

Safety of [ 57842-27-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H314
Precautionary Statements:P501-P260-P270-P264-P280-P303+P361+P353-P301+P330+P331-P363-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P405
Class:8
UN#:1759
Packing Group:

Application In Synthesis of [ 57842-27-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 57842-27-0 ]

[ 57842-27-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 942190-61-6 ]
  • [ 57842-27-0 ]
  • [ 942190-62-7 ]
YieldReaction ConditionsOperation in experiment
61% With pyridine; In dichloromethane; at 20℃; for 120h; To a solution of compound 3W (2.8 g, 11.4 mmol) in CH2CI2 (100 ml) was added 1 ,3-ben2:odithiol-2-yIium tetrafluoroborate (5.4 g, 22.8 mmol) followed by pyridine (0.2 ml). The reaction mixture was stirred at room temperature for five days. Quenched the reaction mixture with triethylamine (9.6 ml) and stirred for 15 minutes. The reaction mixture was washed with water (100 ml), dried over Na2SO4, filtered and <n="443"/>concentrated. The residue was purified on silica gel eluting with 1/4 EtOAc/hexane then 1/2 EtOAC/hexane to give the desired product 4W (2.75 g, 61%).
 

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