Alternatived Products of [ 60397-77-5 ]
Product Details of [ 60397-77-5 ]
CAS No. : | 60397-77-5 |
MDL No. : | MFCD00021005 |
Formula : |
C9H11NO
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
149.19
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 60397-77-5 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 60397-77-5 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 60397-77-5 ]
- Downstream synthetic route of [ 60397-77-5 ]
- 1
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[ 64-18-6 ]
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[ 95-68-1 ]
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[ 60397-77-5 ]
Yield | Reaction Conditions | Operation in experiment |
95% |
With NaY zeolite functionalized by sulfamic acid/Cu(OAc)2; at 20℃; for 0.0833333h; |
General procedure: To a mixture of amine (1mmol) and NaY/SA/Cu(II) (0.01g), formic acid (5mmol, 0.19mL) was added and stirred for appropriate time at room temperature. After completion of the reaction as monitored by TLC (n-hexane/EtOAc=8/2), NaY/SA/Cu(II) catalyst was filtered and organic layer evaporated under reduced pressure to give pure product. The structure of the products was established from their physical properties and spectral (1H NMR, 13C NMR and IR) analysis and were compared with the data reported in the literature and are available as the Supporting information |
Reference:
[1]ChemMedChem,2014,vol. 9,p. 2557 - 2564
[2]Chinese Chemical Letters,2017,vol. 28,p. 1767 - 1772
[3]Comptes Rendus Chimie,2013,vol. 16,p. 1008 - 1016
[4]New Journal of Chemistry,2015,vol. 39,p. 4398 - 4406
[5]Journal of Molecular Catalysis A: Chemical,2013,vol. 378,p. 148 - 155
[6]Research on Chemical Intermediates,2017,vol. 43,p. 413 - 422
[7]Bulletin of the Korean Chemical Society,2011,vol. 32,p. 1209 - 1214
[8]Chemische Berichte,1885,vol. 18,p. 1004
[9]Organic Letters,2012,vol. 14,p. 4270 - 4273
- 2
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[ 55499-44-0 ]
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[ 77287-34-4 ]
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[ 60397-77-5 ]
Yield | Reaction Conditions | Operation in experiment |
91% |
With caesium carbonate; at 70℃; for 9h; |
General procedure: A mixture of the appropriate arylboronic acid (1.0 mmol),NH2CHO (2.5 mmol), base (1.3 mmol) and rGO/Cu NPs (25 mg) wasstirred at 70C for the appropriate time. After completion of reac-tion (as monitored by TLC), ethyl acetate and water was added andorganic layer was separated. Then, aqueous layer was extracted with ethyl acetate, washed with water, dried over MgSO4, filteredand evaporated under reduced pressure. The residue was purifiedby column chromatography to give the desired pure products. Allproducts are known in the literature and were characterized by IR,NMR and melting points and their spectroscopic data identical tothat reported in the literature [15,16]. |
- 3
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[ 21436-96-4 ]
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[ 60100-09-6 ]
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[ 60397-77-5 ]