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Chemical Structure| 68141-55-9 Chemical Structure| 68141-55-9

Structure of 68141-55-9

Chemical Structure| 68141-55-9

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Product Details of [ 68141-55-9 ]

CAS No. :68141-55-9
Formula : C16H24N2OS
M.W : 292.44
SMILES Code : O=C(NC(N(CCCC)CCCC)=S)C1=CC=CC=C1

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Application In Synthesis of [ 68141-55-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 68141-55-9 ]

[ 68141-55-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 17084-13-8 ]
  • [ 72287-26-4 ]
  • [ 68141-55-9 ]
  • [Pd(dichloro[bis(diphenylphosphino)ferrocene])(N,N-dibutyl-N′-benzoylthioureato-k2O,S)]PF6 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In methanol; at 80℃; for 2h; General procedure: The complexes were prepared as yellow solid products by a similar method to that used for [Pd(PPh3)2Cl2] [9] from direct reactions with the precursor [Pd(dppf)Cl2], with the N,N-disubstituted-N?-acylthioureas, in methanol solutions. The complexes were separated from the reaction mixtures as yellow crystalline solids. Filtration and further washing with hot water and hot hexane were enough to afford pure and stable compounds, in about 80percent yields. Thus, the general procedure for the synthesis of the complexes is described: A solution of [Pd(dppf)Cl2] (1.46g; 2.00mmol) in 5mL of methanol, was added dropwise to a solution of corresponding N,N-dialkyl-N?-(acyl/aroyl)thiourea (2.00mmol), dissolved in 30mL of the same solvent, and 0.368g (2.00mmol) of KPF6. The reaction was heated under magnetic stirring at about 80°C, for 2h. The reaction mixture was left in the refrigerator overnight. The yellow solids obtained were filtered off and washed, successively, with hot water and hot hexane (3×20mL). The obtained compounds are stable in the air and in dimethylsuphoxide solutions, for at least 72h, as showed 31P{1H} NMR experiments.
 

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