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Chemical Structure| 70938-42-0 Chemical Structure| 70938-42-0

Structure of 70938-42-0

Chemical Structure| 70938-42-0

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Product Details of [ 70938-42-0 ]

CAS No. :70938-42-0
Formula : C7H5N3O
M.W : 147.13
SMILES Code : O=CC1=CC=C(NN=N2)C2=C1
MDL No. :MFCD08704415
InChI Key :GJBWJHRJXRTAIC-UHFFFAOYSA-N
Pubchem ID :11600692

Safety of [ 70938-42-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H332-H335
Precautionary Statements:P233-P260-P261-P264-P270-P271-P280-P301+P312-P302+P352-P304-P304+P340-P305+P351+P338-P312-P321-P330-P332+P313-P337+P313-P340-P362-P403-P403+P233-P405-P501

Application In Synthesis of [ 70938-42-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 70938-42-0 ]

[ 70938-42-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 20876-36-2 ]
  • [ 70938-42-0 ]
  • [ 1168720-70-4 ]
YieldReaction ConditionsOperation in experiment
20% With piperidine; In ethanol; at 90℃; for 2h; A scintillation vial was charged with <strong>[20876-36-2]5-aminoindolin-2-one</strong> (37 mg, 0.247 mmol), lH-benzo[d][l,2,3]triazole-5-carbaldehyde (40 mg, 0.272 mmol), piperidine <n="99"/>(2.5 uL, 0.025 mmol) and EtOH (2 mL). The reaction was then heated to 9O0C for 2 hrs. The EtOH was removed in vacuo and the residue loaded onto a silica gel column eluting with 92:8 CH2Cl2MeOH to give 14 mg, 20 percent of a red solid. 1H NMR (400 MHz, d6-DMSO) delta 15.96 (bs, IH), 10.15 (s, IH), 8.21 (bs, IH), 8.02 (bs, IH), 7.73 (bs, IH), 7.67 (s, IH), 6.87 (s, IH), 6.59-6.47 (m, 2H), 4.65 (bs, 2H); MS ESI 278.0 [M + H]+, calcd for [C15HnN5O + H]+ 278.10.
 

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