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Chemical Structure| 7205-61-0 Chemical Structure| 7205-61-0

Structure of 7205-61-0

Chemical Structure| 7205-61-0

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Product Details of [ 7205-61-0 ]

CAS No. :7205-61-0
Formula : C10H14OS
M.W : 182.28
SMILES Code : CC(SC1=CC=C(OC)C=C1)C
MDL No. :MFCD22056033

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Application In Synthesis of [ 7205-61-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 7205-61-0 ]

[ 7205-61-0 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 80041-89-0 ]
  • [ 1950-68-1 ]
  • [ 7205-61-0 ]
  • 2
  • [ 623-73-4 ]
  • [ 7205-61-0 ]
  • [ 28743-98-8 ]
YieldReaction ConditionsOperation in experiment
28% With hemin; In water; at 40℃; for 96h;Green chemistry; General procedure: Sulfide (0.5 mmol) was added into 3 mL of aqueous solution of 25.0 mmol hemin and 0.1 mmol Triton X-100, followed by adding 0.6 mmol diazo ester in one portion. The reaction vial was then placed in a constant temperature shaker and left to shake at 220 rpm under 40 C. After 4 days, the mixture was extracted twice with EtOAc (2 mL x 2). The organic layer was further washed with brine and then dried with Na2SO4. Then the organic solvent was removed in vacuum and hemin was removed by a short silica gel column, and eluted by petroleum ether to give the corresponding product. For gram scale synthesis 1a and 1p were employed with 5 mmol, 6.25 mmol respectively.
 

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