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Type HazMat fee for 500 gram (Estimated)
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Chemical Structure| 760-67-8 Chemical Structure| 760-67-8

Structure of 760-67-8

Chemical Structure| 760-67-8

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Product Details of [ 760-67-8 ]

CAS No. :760-67-8
Formula : C8H15ClO
M.W : 162.66
SMILES Code : CCCCC(CC)C(Cl)=O
MDL No. :MFCD00000718
InChI Key :WFSGQBNCVASPMW-UHFFFAOYSA-N
Pubchem ID :79103

Safety of [ 760-67-8 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H227-H290-H302-H314-H317-H330
Precautionary Statements:P210-P234-P260-P264-P270-P271-P272-P280-P284-P301+P312+P330-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P333+P313-P362+P364-P370+P378-P390-P403+P233-P403+P235-P405-P406-P501
Class:6.1(8)
UN#:2927
Packing Group:

Application In Synthesis of [ 760-67-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 760-67-8 ]

[ 760-67-8 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 4981-66-2 ]
  • [ 760-67-8 ]
  • 9,10-bis(2-ethylhexanoyloxy)anthracene [ No CAS ]
YieldReaction ConditionsOperation in experiment
3.6 g thermometer, In a 200 ml three-necked flask equipped with a stirrer, under a nitrogen atmosphere, 2.10g (10.0 mmol) of 9,10-dihydroxyanthracene was reslurried in 20 g of deaerated water and a solution of 0.92 g (23.0 mmol) of sodium hydroxide dissolved in 3 g of degassed water was added, An aqueous solution of a disodium salt of 10-dihydroxyanthracene as an enriched color was prepared. To this aqueous solution was added 20 mg of tetrabutylammonium bromide and while cooling with ice water, a solution of 3.58 g (22.0 mmol) of 2-ethylhexanoyl chloride in 22 g of toluene was added. After the addition, the mixture was stirred for 2 hours, and the aqueous layer was separated. Then, the toluene layer was washed twice with 10 ml of water, then 40 ml of methanol was added and concentrated. The precipitated crystals were suction filtered and dried to obtain 3.60 g (7.8 mmol) of white crystals of 9,10-bis(2-ethylhexanoyloxy)anthracene. The yield based on the raw material 9,10-dihydroxyanthracene was 78 molpercent.
  • 2
  • [ 2439-54-5 ]
  • [ 760-67-8 ]
  • N-methyl-N-octyl-2-ethylhexanamide [ No CAS ]
YieldReaction ConditionsOperation in experiment
208 g With sodium hydroxide; In water; at 4 - 50℃; for 2h; I.1-Synthesis of N-methyl-N-octyl-2-ethylhexanamide or MOEHA MOEHA, which meets the above formula (I) where R is an n-octyl group, is synthesized from 2-ethylhexanoyl chloride and <strong>[2439-54-5]N-methyl-N-octylamine</strong>, in the presence of sodium hydroxide in water (reaction scheme A). For this purpose, sodium hydroxide (30percent NaOH-112 g-0.839 mole-1.19 eq.), water (100 g) and <strong>[2439-54-5]N-methyl-N-octylamine</strong> (100 g-0.698 mole-1 eq.) are placed in a fully equipped 500 mL reactor. The system is placed under agitation, the set temperature is 4° C. The 2-ethylhexanoyl chloride (136.5 g-0.839 mole-1.19 eq.) is poured at a bulk temperature of between 14° C. and 17° C. (pour time: 90 minutes). The progress of the reaction is controlled and shows the presence of 0.6percent of residual amine. The formation is obtained of 90percent of MOEHA and 8.8percent of an unknown impurity. The medium is heated to 50° C. for 30 minutes to consume the residual amine. The medium is then cooled to 20° C. and decanted. The organic phase is washed twice with 100 mL water to obtain 208 g of reaction product. The MOEHA is subsequently obtained with 98.3percent purity (measured by gas phase chromatography coupled to a flame ionization detector-or GC-FID) after two distillations under pressure (of 2 and 8 mbar respectively). 13C NMR (100 MHz, CDCl3, 25° C.) delta (ppm): 3.37 (t, J=7.0, 2H, 2HalphaA); 3.28 (t, J=7.0, 2H, 2HalphaB); 3.00 (s, 3H, CH3A); 2.92 (s, 3H, CH3B); 2.61 - 2.42 (m, 2H, H2Aet H2B); 1.90-1.77 (m, 2H, CH2A); 1.71-1.35 (m, 10H, 2CH2A and 3CH2B); 1.34 - 1.11 (m, 28H, 7CH2A and 7CH2B); 0.94-0.77 (m, 18H, 3CH3A and CH3B) 1H NMR (400 MHz, CDCl3, 25° C.) delta (ppm): 176.2; 176.0 (COA and COB); 50.1; 48.1 (CalphaA and CalphaB); 43.2; 42.9 (C2A and C2B); 35.6; 33.8 (CH3A and CH3B); 32.8; 32.7; 31.9; 31.9; 30.1; 30.0; 29.5; 29.4; 29.4; 29.3; 29.2; 27.5; 27.5; 27.0; 26.9; 26.2; 23.1; 23.0; 22.8 (20CH2); 14.2; 14.2; 14.1; 14.1 (2CH3A and 2CH3B); 12.3; 12.2 (CH3A and CH3B) MS (EI), m/z (I percent): 269 (5percent) [M]+, 240 (22percent) [M-C2H5]+, 226 (22percent) [M-C3H7]+, 212 (40percent) [M-C4H9]+, 198 (25percent) [M-C5H11]+, 170 (100percent) [M -C7H15]+, 142 (5percent) [C9H20N]+, 127 (5percent) [C8H15O]+ HRMS (EI): m/z calculated for [MH]+(C17H35NO) 269.2714; found 269.2672
 

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