There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
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Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
Structure of 760-67-8
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The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
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Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
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CAS No. : | 760-67-8 |
Formula : | C8H15ClO |
M.W : | 162.66 |
SMILES Code : | CCCCC(CC)C(Cl)=O |
MDL No. : | MFCD00000718 |
InChI Key : | WFSGQBNCVASPMW-UHFFFAOYSA-N |
Pubchem ID : | 79103 |
GHS Pictogram: |
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Signal Word: | Danger |
Hazard Statements: | H227-H290-H302-H314-H317-H330 |
Precautionary Statements: | P210-P234-P260-P264-P270-P271-P272-P280-P284-P301+P312+P330-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P333+P313-P362+P364-P370+P378-P390-P403+P233-P403+P235-P405-P406-P501 |
Class: | 6.1(8) |
UN#: | 2927 |
Packing Group: | Ⅱ |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
3.6 g | thermometer, In a 200 ml three-necked flask equipped with a stirrer, under a nitrogen atmosphere, 2.10g (10.0 mmol) of 9,10-dihydroxyanthracene was reslurried in 20 g of deaerated water and a solution of 0.92 g (23.0 mmol) of sodium hydroxide dissolved in 3 g of degassed water was added, An aqueous solution of a disodium salt of 10-dihydroxyanthracene as an enriched color was prepared. To this aqueous solution was added 20 mg of tetrabutylammonium bromide and while cooling with ice water, a solution of 3.58 g (22.0 mmol) of 2-ethylhexanoyl chloride in 22 g of toluene was added. After the addition, the mixture was stirred for 2 hours, and the aqueous layer was separated. Then, the toluene layer was washed twice with 10 ml of water, then 40 ml of methanol was added and concentrated. The precipitated crystals were suction filtered and dried to obtain 3.60 g (7.8 mmol) of white crystals of 9,10-bis(2-ethylhexanoyloxy)anthracene. The yield based on the raw material 9,10-dihydroxyanthracene was 78 molpercent. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
208 g | With sodium hydroxide; In water; at 4 - 50℃; for 2h; | I.1-Synthesis of N-methyl-N-octyl-2-ethylhexanamide or MOEHA MOEHA, which meets the above formula (I) where R is an n-octyl group, is synthesized from 2-ethylhexanoyl chloride and <strong>[2439-54-5]N-methyl-N-octylamine</strong>, in the presence of sodium hydroxide in water (reaction scheme A). For this purpose, sodium hydroxide (30percent NaOH-112 g-0.839 mole-1.19 eq.), water (100 g) and <strong>[2439-54-5]N-methyl-N-octylamine</strong> (100 g-0.698 mole-1 eq.) are placed in a fully equipped 500 mL reactor. The system is placed under agitation, the set temperature is 4° C. The 2-ethylhexanoyl chloride (136.5 g-0.839 mole-1.19 eq.) is poured at a bulk temperature of between 14° C. and 17° C. (pour time: 90 minutes). The progress of the reaction is controlled and shows the presence of 0.6percent of residual amine. The formation is obtained of 90percent of MOEHA and 8.8percent of an unknown impurity. The medium is heated to 50° C. for 30 minutes to consume the residual amine. The medium is then cooled to 20° C. and decanted. The organic phase is washed twice with 100 mL water to obtain 208 g of reaction product. The MOEHA is subsequently obtained with 98.3percent purity (measured by gas phase chromatography coupled to a flame ionization detector-or GC-FID) after two distillations under pressure (of 2 and 8 mbar respectively). 13C NMR (100 MHz, CDCl3, 25° C.) delta (ppm): 3.37 (t, J=7.0, 2H, 2HalphaA); 3.28 (t, J=7.0, 2H, 2HalphaB); 3.00 (s, 3H, CH3A); 2.92 (s, 3H, CH3B); 2.61 - 2.42 (m, 2H, H2Aet H2B); 1.90-1.77 (m, 2H, CH2A); 1.71-1.35 (m, 10H, 2CH2A and 3CH2B); 1.34 - 1.11 (m, 28H, 7CH2A and 7CH2B); 0.94-0.77 (m, 18H, 3CH3A and CH3B) 1H NMR (400 MHz, CDCl3, 25° C.) delta (ppm): 176.2; 176.0 (COA and COB); 50.1; 48.1 (CalphaA and CalphaB); 43.2; 42.9 (C2A and C2B); 35.6; 33.8 (CH3A and CH3B); 32.8; 32.7; 31.9; 31.9; 30.1; 30.0; 29.5; 29.4; 29.4; 29.3; 29.2; 27.5; 27.5; 27.0; 26.9; 26.2; 23.1; 23.0; 22.8 (20CH2); 14.2; 14.2; 14.1; 14.1 (2CH3A and 2CH3B); 12.3; 12.2 (CH3A and CH3B) MS (EI), m/z (I percent): 269 (5percent) [M]+, 240 (22percent) [M-C2H5]+, 226 (22percent) [M-C3H7]+, 212 (40percent) [M-C4H9]+, 198 (25percent) [M-C5H11]+, 170 (100percent) [M -C7H15]+, 142 (5percent) [C9H20N]+, 127 (5percent) [C8H15O]+ HRMS (EI): m/z calculated for [MH]+(C17H35NO) 269.2714; found 269.2672 |
Tags: 760-67-8 synthesis path| 760-67-8 SDS| 760-67-8 COA| 760-67-8 purity| 760-67-8 application| 760-67-8 NMR| 760-67-8 COA| 760-67-8 structure
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
Prevention | |
Code | Phrase |
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P202 | Do not handle until all safety precautions have been read and understood. |
P210 | Keep away from heat/sparks/open flames/hot surfaces. - No smoking. |
P211 | Do not spray on an open flame or other ignition source. |
P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
P223 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | Keep wetted |
P231 | Handle under inert gas. |
P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
P234 | Keep only in original container. |
P235 | Keep cool |
P240 | Ground/bond container and receiving equipment. |
P241 | Use explosion-proof electrical/ventilating/lighting/equipment. |
P242 | Use only non-sparking tools. |
P243 | Take precautionary measures against static discharge. |
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P251 | Pressurized container: Do not pierce or burn, even after use. |
P260 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | Do not get in eyes, on skin, or on clothing. |
P263 | Avoid contact during pregnancy/while nursing. |
P264 | Wash hands thoroughly after handling. |
P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
P271 | Use only outdoors or in a well-ventilated area. |
P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
P284 | Wear respiratory protection. |
P285 | In case of inadequate ventilation wear respiratory protection. |
P231 + P232 | Handle under inert gas. Protect from moisture. |
P235 + P410 | Keep cool. Protect from sunlight. |
Response | |
Code | Phrase |
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P304 | IF INHALED: |
P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
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P308 | IF exposed or concerned: |
P309 | IF exposed or if you feel unwell: |
P310 | Immediately call a POISON CENTER or doctor/physician. |
P311 | Call a POISON CENTER or doctor/physician. |
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P321 | |
P322 | |
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P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
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P362 | Take off contaminated clothing and wash before reuse. |
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P372 | Explosion risk in case of fire. |
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P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
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P402 | Store in a dry place. |
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P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
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P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
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P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
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H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
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H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
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H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
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H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
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