Home Cart Sign in  
Chemical Structure| 790667-54-8 Chemical Structure| 790667-54-8

Structure of 790667-54-8

Chemical Structure| 790667-54-8

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 790667-54-8 ]

CAS No. :790667-54-8
Formula : C16H22BrNO3
M.W : 356.26
SMILES Code : O=C(N1CCC(OC2=CC=CC(Br)=C2)CC1)OC(C)(C)C
MDL No. :MFCD12026057

Safety of [ 790667-54-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 790667-54-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 790667-54-8 ]

[ 790667-54-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 790667-54-8 ]
  • [ 387350-92-7 ]
  • [ 1251940-27-8 ]
YieldReaction ConditionsOperation in experiment
15% With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In toluene; at 105℃; for 16h;Inert atmosphere; A mixture of compound 27a (7.60 g, 21.3 mmol), compound 1 (3.00 g, 15.2 mmol), Pd2(dba)3 (641 mg, 0.700 mmol), Xantphos (810 mg, 1.40 mmol), and Cs2CO3 (9.90 g, 30.4 mmol) in toluene (130 mL) was stirred at 105 C under Ar atmosphere for 16 h. The mixture was partitioned between with AcOEt and water. The organic layer was washed with brine, dried over MgSO4, and concentrated. The residue was purified by silica gel column chromatography (hexane/AcOEt = 75/25 to 60/40) to give the title compound as a solid (1.06 g, 15%). 1H NMR (300 MHz, CDCl3) δ 1.47 (9H, s), 1.70-1.85 (2H, m), 1.87-2.01 (2H, m), 3.02 (3H, s), 3.19 (2H, t, J = 8.7 Hz), 3.28-3.45 (2H, m), 3.61-3.80 (2H, m), 4.07 (2H, t, J = 8.7 Hz), 4.42-4.57 (1H, m), 6.60-6.69 (1H, m), 6.76-6.82 (1H, m), 6.82-6.92 (1H, m), 7.07 (1H, d, J = 9.0 Hz), 7.20-7.36 (1H, m), 7.56-7.71 (2H, m).
 

Historical Records

Technical Information

Categories