Alternatived Products of [ 84547-89-7 ]
Product Details of [ 84547-89-7 ]
CAS No. : | 84547-89-7 |
MDL No. : | MFCD00464257 |
Formula : |
C5H4BrN3O4
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
250.01
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 84547-89-7 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 84547-89-7 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 84547-89-7 ]
- 1
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[ 84547-84-2 ]
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[ 84547-89-7 ]
Yield | Reaction Conditions | Operation in experiment |
15 g |
With sulfuric acid; nitric acid; at 20 - 50℃; for 32.0h;Cooling with ice; |
Compound 22 (20 g) was dissolved in 100 mL of concentrated sulfuric acid.33 mL of concentrated nitric acid was slowly added dropwise in an ice water bath.After reacting for 16 h at room temperature, TLC showed a large amount of substrate remaining.After heating to 50 ° C for 16 h, the substrate substantially disappeared.After cooling, the reaction solution was slowly added dropwise to 1 L of ice water.Extract with ethyl acetate and wash the organic phase several times with water until pH = 7.After concentration, column chromatography gave yellowSolid 23 (15 g). |
- 2
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[ 84547-84-2 ]
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[ 84547-89-7 ]
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[ 32683-45-7 ]
Reference:
[1]Journal of general chemistry of the USSR,1982,vol. 52,p. 2291 - 2296
Zhurnal Obshchei Khimii,1982,vol. 52,p. 2592 - 2598
[2]Journal of general chemistry of the USSR,1982,vol. 52,p. 2291 - 2296
Zhurnal Obshchei Khimii,1982,vol. 52,p. 2592 - 2598
- 3
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[ 84547-89-7 ]
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[ 89607-12-5 ]
Yield | Reaction Conditions | Operation in experiment |
58% |
With ammonium hydroxide at 190℃; for 5h; high pressure; |
|
55% |
In water at 190℃; for 5h; high pressure; |
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Reference:
[1]Perevalov, V. P.; Andreeva, M. A.; Baryshnenkova, L. I.; Manaev, Yu. A.; Yamburg, G. S.; et al.
[Chemistry of Heterocyclic Compounds, 1983, vol. 19, # 12, p. 1326 - 1330][Khimiya Geterotsiklicheskikh Soedinenii, 1983, vol. 19, # 12, p. 1676 - 1679]
[2]Perevalov, V. P.; Baryshnenkova, L. I.; Andreeva, M. A.; Manaev, Yu. A.; Denisova, I. A.; et al.
[Chemistry of Heterocyclic Compounds, 1983, vol. 19, # 12, p. 1322 - 1326][Khimiya Geterotsiklicheskikh Soedinenii, 1983, vol. 19, # 12, p. 1672 - 1675]