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Chemical Structure| 870963-59-0 Chemical Structure| 870963-59-0

Structure of 870963-59-0

Chemical Structure| 870963-59-0

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Product Details of [ 870963-59-0 ]

CAS No. :870963-59-0
Formula : C9H12N2O2
M.W : 180.20
SMILES Code : O=C(OC)C1=CC=C(CNN)C=C1

Safety of [ 870963-59-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P310+P330-P405
Class:6.1
UN#:2811
Packing Group:

Application In Synthesis of [ 870963-59-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 870963-59-0 ]

[ 870963-59-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 870963-59-0 ]
  • [ 39207-65-3 ]
  • [ 1189582-81-7 ]
YieldReaction ConditionsOperation in experiment
12% toluene-4-sulfonic acid; In toluene; at 90℃; for 3h; Example 239 Methyl 4-[(3-(1-methylethyl)-4,5,6,7-tetrahydro-1H-indazol-1-yl)methyl]benzoate A solution of <strong>[39207-65-3]2-(2-methylpropanoyl)cyclohexanone</strong> (433 mg, 2.58 mmol), methyl 4-(hydrazinyl methyl)benzoate (460 mg, 2.58 mmol), and p-toluenesulfonic acid (100 mg) in toluene (30 mL) was stirred at 90 °C for 3 hours. The solvent was evaporated off under reduced pressure, and t he residue was purified by preparative HPLC to give the titled compound (100 mg, yield 12percent). MS Calcd.: 312; MS Found: 313(M+H). 1 H NMR (400 MHz, CDCl3) delta ppm 1.31 (d, J = 7.2 Hz, 6H), 1.71-1.78 (m, 4H), 2.40 (t, J = 7.2 Hz, 2H), 2.52 (t, J = 7.2 Hz, 2H), 2.97-3.04 (m, 1H), 3.92 (s, 3H), 5.25 (s, 2H), 7.11-7.13 (m, 2H), 7.98-8.00 (m, 2H).
 

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[ 870963-59-0 ]

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A1329189 [870822-94-9]

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