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Chemical Structure| 87393-53-1 Chemical Structure| 87393-53-1

Structure of 87393-53-1

Chemical Structure| 87393-53-1

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Product Citations

Christian, Alec H. ;

Abstract: Metallaphotoredox-catalyzed C-S cross-coupling between heteroaryl bromides RBr (R = quinolin-3-yl, pyrimidin-5-yl, pyridin-2-yl, 2-methyl-imidazo[1,2-a]pyridin-5-yl, etc.) and α-thioacetic acids R1SC(R2R3)CO2H (R1 = 4-methoxyphenyl, pyridin-4-yl, benzo[d]oxazol-2-yl, etc.; R2 = H, Me, Ph; R3 = H, Me) to form biaryl thioethers RSR1 is described. This transformation allows for cross-coupling between building blocks containing reactive functional groups, nitrogen heterocycles, and pharmaceutically relevant scaffolds. Mechanistic experiments indicate a unique means by which this C-S cross-coupling occurs.

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Product Details of [ 87393-53-1 ]

CAS No. :87393-53-1
Formula : C15H11NS
M.W : 237.32
SMILES Code : C1(SC2=CC=CC=C2)=CC3=CC=CC=C3N=C1
MDL No. :MFCD05742387

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