There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type
HazMat fee for 500 gram (Estimated)
Excepted Quantity
USD 0.00
Limited Quantity
USD 15-60
Inaccessible (Haz class 6.1), Domestic
USD 80+
Inaccessible (Haz class 6.1), International
USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic
USD 100+
Accessible (Haz class 3, 4, 5 or 8), International
USD 200+
Structure of 89-95-2 * Storage: {[proInfo.prStorage]}
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Reference:
[1] Chemical and Pharmaceutical Bulletin, 2005, vol. 53, # 4, p. 361 - 365
2
[ 89-95-2 ]
[ 89-92-9 ]
Reference:
[1] Bulletin of the Chemical Society of Ethiopia, 2012, vol. 26, # 2, p. 305 - 309
[2] Phosphorus, Sulfur and Silicon and the Related Elements, 2011, vol. 186, # 7, p. 1470 - 1482
[3] Organic Process Research and Development, 2002, vol. 6, # 2, p. 190 - 191
[4] Tetrahedron Letters, 2010, vol. 51, # 3, p. 540 - 542
[5] Justus Liebigs Annalen der Chemie, 1924, vol. 436, p. 272
[6] Journal of the Chemical Society, 1924, vol. 125, p. 2281[7] Journal of the Chemical Society, 1926, p. 221
[8] Canadian Journal of Chemistry, 1986, vol. 64, p. 1060 - 1071
[9] Tetrahedron Letters, 2011, vol. 52, # 1, p. 13 - 16
[10] Organic and Biomolecular Chemistry, 2013, vol. 11, # 9, p. 1463 - 1467
3
[ 89-95-2 ]
[ 91-13-4 ]
Reference:
[1] Justus Liebigs Annalen der Chemie, 1924, vol. 436, p. 272
4
[ 89-95-2 ]
[ 100-39-0 ]
[ 5896-17-3 ]
Reference:
[1] Journal of Medicinal Chemistry, 2006, vol. 49, # 1, p. 31 - 34
[2] Angewandte Chemie - International Edition, 2004, vol. 43, # 1, p. 115 - 118
[3] Tetrahedron Letters, 2006, vol. 47, # 16, p. 2735 - 2738
[4] Phytochemistry, 1998, vol. 48, # 5, p. 893 - 896
[5] Synlett, 2005, # 4, p. 675 - 684
[6] Tetrahedron, 2001, vol. 57, # 13, p. 2491 - 2498
[7] Bioorganic and Medicinal Chemistry Letters, 2001, vol. 11, # 16, p. 2205 - 2208
[8] Synthesis, 2002, # 18, p. 2701 - 2706
[9] Bioorganic and Medicinal Chemistry Letters, 2004, vol. 14, # 21, p. 5401 - 5405
[10] Russian Journal of General Chemistry, 2005, vol. 75, # 7, p. 1113 - 1124
[11] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 5, p. 1200 - 1205
[12] Bioorganic and Medicinal Chemistry Letters, 2006, vol. 16, # 14, p. 3657 - 3662
5
[ 89-95-2 ]
[ 100-44-7 ]
[ 5896-17-3 ]
Reference:
[1] Chemical and Pharmaceutical Bulletin, 2000, vol. 48, # 7, p. 964 - 973
[2] Bioorganic and Medicinal Chemistry Letters, 2001, vol. 11, # 15, p. 1971 - 1974
[3] Bioorganic and Medicinal Chemistry, 2005, vol. 13, # 5, p. 1537 - 1544
6
[ 89-95-2 ]
[ 22364-68-7 ]
Reference:
[1] Recueil des Travaux Chimiques des Pays-Bas, 1960, vol. 79, p. 1211 - 1222
7
[ 89-95-2 ]
[ 106-95-6 ]
[ 28752-82-1 ]
Reference:
[1] Organic Letters, 2003, vol. 5, # 25, p. 4915 - 4918
[2] Tetrahedron, 2007, vol. 63, # 2, p. 337 - 346
[3] Russian Journal of Organic Chemistry, 2007, vol. 43, # 1, p. 77 - 82
[4] Australian Journal of Chemistry, 2000, vol. 53, # 10, p. 835 - 844
[5] Organic Letters, 2004, vol. 6, # 2, p. 205 - 208
[6] Tetrahedron, 2005, vol. 61, # 32, p. 7746 - 7755
[7] Tetrahedron, 2005, vol. 61, # 42, p. 9996 - 10006
[8] Advanced Synthesis and Catalysis, 2006, vol. 348, # 9, p. 1101 - 1109
[9] Journal of Organic Chemistry, 2007, vol. 72, # 4, p. 1373 - 1378
Reference:
[1] Chemistry - A European Journal, 2002, vol. 8, # 16, p. 3757 - 3768
[2] European Journal of Inorganic Chemistry, 2005, # 4, p. 732 - 744
[3] Organic Preparations and Procedures International, 2005, vol. 37, # 2, p. 173 - 177
[4] Journal of the American Chemical Society, 2004, vol. 126, # 48, p. 15660 - 15661
[5] Journal of the Indian Chemical Society, 1998, vol. 75, # 3, p. 160 - 161
[6] Journal of Organic Chemistry, 2004, vol. 69, # 4, p. 1357 - 1359
isoquinolin-1-yl(2-methylphenyl)methanone[ No CAS ]
Yield
Reaction Conditions
Operation in experiment
95.6%
With ammonium cerium (IV) nitrate; bis(tricyclohexylphosphine)nickel(II) dichloride; 2,2-bis(hydroxymethyl)propionic acid; strontium nitrate; cadmium(II) acetate; In ethylene glycol; at 20 - 60℃; for 10h;Inert atmosphere;
Under room temperature, the nitrogen atmosphere, to the proper amount of organic solvent glycol, by adding 100mmol compounds represented by the following general formula (I) compound, 120mmol aboving (II) compound, 10mmol catalyst NiCl 2 (PCy 3) 2, 150mmol oxidant ammonium ceric nitrate, 150mmol alkali DMPA and 10mmol promoter (for 2.5mmol cadmium acetate and 7.5mmol strontium nitrate of mixture), then heating to 60 °C, and at this temperature the stirring reaction 10 hours; After the reaction, the reaction solution is filtered, adjusted to neutral pH value of the filtrate, saturated salt water is then used to fully wash, then adding ethyl acetate extraction 2-3 time, combined with the phase, drying anhydrous sodium sulfate, concentrated under reduced pressure, the resulting residue over silica gel column chromatography, so as to the acetone and volume ratio of the mixed solution of petroleum ether eluviation, so as to obtain the compound of formula (III), yield of 95.6percent.