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Chemical Structure| 90-63-1 Chemical Structure| 90-63-1

Structure of 1-Hydroxy-1-phenyl-2-propanone
CAS No.: 90-63-1

Chemical Structure| 90-63-1

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Product Details of [ 90-63-1 ]

CAS No. :90-63-1
Formula : C9H10O2
M.W : 150.17
SMILES Code : CC(C(O)C1=CC=CC=C1)=O
MDL No. :MFCD03792883

Safety of [ 90-63-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 90-63-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 90-63-1 ]

[ 90-63-1 ] Synthesis Path-Downstream   1~41

  • 2
  • [ 6738-06-3 ]
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  • [ 101596-63-8 ]
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  • 6
  • [ 90-63-1 ]
  • 1-hydroxy-1-<(4-nitro)-phenyl>-2-propanone [ No CAS ]
  • 7
  • [ 90-63-1 ]
  • [ 102872-97-9 ]
  • 8
  • [ 90-63-1 ]
  • tris-(1-amino-2-hydroxy-1-methyl-2-phenyl-ethyl)-[1,3,5]triazine [ No CAS ]
  • 9
  • [ 917-64-6 ]
  • [ 4410-31-5 ]
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  • 11
  • [ 60-29-7 ]
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  • [ 20907-13-5 ]
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  • 12
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  • phenylmagnesium bromide [ No CAS ]
  • [ 1084-78-2 ]
  • 13
  • [ 623-11-0 ]
  • [ 135762-75-3 ]
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  • [ 64-19-7 ]
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  • 18
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  • 20
  • [ 90-63-1 ]
  • phenylmagnesium bromide [ No CAS ]
  • [ 41728-16-9 ]
  • 21
  • [ 90-63-1 ]
  • phenylmagnesium bromide [ No CAS ]
  • [ 1084-78-2 ]
  • 22
  • [ 90-63-1 ]
  • 2,3,5-Trimethoxy-2,3-dimethyl-4,5-diphenyl-tetrahydro-furan [ No CAS ]
  • 24
  • [ 90-63-1 ]
  • [ 103-71-9 ]
  • 1-phenyl-2-phenylcarbamoyloxy-propan-1-one [ No CAS ]
  • 25
  • [ 64-19-7 ]
  • [ 611-71-2 ]
  • [ 90-63-1 ]
  • 26
  • [ 64-17-5 ]
  • [ 90-63-1 ]
  • [ 64-19-7 ]
  • [ 100-63-0 ]
  • [ 20999-77-3 ]
  • 27
  • [ 90-63-1 ]
  • [ 64-19-7 ]
  • [ 100-63-0 ]
  • (+/-)-1-hydroxy-1-phenyl-acetone-phenylhydrazone [ No CAS ]
  • 28
  • [ 90-63-1 ]
  • [ 1068-57-1 ]
  • 2-hydrazino-1-phenyl-propan-1-ol [ No CAS ]
  • 30
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  • [ 57-14-7 ]
  • [ 116091-96-4 ]
  • 31
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  • [ 100-36-7 ]
  • (1<i>RS</i>:2<i>SR</i>)-2-(2-diethylamino-ethylamino)-1-phenyl-propanol-(1) [ No CAS ]
  • 36
  • [ 579-07-7 ]
  • [ 90-63-1 ]
YieldReaction ConditionsOperation in experiment
78% With Thiamine hydrochloride; triethylamine; In PEG400; at 20℃; for 3h; Method A. To a vigorously stirred mixture of thiamine hydrochloride 2 (337 mg, 1.00 mmol), Et3N (279 muL, 2.00 mmol), and PEG400 (4 mL) alpha-diketone 1f (293 muL, 2.00 mmol) was added in one portion. The mixture was stirred at room temperature for 3 h and then diluted with Et2O (5 mL). The resulting mixture was vigorously stirred for 5 min, allowed to separate out and the ethereal solution was decanted. This process was repeated twice. The collected ethereal fractions were concentrated and the resulting residue was eluted from a column of silica gel with 4:1 cyclohexane/AcOEt to give 5frefPreviewPlaceHolder22 (234 mg, 78percent) as a white amorphous solid. ESI MS (150.1): 173.7 (M+Na+).CommentThe subsequent elution with AcOEt afforded a mixture of PEG-OBz and PEG-OAc. PEG-OBz: 1H NMR: delta=8.20-8.05, 7.60-7.50, and 7.48-7.40 (3m, Ph), 4.50-4.40 and 3.90-3.80 (2m, OCH2CH2OBz), 3.70-3.50 (m, OCH2CH2O-). PEG-OAc: 1H NMR: delta=4.30-4.20 and 3.60-3.50 (2m, OCH2CH2OAc), 3.70-3.50 (m, OCH2CH2O-), 2.08 (s, CH3).
  • 37
  • [ 57-50-1 ]
  • [ 90-63-1 ]
  • 38
  • [ 90-63-1 ]
  • [ 74-88-4 ]
  • [ 7624-24-0 ]
  • 40
  • [ 50-00-0 ]
  • [ 90-63-1 ]
  • [ 10024-89-2 ]
  • [ 804429-52-5 ]
  • 41
  • [ 124-19-6 ]
  • [ 90-63-1 ]
  • [ 88781-25-3 ]
 

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Technical Information

• Appel Reaction • Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Bucherer-Bergs Reaction • Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions • Chugaev Reaction • Clemmensen Reduction • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Corey-Kim Oxidation • Dess-Martin Oxidation • Fischer Indole Synthesis • Grignard Reaction • Henry Nitroaldol Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Jones Oxidation • Lawesson's Reagent • Leuckart-Wallach Reaction • Martin's Sulfurane Dehydrating Reagent • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Mitsunobu Reaction • Moffatt Oxidation • Oxidation of Alcohols by DMSO • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Alcohols • Preparation of Aldehydes and Ketones • Preparation of Amines • Prins Reaction • Reactions of Alcohols • Reactions of Aldehydes and Ketones • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions with Organometallic Reagents • Reformatsky Reaction • Ritter Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Sharpless Olefin Synthesis • Specialized Acylation Reagents-Ketenes • Stobbe Condensation • Swern Oxidation • Tebbe Olefination • Ugi Reaction • Wittig Reaction • Wolff-Kishner Reduction

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