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Chemical Structure| 97802-11-4 Chemical Structure| 97802-11-4

Structure of 97802-11-4

Chemical Structure| 97802-11-4

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Product Details of [ 97802-11-4 ]

CAS No. :97802-11-4
Formula : C15H11BrN2
M.W : 299.17
SMILES Code : NC1=C2N=CC=C(C3=CC=C(Br)C=C3)C2=CC=C1

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Application In Synthesis of [ 97802-11-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 97802-11-4 ]

[ 97802-11-4 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 31736-73-9 ]
  • [ 97802-11-4 ]
  • [ 97802-08-9 ]
YieldReaction ConditionsOperation in experiment
With phosphoric acid; orthoarsenic acid; at 100 - 150℃;Inert atmosphere; General procedure: 4-(4-Fluoro-phenyl)-quinolin-8-ylamine (7.067 g, 29.661 mmol), arsenic acid (8.960 g, 23.333 mmol) and o-phosphoric acid (27 mL) were heated to 100 C under nitrogen. To this a melt of 8.333 g of p-fluoro-3-chloropropriophenone (44.655 mmol) was added drop wise. The solution was then heated to 140-150 C and the solution solidified. The solid was placed onto ice and brought to a pH of 12 followed by extraction with chloroform. The solid was recrystallized from methanol-water to yield 7.343 g of 4,7-bis(4-fluorophenyl)-1,10-phenanthroline as a colorless crystalline solid.
  • 2
  • [ 31736-73-9 ]
  • [ 88-74-4 ]
  • [ 97802-11-4 ]
 

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