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Chemical Structure| 3588-17-8 Chemical Structure| 3588-17-8
Chemical Structure| 3588-17-8

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trans-trans-Muconic acid is a urinary metabolite of benzene and has been used as a biomarker of exposure to benzene in human.

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Product Citations

Product Citations

Tran, Natalie ;

Abstract: Isoreticular chemistry is among the most powerful strategies for designing novel materials with optimizable pore geometry and properties. Of great significance to the further development of isoreticular chemistry is the development of broadly applicable new concepts capable of systematizing the ligand-family expansion as well as establishing correlations between the seemingly uncorrelated. Here, we propose the ligand circuit concept and its use for the synthesis of a family of highly stable, high-performance pore-space-partitioned materials based on an acyclic ligand, trans, trans-muconic acid (zMA). We also expand the degree of flexibility of the acyclic ligand by introducing the dihydro muconic acid (HMA) ligand into the pacs synthesis and study the difference in structure, properties, and stability between the zMA and the HMA-pacs families.

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Product Details of trans-trans-Muconic acid

CAS No. :3588-17-8
Formula : C6H6O4
M.W : 142.11
SMILES Code : O=C(O)/C=C/C=C/C(O)=O
MDL No. :MFCD00002702

Safety of trans-trans-Muconic acid

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Application In Synthesis of trans-trans-Muconic acid

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3588-17-8 ]

[ 3588-17-8 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 2645-22-9 ]
  • zinc(II) acetate hexahydrate [ No CAS ]
  • [ 3588-17-8 ]
  • [Zn(trans, trans-muconate)(4,4'-dipyridylsulfide)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% General procedure: Zn(OAc)2·6H2O (0.055 g, 0.25 mmol) was dissolved in 4 ml of deionized water to which an aqueous solution (2 ml) of H2muco (0.036 g, 0.25 mmol) neutralized with NaOH (0.020 g, 0.5 mmol) was added with constant stirring. To this solution an ethanolic solution (2 ml) of dbds (0.055 g, 0.25 mmol) was added and the contents were stirred for 24 h at room temperature and then the solid obtained was filtered and the filtrate was allowed to evaporate slowly. Orange-yellow block crystals of [Zn(muco)(dbds)2](1) were obtained after four weeks (Yield: 70percent).. After being cooled to room temperature, orange-yellow block crystals of 2 were isolated (Yield: 40percent). Anal. calcd. for C16H12N2O4SZn·7H2O: C, 36.82; H, 2.57; N, 6.36. Found: C,36.40; H,2.71; N,6.31. FT-IR (KBr, 4000-400 cm-1): 2932(w), 1593(s), 1533-1478(s), 1421-1377(s), 1223(s), 814-726 (s).
  • 2
  • [ 2645-22-9 ]
  • zinc(II) acetate hexahydrate [ No CAS ]
  • [ 3588-17-8 ]
  • [Zn(trans, trans-muconate)(4,4'-dipyridyldisulfide)2(H2O)2] [ No CAS ]
YieldReaction ConditionsOperation in experiment
70% 2.2 Synthesis of [Zn(muco)(dbds)2(H2O)2] (1) Zn(OAc)2·6H2O (0.055 g, 0.25 mmol) was dissolved in 4 ml of deionized water to which an aqueous solution (2 ml) of H2muco (0.036 g, 0.25 mmol) neutralized with NaOH (0.020 g, 0.5 mmol) was added with constant stirring. To this solution an ethanolic solution (2 ml) of dbds (0.055 g, 0.25 mmol) was added and the contents were stirred for 24 h at room temperature and then the solid obtained was filtered and the filtrate was allowed to evaporate slowly. Orange-yellow block crystals of [Zn(muco)(dbds)2](1) were obtained after four weeks (Yield: 70percent). Anal. calcd. for C26H24N4O6S4Zn·3H2O: C, 42.38; H, 3.21; N, 9.71. Found: C, 42.61; H,2.70; N,10.40. FT-IR (KBr, 4000-400 cm-1): 3410-3199(w), 2981(w), 1611(s), 1544(s) 1423-1354(s), 1291-1222(s), 865-713(s).
 

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