Name: 1028432-04-3|N-((tert-Butyldimethylsilyl)oxy)-4-methylbenzenesulfonamide|95%
Brand: Ambeed
SKU: A936976
Rating: 94 (32 reviews)

1
[ 1028432-04-3 ]
[ 1028432-26-9 ]
[ 1028432-17-8 ]

Yield	Reaction Conditions	Operation in experiment
85%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]

2
[ 619-73-8 ]
[ 1028432-04-3 ]
[ 1028432-11-2 ]

Yield	Reaction Conditions	Operation in experiment
97%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.833333h; Inert atmosphere;
97%	Stage #1: 4-nitrobenzyl chloride; N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

3
[ 64196-68-5 ]
[ 1028432-04-3 ]
C₁₉H₃₁NO₅SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
93%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]

4
[ 27871-49-4 ]
[ 1028432-04-3 ]
C₁₇H₂₉NO₅SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
95%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]

5
[ 10340-23-5 ]
[ 1028432-04-3 ]
[ 1028432-15-6 ]

Yield	Reaction Conditions	Operation in experiment
99%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]

6
[ 2749-86-2 ]
[ 1028432-04-3 ]
[ 1028432-13-4 ]

Yield	Reaction Conditions	Operation in experiment
100%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;
100%	Stage #1: hex-5-en-2-yn-1-ol; N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

7
[ 122-97-4 ]
[ 1028432-04-3 ]
[ 1028432-05-4 ]

Yield	Reaction Conditions	Operation in experiment
99%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;
99%	Stage #1: 3-Phenyl-1-propanol; N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;
87%	With (phthalocyaninato)iron(II); ethyl 2-(4-cyanophenyl)hydrazinecarboxylate; triphenylphosphine In toluene at 20℃; for 60h; Molecular sieve; Green chemistry;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]
[3]Hirose, Daisuke; Gazvoda, Martin; Košmrlj, Janez; Taniguchi, Tsuyoshi [Chemical Science, 2016, vol. 7, # 8, p. 5148 - 5159]

8
[ 1028432-04-3 ]
[ 2344-70-9 ]
[ 1028432-06-5 ]

Yield	Reaction Conditions	Operation in experiment
91%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;
91%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 1-phenyl-3-butanol With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

9
[ 1028432-04-3 ]
[ 637-59-2 ]
[ 1028432-05-4 ]

Yield	Reaction Conditions	Operation in experiment
	With caesium carbonate In N,N-dimethyl-formamide at 60℃; for 1.33333h; Inert atmosphere;
	With caesium carbonate In N,N-dimethyl-formamide at 60℃;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

10
[ 1028432-04-3 ]
1-mesitylethanol [ No CAS ]
[ 1028432-18-9 ]

Yield	Reaction Conditions	Operation in experiment
99%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 40℃; Inert atmosphere;
99%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 1-mesitylethanol With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 40℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

11
[ 1028432-04-3 ]
[ 3742-75-4 ]
[ 1028432-05-4 ]

Yield	Reaction Conditions	Operation in experiment
	With caesium carbonate In N,N-dimethyl-formamide at 60℃; for 1.5h; Inert atmosphere;
	With caesium carbonate In N,N-dimethyl-formamide at 60℃;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

12
[ 1028432-04-3 ]
[ 69804-99-5 ]
[ 1028432-05-4 ]

Yield	Reaction Conditions	Operation in experiment
	With caesium carbonate In N,N-dimethyl-formamide at 60℃; for 1.5h; Inert atmosphere;
	With caesium carbonate In N,N-dimethyl-formamide at 60℃;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

13
[ 1028432-04-3 ]
[ 132841-84-0 ]
[ 1028432-08-7 ]

Yield	Reaction Conditions	Operation in experiment
97%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;
97%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 7-(phenylseleno)heptan-1-ol With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

14
[ 1028432-04-3 ]
[ 21915-57-1 ]
[ 1028432-07-6 ]

Yield	Reaction Conditions	Operation in experiment
100%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;
100%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 4-(oxiran-2-yl)butyl acetate With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

15
[ 1028432-04-3 ]
[ 105-13-5 ]
[ 1028432-10-1 ]

Yield	Reaction Conditions	Operation in experiment
91%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;
91%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 4-Methoxybenzyl alcohol With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

16
[ 1028432-04-3 ]
[ 4407-36-7 ]
[ 1028432-12-3 ]

Yield	Reaction Conditions	Operation in experiment
99%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.0833333h; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]

17
[ 1028432-04-3 ]
[ 4064-06-6 ]
[ 1028432-09-8 ]

Yield	Reaction Conditions	Operation in experiment
84%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1.25h; Inert atmosphere;
84%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]
[2]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

18
[ 41879-39-4 ]
[ 98-59-9 ]
[ 1028432-04-3 ]

Yield	Reaction Conditions	Operation in experiment
24.6 g	In N,N-dimethyl-formamide at 0 - 20℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Letters, 2008, vol. 10, # 11, p. 2259 - 2261]

19
[ 1028432-04-3 ]
[ 1147336-06-8 ]
[ 1147336-09-1 ]

Yield	Reaction Conditions	Operation in experiment
91%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 25℃; Inert atmosphere;
91%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 25℃; for 2h; Inert atmosphere;	16 [0153] To a solution of 4-thienoylfuroxan-3 -methanol (17) (0.5 g, 2.21 mmol) N-(t- butyldimethylsilyloxy)-4-methylbenzenesulfonamide (0.61 g, 2.01 mmol), and triphenylphosphine (1.05 g, 4.02 mmol) in toluene (7.5 mL) and THF (2.5 mL) was added dropwise DEAD (0.84 ml, 2.11 mmol) at 0 0C. The reaction mixture was allowed to attain room temperature in 2 h. The reaction mixture was diluted with ethyl acetate, successively washed with water, saturated NaHCO3, brine and dried (MgSO4). The crude product was purified on a 50 g Biotage silica gel column. Gradient elution with ethyl acetate (2→40%) in hexanes gave the product 18 as white solid: yield 0.93g (1.83 mmol, 91 %). 1H NMR (CDCl3) δ 0.22 (s, 6H, CH3), 0.88 (s, 9H, CH3), 2.49 (s, 3H, CH3), 4.30 (s, 2H, CH2) 7.27 (dd, J= 5.0 Hz and 3.8 Hz, IH, Het-H), 7.39 (d, J= 8.4 Hz, 2H, Ar-H), 7.76 (d, J= 8.4 Hz, 2H, Ar-H), 7.91 (dd, J= 5.0 Hz and 1.0 Hz, IH, Het-H) and 8.31 (dd, J= 4.0 Hz and 1.2 Hz, IH, Het-H); 13C NMR (CDCl3) δ ^l.9, 17.9, 21.7, 25.8, 47.8, 110.7, 128.2, 129.1, 129.5, 130.5, 137.5, 137.6, 140.4, 145.6, 153.6 and 175.1.

Reference： [1]Rai, Ganesha; Thomas, Craig J.; Leister, William; Maloney, David J. [Tetrahedron Letters, 2009, vol. 50, # 15, p. 1710 - 1713]
[2]Current Patent Assignee: ILLINOIS STATE UNIVERSITY; GOVERNMENT OF THE UNITED STATES - WO2010/19772, 2010, A2 Location in patent: Page/Page column 26

20
[ 1028432-04-3 ]
[ 362-75-4 ]
[ 1142935-23-6 ]

Yield	Reaction Conditions	Operation in experiment
81%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 20℃;

Reference： [1]Location in patent: experimental part Singh, Manish K.; Lakshman, Mahesh K. [Journal of Organic Chemistry, 2009, vol. 74, # 8, p. 3079 - 3084]

21
[ 19748-66-4 ]
[ 1028432-04-3 ]
[ 1259031-90-7 ]

Reference： [1]Journal of Organic Chemistry,2011,vol. 76,p. 188 - 194

22
[ 4441-30-9 ]
[ 1028432-04-3 ]
[ 1259031-91-8 ]

Yield	Reaction Conditions	Operation in experiment
98%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

23
[ 5317-33-9 ]
[ 1028432-04-3 ]
[ 1259031-92-9 ]

Reference： [1]Journal of Organic Chemistry,2011,vol. 76,p. 188 - 194

24
[ 1028432-04-3 ]
[ 1259031-78-1 ]
[ 1259031-83-8 ]

Yield	Reaction Conditions	Operation in experiment
97%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

25
[ 1028432-04-3 ]
[ 1259031-79-2 ]
[ 1259031-85-0 ]

Yield	Reaction Conditions	Operation in experiment
96%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

26
[ 1028432-04-3 ]
[ 1259031-80-5 ]
[ 1259031-86-1 ]

Yield	Reaction Conditions	Operation in experiment
97%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

27
[ 1028432-04-3 ]
[ 1259031-81-6 ]
[ 1259031-87-2 ]

Yield	Reaction Conditions	Operation in experiment
96%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

28
[ 1028432-04-3 ]
[ 1259031-77-0 ]
[ 1259031-82-7 ]

Yield	Reaction Conditions	Operation in experiment
98%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

29
[ 104-58-5 ]
[ 1028432-04-3 ]
[ 1259031-89-4 ]

Yield	Reaction Conditions	Operation in experiment
96%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

30
[ 86368-07-2 ]
[ 1028432-04-3 ]
[ 1259031-88-3 ]

Yield	Reaction Conditions	Operation in experiment
99%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

31
[ 1028432-04-3 ]
[ 17719-78-7 ]
[ 1259031-84-9 ]

Yield	Reaction Conditions	Operation in experiment
96%	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 1h; Inert atmosphere;

Reference： [1]Su, Deyong; Wang, Xinyan; Shao, Changwei; Xu, Jimin; Zhu, Rui; Hu, Yuefei [Journal of Organic Chemistry, 2011, vol. 76, # 1, p. 188 - 194]

32
[ 1028432-04-3 ]
[ 1270026-72-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 0 °C 2: trifluorormethanesulfonic acid / dichloromethane; water; acetonitrile / 1 h / 0 °C

Reference： [1]Yeom, Hyun-Suk; So, Eunsu; Shin, Seunghoon [Chemistry - A European Journal, 2011, vol. 17, # 6, p. 1764 - 1767]

33
[ 1028432-04-3 ]
[ 73696-28-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran; toluene / 0 °C 2: trifluorormethanesulfonic acid / dichloromethane; water; acetonitrile / 1 h / 0 °C 3: [Au(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)(NTf₂)] / toluene / 1 h / 60 °C / Molecular sieve

Reference： [1]Yeom, Hyun-Suk; So, Eunsu; Shin, Seunghoon [Chemistry - A European Journal, 2011, vol. 17, # 6, p. 1764 - 1767]

34
[ 1028432-04-3 ]
[ 927-74-2 ]
C₁₇H₂₇NO₃SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃;

Reference： [1]Yeom, Hyun-Suk; So, Eunsu; Shin, Seunghoon [Chemistry - A European Journal, 2011, vol. 17, # 6, p. 1764 - 1767]

35
[ 4356-69-8 ]
[ 1028432-04-3 ]
1,1-bis(4-methoxyphenyl)-2-tosylethene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
53%	With manganese(IV) oxide; 2-(2-(4,5-dihydrooxazol-2-yl)propan-2-yl)-4,5-dihydrooxazole; copper(II) bis(trifluoromethanesulfonate) In toluene at 120℃; for 24h; Inert atmosphere; Molecular sieve;

Reference： [1]Liwosz, Timothy W.; Chemler, Sherry R. [Chemistry - A European Journal, 2013, vol. 19, # 38, p. 12771 - 12777]

36
[ 1028432-04-3 ]
[ 104-54-1 ]
C₂₂H₃₁NO₃SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
99%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; 3-Phenylpropenol With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

37
[ 547-64-8 ]
[ 1028432-04-3 ]
[ 1028432-16-7 ]

Yield	Reaction Conditions	Operation in experiment
95%	Stage #1: methyl lactate; N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

38
[ 1028432-04-3 ]
C₁₆H₂₄O₃ [ No CAS ]
C₂₉H₄₅NO₅SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
85%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; C₁₆H₂₄O₃ With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

39
[ 1028432-04-3 ]
[ 81028-03-7 ]
[ 1613337-88-4 ]

Yield	Reaction Conditions	Operation in experiment
88%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; (Z)-4-benzyloxy-but-2-en-1-ol With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

40
3-nonene-1-ol [ No CAS ]
[ 1028432-04-3 ]
C₂₂H₃₉NO₂SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
99%	Stage #1: 3-nonene-1-ol; N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

41
[ 1028432-04-3 ]
[ 27977-16-8 ]
C₁₉H₃₁NO₅SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
93%	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; acetic acid 4-hydroxybut-2-enyl ester With triphenylphosphine In tetrahydrofuran; toluene for 0.166667h; Inert atmosphere; Cooling with ice; Stage #2: With diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 10℃; Inert atmosphere;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

42
[ 18162-48-6 ]
[ 98-59-9 ]
[ 1028432-04-3 ]

Yield	Reaction Conditions	Operation in experiment
69%	Stage #1: tert-butyldimethylsilyl chloride With hydroxylamine hydrochloride In N,N-dimethyl-formamide for 0.5h; Cooling with ice; Stage #2: With triethylamine In N,N-dimethyl-formamide at 10℃; Stage #3: p-toluenesulfonyl chloride In N,N-dimethyl-formamide at 10℃;

Reference： [1]Kitahara, Katsushi; Toma, Tatsuya; Shimokawa, Jun; Fukuyama, Tohru [Organic Syntheses, 2012, vol. 89, p. 480 - 490]

43
[ 1028432-04-3 ]
3-[6-chloro-2-(2-thienyl)quinolin-3-yl]-1-propanol [ No CAS ]
N-(tert-butyldimethylsilyloxy)-N-[3-(6-chloro-2-(2-thienyl)quinolin-3-yl)propyl]-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0 - 20℃; for 0.0833333h;	23 N-(tert-butyldimethylsilyloxy)-N-[3-(6-chloro-2-(2-thienyl)quinolin-3-yl)propyl]-4-methylbenzenesulfonamide 46 To a solution of alcohol 45 (400 mg, 1.32 mmol) in anhydrous toluene (4 mL) and THF (1.2 mL), N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide (397 mg, 1.32 mmol) and PPh3 (691 mg, 2.63 mmol) were added. The mixture was cooled to 0 °C and treated dropwise with DEAD (40% solution in toluene, 0.86 mL, 1.98 mmol). The reaction mixture was stirred at room temperature for 5 min, concentrated at reduced pressure and purified through column chromatography (35-70 μm silica gel, hexane/EtOAc mixtures, gradient elution). On elution with hexane/EtOAc 90:10, slightly impure 46 (913 mg) was isolated; Rf 0.60 (hexane/EtOAc 1:1); mp 91-92 °C; IR (ATR) N-(tert-butyldimethylsilyloxy)-N-[3-(6-chloro-2-(2-thienyl)quinolin-3-yl)propyl]-4-methylbenzenesulfonamide 46 ν 1594, 1548, 1522 (Ar-C-C and Ar-C-N st), 1359, 1168 (SO2) cm-1; 1H NMR (400 MHz, CDCl3) δ 0.09 [s, 6H, Si(CH3)2], 0.72 [s, 9H, Si[C(CH3)3]], 1.80 (tt, J = J' = 7.4 Hz, 2H, 2-H2), 2.25 (s, 3H, tosyl CH3), 2.81 (t, J = 7.2 Hz, 2H), 2.90 (t, J = 7.6 Hz, 2H) (1-H2 and 3-H2), 6.97 (dd, J = 4.8 Hz, J' = 4.0 Hz, 1H, 4"-H), 7.09-7.18 (complex signal), 7.20-7.24 (complex signal) [4H, 3"-H, 5"-H, and tosyl-C3(5)-H], 7.42 (dd, J = 9.2 Hz, J' = 2.0 Hz, 1H, 7'-H), 7.51 [br d, J = 8.4 Hz, 2H, tosyl-C2(6)-H], 7.57 (d, J = 2.0 Hz, 1H, 5'-H), 7.74 (s, 1H, 4'-H), 7.85 (d, J = 9.2 Hz, 1H, 8'-H); 13C NMR (100.6 MHz, CDCl3) δ - 4.1 [2CH3, Si(CH3)3], 18.4 [C, SiC(CH3)3], 21.8 (CH3, tosyl CH3), 26.1 [3CH3, SiC(CH3)3], 27.3 (CH2, C2), 30.8 (CH2, C3), 55.4 (CH2, C1), significant aromatic signals: 125.7 (CH, C8'), 129.5 [2CH, tosyl-C3(5)], 130.0 [2CH, tosyl-C2(6)], 132.4 (C), 132.8 (C) (C6', C8a'), 136.0 (CH, C4'), 144.8 (C, C3'), 152.9 (C, C2'); HRMS (ESI), calcd for [C29H3535ClN2O3S2Si + H+] 587.1620, found 587.1596.

Reference： [1]Di Pietro, Ornella; Vicente-Garciá, Esther; Taylor, Martin C.; Berenguer, Diana; Viayna, Elisabet; Lanzoni, Anna; Sola, Irene; Sayago, Helena; Riera, Cristina; Fisa, Roser; Clos, M. Victòria; Pérez, Belén; Kelly, John M.; Lavilla, Rodolfo; Munõz-Torrero, Diego [European Journal of Medicinal Chemistry, 2015, vol. 105, p. 120 - 137]

44
[ 1028432-04-3 ]
[ 94966-45-7 ]
N-(1-(4-bromophenyl)-3,3-diphenylpropa-1,2-dien-1-yl)-N-((tertbutyldimethylsilyl)oxy)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
29%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

45
[ 1028432-04-3 ]
1,1-diphenyl-10-(triisopropylsilyl)deca-2,9-diyn-1-ol [ No CAS ]
N-((tert-butyldimethylsilyl)oxy)-N-(1,1-diphenyl-10-(triisopropylsilyl)-deca-1,2-dien-9-yn-3-yl)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
24%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

46
[ 1028432-04-3 ]
1-phenyl-1-(o-tolyl)hept-2-yn-1-ol [ No CAS ]
N-((tert-butyldimethylsilyl)oxy)-4-methyl-N-(1-phenyl-1-(o-tolyl)-hepta-1,2-dien-3-yl)benzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
17%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

47
[ 1028432-04-3 ]
[ 18215-68-4 ]
N-((tert-butyldimethylsilyl)oxy)-N-(1,1-diphenylhepta-1,2-dien-3-yl)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

48
[ 1028432-04-3 ]
(E)-1,1-diphenyl-2-tosylhept-1-en-3-one oxime [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]
[2]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

49
[ 1028432-04-3 ]
(E)-1,1-diphenyl-2-tosylhept-1-en-3-one O-(4-bromobenzoyl)oxime [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C 3: triethylamine; dmap / dichloromethane / 15 h / 20 °C / Inert atmosphere
	Multi-step reaction with 3 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C 3: triethylamine; dmap / dichloromethane / 15 h / 20 °C / Inert atmosphere

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]
[2]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

50
[ 1028432-04-3 ]
3,3-diphenyl-2-tosylacrylaldehyde oxime [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

51
[ 1028432-04-3 ]
1-cyclohexyl-3,3-diphenyl-2-tosylprop-2-en-1-one oxime [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

52
[ 1028432-04-3 ]
1-phenoxy-4,4-diphenyl-3-tosylbut-3-en-2-one oxime [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

53
[ 1028432-04-3 ]
1,1-bis(4-chlorophenyl)-2-tosylhept-1-en-3-one oxime [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

54
[ 1028432-04-3 ]
[ 1415035-10-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: silver fluoride / acetonitrile / 20 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

55
[ 1522-13-0 ]
[ 1028432-04-3 ]
N-((tert-butyldimethylsilyl)oxy)-4-methyl-N-(1,3,3-triphenylpropa-1,2-dien-1-yl)benzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
46%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

56
[ 1522-13-0 ]
[ 1028432-04-3 ]
1,3,3-triphenyl-2-tosylprop-2-en-1-one oxime [ No CAS ]
3,5,5-triphenyl-4-tosyl-4,5-dihydroisoxazole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -78 - 20 °C / Molecular sieve 2: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 0.17 h / 0 °C

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

57
[ 1028432-04-3 ]
[ 3923-52-2 ]
N-((tert-butyldimethylsilyl)oxy)-N-(3,3-diphenylpropa-1,2-dien-1-yl)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
12%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

58
[ 1028432-04-3 ]
3-cyclohexyl-1,1-diphenylprop-2-yn-1-ol [ No CAS ]
N-((tert-butyldimethylsilyl)oxy)-N-(1-cyclohexyl-3,3-diphenylpropa-1,2-dien-1-yl)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
14%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

59
[ 1028432-04-3 ]
[ 16464-46-3 ]
N-((tert-butyldimethylsilyl)oxy)-4-methyl-N-(1-phenoxy-4,4-diphenylbuta-2,3-dien-2-yl)benzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
6%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

60
[ 1028432-04-3 ]
1,1'-bis(4-chlorophenyl)hept-2-yn-1-ol [ No CAS ]
N-(1,1-bis(4-chlorophenyl)hepta-1,2-dien-3-yl)-N-((tert-butyldimethylsilyl)oxy)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

61
[ 1028432-04-3 ]
1,1'-bis(4-methoxyphenyl)hept-2-yn-1-ol [ No CAS ]
N-(1,1-bis(4-methoxyphenyl)hepta-1,2-dien-3-yl)-N-((tert-butyldimethylsilyl)oxy)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
33%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78 - 20℃; Molecular sieve;

Reference： [1]Tanimoto, Hiroki; Yokoyama, Keiichi; Mizutani, Yusuke; Shitaoka, Takashi; Morimoto, Tsumoru; Nishiyama, Yasuhiro; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2016, vol. 81, # 2, p. 559 - 574]

62
[ 1028432-04-3 ]
[ 344259-19-4 ]
N-(2-(cyclohex-2-en-1-yl)ethyl)-N-((tert-butyldimethylsilyl)oxy)-4-toluenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
73%	With caesium carbonate In N,N-dimethyl-formamide for 17h;

Reference： [1]Hazelden, Ian R.; Ma, Xiaofeng; Langer, Thomas; Bower, John F. [Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11198 - 11202][Angew. Chem., 2016, vol. 128, # 37, p. 11364 - 11368,5]

63
[ 1593-60-8 ]
[ 18162-48-6 ]
[ 1028432-04-3 ]

Reference： [1]Angewandte Chemie - International Edition,2016,vol. 55,p. 11198 - 11202
Angew. Chem.,2016,vol. 128,p. 11364 - 11368,5

64
[ 1028432-04-3 ]
C₁₅H₁₉NO₂S [ No CAS ]
(3aR*,7aS*)-1-tosyl-2,3,3a,4,5,7a-hexahydro-1H-indole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 1: caesium carbonate / N,N-dimethyl-formamide / 17 h 2: pyridine hydrogenfluoride / tetrahydrofuran / 20 °C 3: 1 h 4: tris-(dibenzylideneacetone)dipalladium(0); tris<3,5-bis(trifluoromethyl)phenyl>phosphane; triethylamine / N,N-dimethyl-formamide / 80 °C / Inert atmosphere; Sealed tube
	Multi-step reaction with 4 steps 1: caesium carbonate / N,N-dimethyl-formamide / 17 h 2: pyridine hydrogenfluoride / tetrahydrofuran / 20 °C 3: triethylamine / dichloromethane / 0 - 20 °C 4: tris-(dibenzylideneacetone)dipalladium(0); tris<3,5-bis(trifluoromethyl)phenyl>phosphane; triethylamine / N,N-dimethyl-formamide / 80 °C / Inert atmosphere; Sealed tube

Reference： [1]Hazelden, Ian R.; Ma, Xiaofeng; Langer, Thomas; Bower, John F. [Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11198 - 11202][Angew. Chem., 2016, vol. 128, # 37, p. 11364 - 11368,5]
[2]Hazelden, Ian R.; Ma, Xiaofeng; Langer, Thomas; Bower, John F. [Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11198 - 11202][Angew. Chem., 2016, vol. 128, # 37, p. 11364 - 11368,5]

65
[ 1028432-04-3 ]
N-(2-(cyclohex-2-en-1-yl)ethyl)-N-hydroxy-4-toluenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: caesium carbonate / N,N-dimethyl-formamide / 17 h 2: pyridine hydrogenfluoride / tetrahydrofuran / 20 °C

Reference： [1]Hazelden, Ian R.; Ma, Xiaofeng; Langer, Thomas; Bower, John F. [Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11198 - 11202][Angew. Chem., 2016, vol. 128, # 37, p. 11364 - 11368,5]

66
[ 1028432-04-3 ]
N-2-(cyclohex-2-en-1-yl)ethyl-N-(methanesulfonyloxy)-4-toluenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: caesium carbonate / N,N-dimethyl-formamide / 17 h 2: pyridine hydrogenfluoride / tetrahydrofuran / 20 °C 3: triethylamine / dichloromethane / 0 - 20 °C

Reference： [1]Hazelden, Ian R.; Ma, Xiaofeng; Langer, Thomas; Bower, John F. [Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11198 - 11202][Angew. Chem., 2016, vol. 128, # 37, p. 11364 - 11368,5]

67
[ 1028432-04-3 ]
N-2-(cyclohex-2-en-1-yl)ethyl-N-(trifluoroacetyloxy)-4-toluenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: caesium carbonate / N,N-dimethyl-formamide / 17 h 2: pyridine hydrogenfluoride / tetrahydrofuran / 20 °C 3: 1 h

Reference： [1]Hazelden, Ian R.; Ma, Xiaofeng; Langer, Thomas; Bower, John F. [Angewandte Chemie - International Edition, 2016, vol. 55, # 37, p. 11198 - 11202][Angew. Chem., 2016, vol. 128, # 37, p. 11364 - 11368,5]

68
[ 1028432-04-3 ]
C₃₅H₅₄N₂O₁₀SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1.1: caesium carbonate / acetonitrile / 2 h / 20 °C / Inert atmosphere 2.1: ethylmagnesium bromide / tetrahydrofuran; diethyl ether / 0.33 h / 0 - 20 °C / Inert atmosphere 2.2: 0.5 h / 0 °C / Inert atmosphere

Reference： [1]Maehara, Tomoaki; Motoyama, Keisuke; Toma, Tatsuya; Yokoshima, Satoshi; Fukuyama, Tohru [Angewandte Chemie - International Edition, 2017, vol. 56, # 6, p. 1549 - 1552][Angew. Chem., 2017, p. 1571 - 1574]

69
[ 1028432-04-3 ]
C₃₅H₅₆N₂O₁₀SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1.1: caesium carbonate / acetonitrile / 2 h / 20 °C / Inert atmosphere 2.1: ethylmagnesium bromide / tetrahydrofuran; diethyl ether / 0.33 h / 0 - 20 °C / Inert atmosphere 2.2: 0.5 h / 0 °C / Inert atmosphere 3.1: palladium 10% on activated carbon; quinoline; hydrogen / ethanol; ethyl acetate / 1.5 h / 20 °C

Reference： [1]Maehara, Tomoaki; Motoyama, Keisuke; Toma, Tatsuya; Yokoshima, Satoshi; Fukuyama, Tohru [Angewandte Chemie - International Edition, 2017, vol. 56, # 6, p. 1549 - 1552][Angew. Chem., 2017, p. 1571 - 1574]

70
[ 1028432-04-3 ]
[ 106-96-7 ]
C₁₆H₂₅NO₃SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
96.5%	With caesium carbonate In acetonitrile at 20℃; for 2h; Inert atmosphere;

Reference： [1]Maehara, Tomoaki; Motoyama, Keisuke; Toma, Tatsuya; Yokoshima, Satoshi; Fukuyama, Tohru [Angewandte Chemie - International Edition, 2017, vol. 56, # 6, p. 1549 - 1552][Angew. Chem., 2017, p. 1571 - 1574]

71
[ 1028432-04-3 ]
6-hydroxy-6,6-diphenylhex-4-yn-1-yl acetate [ No CAS ]
4-( (N-((tert-butyldimethylsi l y l )oxy)-4-methylphenyl)sulfonamido)-6,6-diphenylhexa-4,5-dien-1-yl acetate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
74%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 0.5h; Molecular sieve; Inert atmosphere;

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

72
[ 1028432-04-3 ]
7-hydroxy-7,7-diphenylhept-5-yn-1-yl acetate [ No CAS ]
5-( (N-((tert-butyldimethylsilyl)oxy)-4-methylphenyl)sulfonamido)-7,7-diphenylhepta-5,6-dien-1-yl acetate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 0.5h; Molecular sieve; Inert atmosphere;

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

73
[ 1028432-04-3 ]
5-hydroxy-5,5-diphenylpent-3-yn-1-yl acetate [ No CAS ]
3-((N-((tert-butyldimethylsi lyl)oxy)-4-methylphenyl)sulfonamido)-5,5-diphenylpenta-3,4-dien-1-yl acetate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
73%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 0.5h; Molecular sieve; Inert atmosphere;

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

74
[ 1028432-04-3 ]
N-(4-hydroxy-4,4-diphenylbut-2-yn-1-yl)-4-methylbenzenesulfonamide [ No CAS ]
N-((tert-butyldimethylsilyl)oxy)-4-methyl-N-(1-((4-methylphenyl)-sulfonamido)-4,4-diphenylbuta-2,3-dien-2-yl)benzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
43%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -90 - 20℃; Molecular sieve; Inert atmosphere;

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

75
[ 1028432-04-3 ]
diethyl 2-(5-hydroxy-5,5-diphenylpent-3-yn-1-yl)malonate [ No CAS ]
diethyl 2-(3-((N-((tert-butyldimethylsilyl)oxy)-4-methylphenyl)sulfonamido)-5,5-diphenylpenta-3,4-dien-1-yl)malonate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
69%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -90 - 20℃; Molecular sieve; Inert atmosphere;

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

76
[ 1028432-04-3 ]
diethyl 2-(4-hydroxy-4,4-diphenylbut-2-yn-1-yl)malonate [ No CAS ]
diethyl 2-(2-((N-((tert-butyldimethylsilyl)oxy)-4-methylphenyl)sulfonamido)-4,4-diphenylbuta-2,3-dien-1-yl)malonate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -90 - 20℃; Molecular sieve; Inert atmosphere;

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

77
[ 1028432-04-3 ]
N-((tert-butyldimethylsilyl)oxy)-N-(5-hydroxy-1,1-diphenylpenta-1,2-dien-3-yl)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere 2: sodium methylate / methanol / 5 h / 20 °C

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

78
[ 1028432-04-3 ]
S-(3-((N-((tert-butyldimethylsilyl)oxy)-4-methylphenyl)sulfonamido)-5,5-diphenylpenta-3,4-dien-1-yl) ethanethioate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere 2: sodium methylate / methanol / 5 h / 20 °C 3: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 0.17 h / 0 - 20 °C / Inert atmosphere

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

79
[ 1028432-04-3 ]
N-((tert-butyldimethylsilyl)oxy)-N-(5-(1,3-dioxoisoindolin-2-yl)-1,1-diphenylpenta-1,2-dien-3-yl)-4-methylbenzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere 2: sodium methylate / methanol / 5 h / 20 °C 3: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 4 h / 0 °C / Inert atmosphere

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

80
[ 1028432-04-3 ]
N-((tert-butyldimethylsilyl)oxy)-4-methyl-N-(5-((4-methylphenyl)-sulfonamido)-1,1-diphenylpenta-1,2-dien-3-yl)benzenesulfonamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 4 steps 1.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere 2.1: sodium methylate / methanol / 5 h / 20 °C 3.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 4 h / 0 °C / Inert atmosphere 4.1: hydrazine hydrate / chloroform; methanol / 3 h / 0 - 20 °C 4.2: 0 - 20 °C

Reference： [1]Tanimoto, Hiroki; Ueda, Sho; Morimoto, Tsumoru; Kakiuchi, Kiyomi [Journal of Organic Chemistry, 2018, vol. 83, # 3, p. 1614 - 1626]

81
[ 1028432-04-3 ]
3-(inden-2-yl)but-2-en-1-ol [ No CAS ]
C₂₆H₃₅NO₃SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene at 0℃; for 0.166667h; Inert atmosphere;	3-(Inden-2-yl)but-2-enal oxime (13) DEAD (40% in toluene, 0.15 mL, 0.32 mmol) was added slowly to a mixture of 2-alkenylindole 11 (150 mg, 0.81 mmol), O-TBS-N-tosylhydroxylamine (218 mg, 0.72mmol), and PPh3 (424 mg, 1.62 mmol) in toluene (6 mL) and THF (2 mL) at 0 °C. After stirring at the temperature for 10 min, the solvent was evaporated to half an amount. The mixture was dissolved in MeCN (10 mL), and CsF (245 mg, 1.62 mmol) was added. After stirring at rt for 1 h, saturated NH4Cl aq.was added and extracted with EtOAc. The organic layer was washed with brine, dried over Na2SO4, and evaporated in vacuo. The residue was purified by column chromatography using EtOAc-hexane (3:7, v/v)as an eluent to give the oxime 13 (123 mg, 76%) as yellow solid. 1H-NMR (CDCl3) δ: 8.23 (2/3H, d, J = 10.4 Hz), 7.61 (1/3H, d, J = 10.4 Hz), 7.46 (1/3H, d, J = 7.2 Hz), 7.42 (2/3H, d, J = 7.2 Hz), 7.41 (1H/3, d,J = 7.2 Hz), 7.36 (2/3H, d, J = 7.2 Hz), 7.30 (1/3H, t, J = 7.2 Hz), 7.27 (1/3H, t, J = 7.2 Hz), 7.23 (2/3H, d,J = 7.2 Hz), 7.19 (2/3H, d, J = 7.2 Hz), 7.00 (2/3H, s), 6.98 (1/3H, s), 6.72 (1/3H, d, J = 10.4 Hz), 6.43(2/3H, d, J = 10.4 Hz), 3.64 (4/3H, s), 3.63 (2/3H, s), 2.20 (3/3H, s), 2.18 (6/3H, s), one proton (OH) wasnot observed. MS m/z: 199 (M+). HRMS (EI) calcd for C13H13NO 199.0997; found 199.0988.

Reference： [1]Nishiyama, Takashi; Fujiwaki, Takaya; Hatae, Noriyuki; Uchiyama, Emiko; Takeuchi, Nao; Minami, Kazuhide; Yokoyama, Chika; Kinoshita, Tomoya; Ishikura, Minoru; Hibino, Satoshi; Choshi, Tominari [Heterocycles, 2018, vol. 97, # 1, p. 383 - 394]

82
[ 1028432-04-3 ]
C₈H₆ClN₃O₂ [ No CAS ]
C₂₁H₂₈N₄O₅SSi [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Stage #1: N-(tert-butyldimethylsilyloxy)-4-methylbenzenesulfonamide; C₈H₆ClN₃O₂ With potassium carbonate; sodium iodide In acetonitrile at 20℃; Stage #2: With dmap In dichloromethane at 20℃;

Reference： [1]Li, Gongming; Guo, Qingqing; Feng, Chao; Chen, Huan; Zhao, Wenjiao; Li, Shu; Hong, Yang; Sun, Dequn [Parasites and vectors, 2021, vol. 14, # 1]

Type	HazMat fee for 500 gram (Estimated)
Excepted Quantity	USD 0.00
Limited Quantity	USD 15-60
Inaccessible (Haz class 6.1), Domestic	USD 80+
Inaccessible (Haz class 6.1), International	USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic	USD 100+
Accessible (Haz class 3, 4, 5 or 8), International	USD 200+

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CAS No. :	1028432-04-3	MDL No. :	MFCD11976059
Formula :	C₁₃H₂₃NO₃SSi	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	XWGSCRBSSWZLBD-UHFFFAOYSA-N
M.W :	301.48	Pubchem ID :	24899640
Synonyms :

Signal Word:	Danger	Class:	8
Precautionary Statements:	P280-P305+P351+P338-P310	UN#:	3259
Hazard Statements:	H314	Packing Group:	Ⅱ
GHS Pictogram:

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
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P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

[ CAS No. 1028432-04-3 ] {[proInfo.proName]}

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[ 1028432-04-3 ] Synthesis Path-Downstream 1~82

Precautionary Statements-General

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