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[ CAS No. 1593-60-8 ]

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Cat. No.: {[proInfo.prAm]}
2D
Chemical Structure| 1593-60-8
Chemical Structure| 1593-60-8
Structure of 1593-60-8 *Storage: {[proInfo.prStorage]}

Quality Control of [ 1593-60-8 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 1593-60-8 ]

SDS

Product Details of [ 1593-60-8 ]

CAS No. :1593-60-8MDL No. :MFCD11850835
Formula :C7H9NO3SBoiling Point :-
Linear Structure Formula :-InChI Key :N/A
M.W :187.22Pubchem ID :-
Synonyms :

Computed Properties of [ 1593-60-8 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 1593-60-8 ]

Signal Word:WarningClassN/A
Precautionary Statements:P261-P305+P351+P338UN#:N/A
Hazard Statements:H302-H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 1593-60-8 ]

  • Upstream synthesis route of [ 1593-60-8 ]

[ 1593-60-8 ] Synthesis Path-Upstream   1~2

  • 1
  • [ 98-59-9 ]
  • [ 1593-60-8 ]
YieldReaction ConditionsOperation in experiment
87.5% With hydroxylamine hydrochloride; magnesium oxide In tetrahydrofuran; methanol; water at 20℃; Hydroxylamine hydrochloride (7.2 g, 86 mmol) was dissolved in methanol (30 ml) and water (20 ml), magnesium oxide (5.1 g, 129 mmol) was added, stirred for 10 minutes, then p-toluenesulfonyl chloride (8 g, 43 mmol) in tetrahydrofuran (300 ml), stirred vigorously at room temperature, and reacted to TLC to monitor the starting material for complete reaction. The extract was filtered through Celite, dried over anhydrous magnesium sulfate and concentrated under reduced pressure to give N-hydroxy-4-methylbenzenesulfonamide (7 g, white solid) in 87.5percent yield.
Reference: [1] Patent: CN105418632, 2016, A. Location in patent: Paragraph 0175; 0176; 0177
[2] Synlett, 2009, # 13, p. 2149 - 2153
[3] Journal of Inorganic Biochemistry, 2013, vol. 118, p. 134 - 139
[4] Journal fuer Praktische Chemie (Leipzig), 1901, vol. <2>63, p. 176[5] Chem. Zentralbl., 1901, vol. 72, # I, p. 455
[6] European Journal of Medicinal Chemistry, 1996, vol. 31, # 12, p. 1001 - 1010
[7] Organometallics, 2017, vol. 36, # 7, p. 1259 - 1268
  • 2
  • [ 66021-66-7 ]
  • [ 1593-60-8 ]
Reference: [1] Bulletin of the Chemical Society of Japan, 1980, vol. 53, # 3, p. 775 - 784
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