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Chemical Structure| 120-95-6 Chemical Structure| 120-95-6

Structure of 120-95-6

Chemical Structure| 120-95-6

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Product Details of [ 120-95-6 ]

CAS No. :120-95-6
Formula : C16H26O
M.W : 234.38
SMILES Code : OC1=CC=C(C(C)(C)CC)C=C1C(C)(C)CC
MDL No. :MFCD00041929
InChI Key :WMVJWKURWRGJCI-UHFFFAOYSA-N
Pubchem ID :8455

Safety of [ 120-95-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H319
Precautionary Statements:P264-P270-P280-P301+P312+P330-P305+P351+P338-P337+P313-P501

Application In Synthesis of [ 120-95-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 120-95-6 ]

[ 120-95-6 ] Synthesis Path-Downstream   1~7

  • 1
  • [ 120-95-6 ]
  • [ 6223-83-2 ]
  • [ 7071-83-2 ]
YieldReaction ConditionsOperation in experiment
With thionyl chloride; triethylamine; In hexane; toluene; Synthesis Example 1 Synthesis of Exemplary Compound (1-36) To 25 g of <strong>[6223-83-2]9-fluorenone-4-carboxylic acid</strong> is added 150 ml of thionyl chloride, followed by heating and stirring at 80 C. for 6 hours. After cooling to room temperature (25 C.), 150 ml of n-hexane is added thereto and the precipitated crystals are filtered to obtain 23 g (yield of 86%) of <strong>[6223-83-2]9-fluorenone-4-carboxylic acid</strong> chloride. Next, to a solution obtained by mixing 15.5 g of 2,4-di-t-pentylphenol, 150 ml of toluene, and 6.7 g of triethylamine is added 14.5 g of <strong>[6223-83-2]9-fluorenone-4-carboxylic acid</strong> chloride obtained above, followed by stirring at room temperature (25 C.) for 48 hours. The reactant is purified by silica gel chromatography to obtain 22 g of an exemplary compound (1-36) which is a desired product.
  • 2
  • [ 150-76-5 ]
  • ethylphenol [ No CAS ]
  • propylphenol [ No CAS ]
  • butylphenol [ No CAS ]
  • pentylphenol [ No CAS ]
  • [ 123-07-9 ]
  • [ 128-39-2 ]
  • [ 620-17-7 ]
  • [ 2934-05-6 ]
  • [ 2078-54-8 ]
  • [ 26886-05-5 ]
  • [ 2934-07-8 ]
  • [ 4130-42-1 ]
  • [ 96-76-4 ]
  • [ 1197-34-8 ]
  • [ 936-89-0 ]
  • [ 120-95-6 ]
  • [ 876-20-0 ]
  • [ 54932-77-3 ]
YieldReaction ConditionsOperation in experiment
With molybdenum(VI) oxide; In ethanol; at 280℃; for 4h;Inert atmosphere; General procedure: 2.0 g of guaiac acid (purchased in Tianjin Guangfu Technology Co., Ltd.), 0.5 g of MOS catalyst and 100 ml of ethanol were placed in a 300 ml reaction vessel, and the air in the reaction vessel was replaced with nitrogen. The temperature was raised to 280 C, and the reaction was stirred for 4 h. After the reaction was completed, the mixture was filtered under suction and rotary evaporated. The liquid product was subjected to qualitative analysis on a gas chromatography-mass spectrometer (GC6890-MS5973, Agilent), and the internal standard was added. Quantitative analysis by gas chromatography. The chromatogram was performed on an HP-5ms, 30m X 0.25mm X 0.25mum capillary column. The conversion of the raw guaiacol is calculated by (initial guaiacol moles - residual guaiacol moles) / (initial guaiacol moles) X100%, and the selectivity of the product hydrocarbyl phenol is (hydrocarbyl phenol) The number of moles / (molar guaiacol moles) X 100 % was calculated. Among the guaiacol conversion products, ethyl phenols include o-ethyl phenol, 2,5-diethyl phenol, 3,5-diethyl phenol, and propyl phenols include 2,6-diisopropyl phenol. , 2,4-diisopropylphenol, 2,4,6-triisopropylphenol, butyl phenols including 2,5-di-sec-butylphenol, 2,6-di-tert-butylphenol, 2, 4-di-tert-butylphenol, 2,6-di-tert-butyl-p-ethylphenol, pentanols include 2,4-di-tert-amylphenol, others include o-ethoxyphenol, o-ethoxybenzene Methyl ether, p-ethyl guaiacol, 2,6-diisopropylanisole).
  • 3
  • [ 90-05-1 ]
  • ethylphenol [ No CAS ]
  • propylphenol [ No CAS ]
  • butylphenol [ No CAS ]
  • pentylphenol [ No CAS ]
  • [ 90-00-6 ]
  • [ 128-39-2 ]
  • [ 2934-05-6 ]
  • [ 2078-54-8 ]
  • [ 2934-07-8 ]
  • [ 4130-42-1 ]
  • [ 96-76-4 ]
  • [ 1197-34-8 ]
  • [ 120-95-6 ]
  • [ 876-20-0 ]
  • [ 54932-77-3 ]
YieldReaction ConditionsOperation in experiment
With molybdenum(VI) oxide; In ethanol; at 280℃; for 4h;Inert atmosphere;Catalytic behavior; General procedure: 2.0 g of guaiac acid (purchased in Tianjin Guangfu Technology Co., Ltd.), 0.5 g of MOS catalyst and 100 ml of ethanol were placed in a 300 ml reaction vessel, and the air in the reaction vessel was replaced with nitrogen. The temperature was raised to 280 C, and the reaction was stirred for 4 h. After the reaction was completed, the mixture was filtered under suction and rotary evaporated. The liquid product was subjected to qualitative analysis on a gas chromatography-mass spectrometer (GC6890-MS5973, Agilent), and the internal standard was added. Quantitative analysis by gas chromatography. The chromatogram was performed on an HP-5ms, 30m X 0.25mm X 0.25mum capillary column. The conversion of the raw guaiacol is calculated by (initial guaiacol moles - residual guaiacol moles) / (initial guaiacol moles) X100%, and the selectivity of the product hydrocarbyl phenol is (hydrocarbyl phenol) The number of moles / (molar guaiacol moles) X 100 % was calculated. Among the guaiacol conversion products, ethyl phenols include o-ethyl phenol, 2,5-diethyl phenol, 3,5-diethyl phenol, and propyl phenols include 2,6-diisopropyl phenol. , 2,4-diisopropylphenol, 2,4,6-triisopropylphenol, butyl phenols including 2,5-di-sec-butylphenol, 2,6-di-tert-butylphenol, 2, 4-di-tert-butylphenol, 2,6-di-tert-butyl-p-ethylphenol, pentanols include 2,4-di-tert-amylphenol, others include o-ethoxyphenol, o-ethoxybenzene Methyl ether, p-ethyl guaiacol, 2,6-diisopropylanisole).
  • 4
  • [ 64-17-5 ]
  • [ 90-05-1 ]
  • [ 1020-31-1 ]
  • [ 128-39-2 ]
  • [ 2934-05-6 ]
  • [ 2078-54-8 ]
  • [ 2934-07-8 ]
  • [ 4130-42-1 ]
  • [ 2444-28-2 ]
  • [ 87-97-8 ]
  • [ 1138-52-9 ]
  • [ 1879-09-0 ]
  • [ 52417-48-8 ]
  • [ 17540-75-9 ]
  • [ 2050-46-6 ]
  • [ 21112-37-8 ]
  • [ 5076-72-2 ]
  • [ 79-74-3 ]
  • [ 120-95-6 ]
  • [ 876-20-0 ]
  • [ 33963-27-8 ]
  • [ 59056-76-7 ]
  • [ 131358-04-8 ]
  • [ 1620-98-0 ]
  • 5
  • [ 64-17-5 ]
  • [ 90-05-1 ]
  • [ 94-71-3 ]
  • [ 1020-31-1 ]
  • [ 2934-05-6 ]
  • [ 2078-54-8 ]
  • [ 2934-07-8 ]
  • [ 4130-42-1 ]
  • [ 2444-28-2 ]
  • [ 87-97-8 ]
  • [ 1138-52-9 ]
  • [ 1879-09-0 ]
  • [ 52417-48-8 ]
  • [ 17540-75-9 ]
  • [ 2050-46-6 ]
  • [ 21112-37-8 ]
  • [ 5076-72-2 ]
  • [ 79-74-3 ]
  • [ 120-95-6 ]
  • [ 876-20-0 ]
  • [ 33963-27-8 ]
  • [ 59056-76-7 ]
  • [ 131358-04-8 ]
  • [ 1620-98-0 ]
  • 6
  • [ 64-17-5 ]
  • [ 120-80-9 ]
  • [ 1020-31-1 ]
  • [ 128-39-2 ]
  • [ 2934-05-6 ]
  • [ 2078-54-8 ]
  • [ 2934-07-8 ]
  • [ 4130-42-1 ]
  • [ 2444-28-2 ]
  • [ 87-97-8 ]
  • [ 1138-52-9 ]
  • [ 1879-09-0 ]
  • [ 52417-48-8 ]
  • [ 17540-75-9 ]
  • [ 2050-46-6 ]
  • [ 21112-37-8 ]
  • [ 5076-72-2 ]
  • [ 79-74-3 ]
  • [ 120-95-6 ]
  • [ 876-20-0 ]
  • [ 33963-27-8 ]
  • [ 59056-76-7 ]
  • [ 131358-04-8 ]
  • [ 1620-98-0 ]
  • 7
  • [ 94-71-3 ]
  • [ 64-17-5 ]
  • [ 1020-31-1 ]
  • [ 128-39-2 ]
  • [ 2934-05-6 ]
  • [ 2078-54-8 ]
  • [ 2934-07-8 ]
  • [ 4130-42-1 ]
  • [ 2444-28-2 ]
  • [ 87-97-8 ]
  • [ 1138-52-9 ]
  • [ 1879-09-0 ]
  • [ 52417-48-8 ]
  • [ 17540-75-9 ]
  • [ 2050-46-6 ]
  • [ 21112-37-8 ]
  • [ 5076-72-2 ]
  • [ 79-74-3 ]
  • [ 120-95-6 ]
  • [ 876-20-0 ]
  • [ 33963-27-8 ]
  • [ 59056-76-7 ]
  • [ 131358-04-8 ]
  • [ 1620-98-0 ]
 

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