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Chemical Structure| 134812-30-9 Chemical Structure| 134812-30-9

Structure of 134812-30-9

Chemical Structure| 134812-30-9

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Product Details of [ 134812-30-9 ]

CAS No. :134812-30-9
Formula : C11H11N3OS
M.W : 233.29
SMILES Code : CC(NC1=NC(C2=CC=CC(N)=C2)=CS1)=O
MDL No. :MFCD01114798

Safety of [ 134812-30-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H320-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 134812-30-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 134812-30-9 ]

[ 134812-30-9 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 10601-99-7 ]
  • [ 134812-30-9 ]
  • 2-(N-acetylamino)-4-[3-(3-ethynylbenzamido)phenyl]thiazole [ No CAS ]
  • 2
  • [ 134812-30-9 ]
  • [ 148332-36-9 ]
  • C27H20N6O2S [ No CAS ]
YieldReaction ConditionsOperation in experiment
95% With dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; at 20℃; for 3h; Synthesized according to the route shown in Figure 4.TpyCOOH (0.55 g, 2 mmol) was added to the dried flask,Aminothiazole compound Tz-NH2 (0.47 g, 2 mmol),Dicyclohexylcarbodiimide DCC (0.41 g, 2 mmol),30 mL of N,N-dimethylformamide was stirred at room temperature for 3 hours.The solvent was evaporated under reduced pressure, washed with water and dried in vacuo.That is, the ligand tpyL1.The yield was 0.94 g and the yield was 95percent.Precursor complex [Ru(tpy)Cl3] (0.79 g, 1.8 mmol) and ligand tpyL1 (0.94)g, 1.9 mmol) in the flask,50 mL of ethylene glycol methyl ether and 0.5 mL of 4-ethylmorpholine were added and refluxed for 4 hours.Cool to room temperature, filter,To the filtrate was added saturated KPF6 (815 mg, 5 mmol) to precipitate a precipitate.Filtration was carried out to collect a precipitate, which was washed with water and diethyl ether, and then dried in vacuo to give a crude product.The single red component was eluted by silica gel column chromatography in a mixed solvent of acetonitrile and methanol (volume ratio: 4:1) to obtain the target terpyridine pyridinium (II) complex RuTz1.The output is 1.48 g,The yield was 74percent.
 

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