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Chemical Structure| 14387-17-8 Chemical Structure| 14387-17-8

Structure of 14387-17-8

Chemical Structure| 14387-17-8

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Product Details of [ 14387-17-8 ]

CAS No. :14387-17-8
Formula : C17H26O3
M.W : 278.39
SMILES Code : CC(OCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1)=O

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Application In Synthesis of [ 14387-17-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14387-17-8 ]

[ 14387-17-8 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 6374-91-0 ]
  • [ 14387-17-8 ]
  • 5,7-dibromo-1-(3,5-di-tert-butyl-4-hydroxybenzyl)indoline-2,3-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine; In N,N-dimethyl-formamide; at 70℃; General procedure: 0.31 g (1.1 mmol) of 3,5-di-tert-butyl-4-hydroxybenzyl acetate 14 and 0.03 mL of triethyl-amine were added to a continuously stirred solution of the isatin derivative 1-13 (1 mmol) in DMF. The reaction was performed at 70, completion of the reaction of the reactants was determined by TLC. After cooling to ambient, the reaction mixture was poured into a brine. The obtained precipitate was filtered off, washed with water, and dried in vacuum (12 mmHg).
  • 2
  • [ 77395-10-9 ]
  • [ 14387-17-8 ]
  • 5-bromo-7-methyl-1-(3,5-di-tert-butyl-4-hydroxybenzyl)indoline-2,3-dione [ No CAS ]
YieldReaction ConditionsOperation in experiment
78% With triethylamine; In N,N-dimethyl-formamide; at 70℃; for 2.5h; General procedure: 0.31 g (1.1 mmol) of 3,5-di-tert-butyl-4-hydroxybenzyl acetate 14 and 0.03 mL of triethyl-amine were added to a continuously stirred solution of the isatin derivative 1-13 (1 mmol) in DMF. The reaction was performed at 70, completion of the reaction of the reactants was determined by TLC. After cooling to ambient, the reaction mixture was poured into a brine. The obtained precipitate was filtered off, washed with water, and dried in vacuum (12 mmHg).
 

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