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[ CAS No. 2923-28-6 ]

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Chemical Structure| 2923-28-6
Chemical Structure| 2923-28-6
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Product Details of [ 2923-28-6 ]

CAS No. :2923-28-6 MDL No. :MFCD00013226
Formula : CAgF3O3S Boiling Point : 162°C at 760 mmHg
Linear Structure Formula :- InChI Key :N/A
M.W :256.94 g/mol Pubchem ID :76223
Synonyms :

Safety of [ 2923-28-6 ]

Signal Word:Danger Class:8
Precautionary Statements:P264-P280-P302+P352-P305+P351+P338+P310-P332+P313-P362+P364 UN#:1759
Hazard Statements:H315-H318 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 2923-28-6 ]

  • Upstream synthesis route of [ 2923-28-6 ]
  • Downstream synthetic route of [ 2923-28-6 ]

[ 2923-28-6 ] Synthesis Path-Upstream   1~13

  • 1
  • [ 2923-28-6 ]
  • [ 74-88-4 ]
  • [ 333-27-7 ]
Reference: [1] Journal of Organic Chemistry, 1974, vol. 39, # 26, p. 3875 - 3877
[2] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry, [3] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980, p. 2887 - 2891
[4] , Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120,
[5] Journal of Organic Chemistry, 1974, vol. 39, # 26, p. 3875 - 3877
[6] Journal of the Chemical Society, [7] Journal of the Chemical Society, 1956, p. 173 - 180
[8] , Gmelin Handbook: F: PerFHalOrg.2, 1.3.1, page 76 - 99,
[9] Patent: US2018/298037, 2018, A1, . Location in patent: Paragraph 0080-0083
  • 2
  • [ 2923-28-6 ]
  • [ 18162-48-6 ]
  • [ 69739-34-0 ]
Reference: [1] Journal of the American Chemical Society, 1982, vol. 104, # 22, p. 6092 - 6099
  • 3
  • [ 123-91-1 ]
  • [ 7440-55-3 ]
  • [ 17455-13-9 ]
  • [ 2923-28-6 ]
  • [ 1195-66-0 ]
Reference: [1] Journal of the American Chemical Society, 2016, vol. 138, # 40, p. 13119 - 13122
  • 4
  • [ 123-91-1 ]
  • [ 7440-55-3 ]
  • [ 17455-13-9 ]
  • [ 1125-88-8 ]
  • [ 2923-28-6 ]
  • [ 72824-04-5 ]
  • [ 22039-97-0 ]
  • [ 1195-66-0 ]
Reference: [1] Journal of the American Chemical Society, 2016, vol. 138, # 40, p. 13119 - 13122
  • 5
  • [ 1483-72-3 ]
  • [ 2923-28-6 ]
  • [ 66003-76-7 ]
Reference: [1] Tetrahedron, 2000, vol. 56, # 6, p. 855 - 863
  • 6
  • [ 1493-13-6 ]
  • [ 20667-12-3 ]
  • [ 2923-28-6 ]
Reference: [1] Dalton Transactions, 2014, vol. 43, # 4, p. 1589 - 1598
[2] Polyhedron, 1996, vol. 15, # 24, p. 4349 - 4354
[3] Journal of the Chemical Society, [4] Journal of the Chemical Society, 1955, p. 2901 - 2910
[5] Journal of the Chemical Society, [6] Journal of the Chemical Society, 1956, p. 173 - 180
[7] Journal of the Chemical Society, [8] Journal of the Chemical Society, 1957, p. 2640 - 2645
[9] C.A., 1956, p. 13982
[10] Patent: US2732398, 1954, ,
[11] Journal of the Chemical Society, [12] Journal of the Chemical Society, 1954, p. 4228 - 4232
[13] , Gmelin Handbook: F: PerFHalOrg.2, 1.3.1, page 76 - 99,
[14] Chemistry - A European Journal, 2015, vol. 21, # 28, p. 10070 - 10081
  • 7
  • [ 1493-13-6 ]
  • [ 2923-28-6 ]
Reference: [1] Patent: US3962224, 1976, A,
  • 8
  • [ 1493-13-6 ]
  • [ 2923-28-6 ]
Reference: [1] Zeitschrift fuer Physikalische Chemie (Muenchen, Germany), 1983, vol. 138, p. 137 - 156
[2] C.A., 1976, vol. 85, p. 28372
[3] Thermochimica Acta, [4] Thermochimica Acta, 1993, vol. 223, p. 207 - 212
[5] , Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120,
  • 9
  • [ 563-63-3 ]
  • [ 2923-28-6 ]
Reference: [1] Journal of Organometallic Chemistry, 2000, vol. 600, # 1-2, p. 112 - 117
  • 10
  • [ 2923-28-6 ]
  • [ 106-93-4 ]
  • [ 18928-34-2 ]
  • [ 103935-47-3 ]
Reference: [1] Journal of Fluorine Chemistry, 1985, vol. 29, p. 123
  • 11
  • [ 2923-28-6 ]
  • [ 34946-82-2 ]
Reference: [1] Journal of Physical Chemistry B, 2005, vol. 109, # 48, p. 22890 - 22898
  • 12
  • [ 2923-28-6 ]
  • [ 2926-29-6 ]
  • [ 811-68-7 ]
YieldReaction ConditionsOperation in experiment
84% With tri-tert-butyl phosphine In acetonitrile at 0 - 20℃; for 12 h; Inert atmosphere Under a nitrogen atmosphere, AgOTf (25.69 g, 100 mmol) and CF3SO2Na (18.73 g, 120 mmol) was dissolved in anhydrous acetonitrile (400 mL), the reaction solution was cooled to 0°C followed by the addition of tBu3P (50.58 g,250 mmol). The reaction solution was returned to room temperature, and stirred well at room temperature for 12 hours. After the reaction, the reaction solution was filtered through celite, the filtrate was cooled to -20 ° C, and crystals were precipitated. The supernatant was purged to remove most of the tri-tert-butylphosphine oxide. The supernatant was removed in vacuo to remove the solvent. The residue was washed thoroughly with ether, vacuum-dried and the residual solid was recrystallized from tetrahydrofuran and toluene to give the product trifluoromethylthio silver(I) (17.55 g, yield 84percent).
Reference: [1] Patent: CN105017110, 2016, B, . Location in patent: Paragraph 0037; 0038
  • 13
  • [ 2923-28-6 ]
  • [ 58479-61-1 ]
  • [ 92886-86-7 ]
Reference: [1] Tetrahedron, 2004, vol. 60, # 38, p. 8375 - 8396
[2] Organic Letters, 2006, vol. 8, # 24, p. 5649 - 5652
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