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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
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Chemical Structure| 35022-42-5 Chemical Structure| 35022-42-5

Structure of 35022-42-5

Chemical Structure| 35022-42-5

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Product Details of [ 35022-42-5 ]

CAS No. :35022-42-5
Formula : C8H4ClNO
M.W : 165.58
SMILES Code : O=C(C#N)C1=CC=CC=C1Cl
MDL No. :MFCD03092702
InChI Key :YUCRNASRVPZKNQ-UHFFFAOYSA-N
Pubchem ID :3534944

Safety of [ 35022-42-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H300-H311+H331-H315-H319-H400
Precautionary Statements:P501-P261-P273-P270-P271-P264-P280-P391-P337+P313-P305+P351+P338-P361+P364-P332+P313-P301+P310+P330-P302+P352+P312-P304+P340+P311-P403+P233-P405
Class:6.1
UN#:3439
Packing Group:

Application In Synthesis of [ 35022-42-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35022-42-5 ]

[ 35022-42-5 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 7647-01-0 ]
  • [ 35022-42-5 ]
  • [ 62123-75-5 ]
  • 2
  • [ 4435-14-7 ]
  • [ 35022-42-5 ]
  • trans-1-cyclohexyl-2-(2-chlorophenyl)-1,2-dicyanoethylene [ No CAS ]
YieldReaction ConditionsOperation in experiment
18.1g Cyclohexyl acetonitrile (a-1) 18g, 2- chloro-benzoyl cyanide (b-1) It was mixed 24g and dichloromethane 700 mL, and cooled to -10 C..Then, after added dropwise over 70 min titanium tetrachloride 82g at the same temperature, was added dropwise over 2 hours N- methylmorpholine88 g, was stirred at room temperature for 15 hours. The reaction mixture was poured into water, stirred and added with chloroform, and filtered theinsoluble matter. The resulting filtrate the aqueous solution of sodium bicarbonate, washed sequentially with water, and then concentrated. By theresulting concentrate is purified by column to give the trans-1- cyclohexyl-2- (2-chlorophenyl) -1,2-dicyano ethylene (c-1) 18.1g.
 

Historical Records

Technical Information

• Alkyl Halide Occurrence • Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Benzylic Oxidation • Birch Reduction • Blaise Reaction • Blanc Chloromethylation • Bucherer-Bergs Reaction • Catalytic Hydrogenation • Clemmensen Reduction • Complex Metal Hydride Reductions • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Fischer Indole Synthesis • Friedel-Crafts Reaction • General Reactivity • Grignard Reaction • Henry Nitroaldol Reaction • Hiyama Cross-Coupling Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Hydrogenolysis of Benzyl Ether • Kinetics of Alkyl Halides • Kumada Cross-Coupling Reaction • Lawesson's Reagent • Leuckart-Wallach Reaction • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Aldehydes and Ketones • Preparation of Alkylbenzene • Preparation of Amines • Prins Reaction • Reactions of Aldehydes and Ketones • Reactions of Alkyl Halides with Reducing Metals • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reformatsky Reaction • Ritter Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Specialized Acylation Reagents-Ketenes • Stille Coupling • Stobbe Condensation • Substitution and Elimination Reactions of Alkyl Halides • Suzuki Coupling • Tebbe Olefination • Thorpe-Ziegler Reaction • Ugi Reaction • Vilsmeier-Haack Reaction • Wittig Reaction • Wolff-Kishner Reduction

Categories

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[ 35022-42-5 ]

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