36517-91-6|5,6-Dimethoxy-1H-indene-1,3(2H)-dione| Ambeed

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Quality Control of [ 36517-91-6 ] Purity: 97% SDS Specification

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Product Details of [ 36517-91-6 ]

CAS No. :	36517-91-6
Formula :	C₁₁H₁₀O₄
M.W :	206.20
SMILES Code :	O=C1CC(C2=C1C=C(OC)C(OC)=C2)=O
MDL No. :	MFCD25962764
InChI Key :	OFQWGNIJXMWOGZ-UHFFFAOYSA-N
Pubchem ID :	12384295

Safety of [ 36517-91-6 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 36517-91-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 36517-91-6 ]

[ 36517-91-6 ] Synthesis Path-Downstream 1~35

1
[ 148517-82-2 ]
[ 36517-91-6 ]

References: [1]Bulletin de la Societe Chimique de France,1993,vol. 130,p. 121 - 124.

2
[ 155586-47-3 ]
[ 36517-91-6 ]

References: [1]Chemistry Letters,1994,p. 389 - 392.

3
[ 2973-77-5 ]
[ 36517-91-6 ]
2-(3,5-Dibromo-4-hydroxy-benzylidene)-5,6-dimethoxy-indan-1,3-dione [ No CAS ]

References: [1]Bioorganic and Medicinal Chemistry Letters,1998,vol. 8,p. 2489 - 2494.

4
[ 36517-91-6 ]
[ 2314-36-5 ]
2-(3,5-Dichloro-4-hydroxy-benzylidene)-5,6-dimethoxy-indan-1,3-dione [ No CAS ]

References: [1]Bioorganic and Medicinal Chemistry Letters,1998,vol. 8,p. 2489 - 2494.

6
[ 2107-69-9 ]
[ 36517-91-6 ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.
[2]ChemPlusChem,2017,vol. 82,p. 1078 - 1095.
[3]Patent: TWI642658,2018,B .Location in patent: Paragraph 0056.
[4]Journal of Organic Chemistry,2021,vol. 86,p. 15217 - 15227.
[5]Angewandte Chemie - International Edition,2020,vol. 59,p. 17429 - 17434.
Angew. Chem.,2020,vol. 132,p. 17582 - 17587,6.
[6]Chemical Communications,2019,vol. 55,p. 2281 - 2284.

7
[ 36517-91-6 ]
[ 74084-26-7 ]
[ 738616-29-0 ]
2,2-bis[bis(3,4-dimethoxyphenyl)methyl]-5,6-dimethoxy-1H-indene-1,3(2H)-dione [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

8
[ 21852-32-4 ]
[ 36517-91-6 ]
[ 888701-47-1 ]
5,6-dimethoxy-2-(3,4-dimethoxybenzyl)-2-[3,4-dimethoxy-6-(3,4-dimethoxybenzyl)benzyl]-2,3-dihydro-1H-indene-1,3-dione [ No CAS ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

9
[ 36517-91-6 ]
[ 120-14-9 ]
[ 36517-70-1 ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

10
[ 36517-91-6 ]
[ 888701-46-0 ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

11
[ 36517-91-6 ]
[ 888701-47-1 ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

12
[ 36517-91-6 ]
2,3,6,7,10,11-hexamethoxy-4b,8b,13,14-tetrahydroindeno[1,2-a:2',1'-b]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.
[2]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

13
[ 36517-91-6 ]
trans-5,6-dimethoxy-2,2-bis(3,4-dimethoxybenzyl)-2,3-dihydro-1H-indene-1,3-diol [ No CAS ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.
[2]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

14
[ 36517-91-6 ]
2,3,6,7,13,14-hexamethoxy-9H,10H-4b,9a-([1,2]benzenomethano)indeno[1,2-a]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.
[2]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

15
[ 36517-91-6 ]
[ 888701-50-6 ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.
[2]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

16
[ 36517-91-6 ]
[ 888701-52-8 ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.
[2]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

17
[ 36517-91-6 ]
5,6-dimethoxy-2-(3,4-dimethoxybenzyl)-2-[3,4-dimethoxy-6-(3,4-dimethoxybenzyl)benzyl]-2,3-dihydro-1H-indene-1,3-dione [ No CAS ]

References: [1]European Journal of Organic Chemistry,2006,p. 1647 - 1655.

18
[ 36517-91-6 ]
2,3,6,7,10,11-hexamethoxy-12d-methyl-12b,12d-dihydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene-4b(8bH)-ol [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

19
[ 36517-91-6 ]
[ 738616-39-2 ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.
[2]Chemical Communications,2019,vol. 55,p. 2281 - 2284.

20
[ 36517-91-6 ]
5-(3,4-dimethoxyphenyl)-2,3,8,9-tetramethoxy-5,10b-dihydroindeno[1,2-a]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

21
[ 36517-91-6 ]
all-cis-2-[bis(3,4-dimethoxyphenyl)methyl]-5,6-dimethoxyindane-1,3-diol [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

22
[ 36517-91-6 ]
[ 738616-33-6 ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.
[2]Chemical Communications,2019,vol. 55,p. 2281 - 2284.

23
[ 36517-91-6 ]
2,3,6,7,10,11-hexamethoxy-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.
[2]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

24
[ 36517-91-6 ]
2,3,6,7,10,11-hexamethoxy-12d-methyl-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

25
[ 36517-91-6 ]
1-bromo-2,3,6,7,10,11-hexamethoxy-12d-methyl-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

26
[ 36517-91-6 ]
2,3,6,7,10,11-hexamethoxy-4b,8b,12b,12d-tetramethyl-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

27
[ 36517-91-6 ]
6-(4,5-dimethoxy-2-nitrophenyl)-2,3,8,9-tetramethoxy-5a-methyl-5,5a,6,10b-tetrahydroindeno[1,2-a]inden-5-yl acetate [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

28
[ 36517-91-6 ]
4b,8b,12b-tribromo-2,3,6,7,10,11-hexamethoxy-12d-methyl-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

29
[ 36517-91-6 ]
2,3,6,7,10,11-hexamethoxy-12d-methyl-4b,8b,12b,12d-tetrahydrodibenzo[2,3:4,5]pentaleno[1,6-ab]indene-4b,8b,12b(12dH)-triol [ No CAS ]

References: [1]European Journal of Organic Chemistry,2004,p. 2381 - 2397.

30
[ 155586-41-7 ]
[ 36517-91-6 ]

References: [1]Chemistry Letters,1994,p. 389 - 392.

31
[ 155586-38-2 ]
[ 36517-91-6 ]

References: [1]Chemistry Letters,1994,p. 389 - 392.

32
3-amino-3-(3,4-dimethoxyphenyl)propanoic acid [ No CAS ]
[ 36517-91-6 ]

References: [1]Bulletin de la Societe Chimique de France,1993,vol. 130,p. 121 - 124.

33
[ 138621-67-7 ]
[ 36517-91-6 ]

References: [1]Bulletin de la Societe Chimique de France,1993,vol. 130,p. 121 - 124.

34
[ 148502-19-6 ]
[ 36517-91-6 ]

References: [1]Bulletin de la Societe Chimique de France,1993,vol. 130,p. 121 - 124.

35
[ 75-15-0 ]
[ 36517-91-6 ]
[ 74-88-4 ]
[ 1201944-89-9 ]

References: [1]Bioorganic and Medicinal Chemistry Letters,2009,vol. 19,p. 6548 - 6551.

Historical Records

Technical Information

• Baeyer-Villiger Oxidation • Barbier Coupling Reaction • Baylis-Hillman Reaction • Benzylic Oxidation • Birch Reduction • Blanc Chloromethylation • Bucherer-Bergs Reaction • Clemmensen Reduction • Corey-Bakshi-Shibata (CBS) Reduction • Corey-Chaykovsky Reaction • Fischer Indole Synthesis • Friedel-Crafts Reaction • Grignard Reaction • Henry Nitroaldol Reaction • Horner-Wadsworth-Emmons Reaction • Hydride Reductions • Hydrogenolysis of Benzyl Ether • Lawesson's Reagent • Leuckart-Wallach Reaction • McMurry Coupling • Meerwein-Ponndorf-Verley Reduction • Nomenclature of Ethers • Passerini Reaction • Paternò-Büchi Reaction • Petasis Reaction • Peterson Olefination • Pictet-Spengler Tetrahydroisoquinoline Synthesis • Preparation of Aldehydes and Ketones • Preparation of Alkylbenzene • Preparation of Amines • Preparation of Ethers • Prins Reaction • Reactions of Aldehydes and Ketones • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Reactions of Ethers • Reformatsky Reaction • Robinson Annulation • Schlosser Modification of the Wittig Reaction • Schmidt Reaction • Specialized Acylation Reagents-Ketenes • Stobbe Condensation • Tebbe Olefination • Ugi Reaction • Vilsmeier-Haack Reaction • Wittig Reaction • Wolff-Kishner Reduction

Related Functional Groups of
[ 36517-91-6 ]

Aryls

A120912 [2107-69-9]

5,6-Dimethoxy-2,3-dihydro-1H-inden-1-one

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Ethers

A120912 [2107-69-9]

5,6-Dimethoxy-2,3-dihydro-1H-inden-1-one

Similarity: 1.00

A425006 [127399-78-4]

5-Hydroxy-6-methoxy-2,3-dihydro-1H-inden-1-one

Similarity: 1.00

A321864 [90843-62-2]

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A788255 [42337-64-4]

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Similarity: 0.94

Ketones

A120912 [2107-69-9]

5,6-Dimethoxy-2,3-dihydro-1H-inden-1-one

Similarity: 1.00

A425006 [127399-78-4]

5-Hydroxy-6-methoxy-2,3-dihydro-1H-inden-1-one

Similarity: 1.00

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Similarity: 0.94

Precautionary Statements-General
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P220	Keep/Store away from clothing/combustible materials.
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P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
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P272	Contaminated work clothing should not be allowed out of the workplace.
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P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
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P285	In case of inadequate ventilation wear respiratory protection.
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P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
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P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
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P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
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P401
P402	Store in a dry place.
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P411
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P413
P420	Store away from other materials.
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P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
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P410 + P403	Protect from sunlight. Store in a well-ventilated place.
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Disposal
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P501	Dispose of contents/container to ...
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
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H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
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H281	Contains refrigerated gas; may cause cryogenic burns or injury
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Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
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H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
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H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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CAS No.: 36517-91-6

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