[ CAS No. 572-09-8 ]

Name: 572-09-8|2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl bromide|98% (stabilized with 1% CaCO3)
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Product Details of [ 572-09-8 ]

CAS No. :	572-09-8	MDL No. :	MFCD00063254
Formula :	C₁₄H₁₉BrO₉	Boiling Point :	412°C at 760 mmHg
Linear Structure Formula :	-	InChI Key :	N/A
M.W :	411.20 g/mol	Pubchem ID :	-
Synonyms :

Safety of [ 572-09-8 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P280-P305+P351+P338	UN#:	N/A
Hazard Statements:	H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 572-09-8 ]

Upstream synthesis route of [ 572-09-8 ]
Downstream synthetic route of [ 572-09-8 ]

[ 572-09-8 ] Synthesis Path-Upstream 1~21

1
[ 773-76-2 ]
[ 572-09-8 ]
[ 492-61-5 ]
[ 130-16-5 ]

Reference： [1] Dalton Transactions, 2013, vol. 42, # 6, p. 2023 - 2034

2
[ 572-09-8 ]
[ 10338-51-9 ]

Reference： [1] Phytochemistry, 1988, vol. 27, # 6, p. 1813 - 1816
[2] Tetrahedron, 1989, vol. 45, # 12, p. 3673 - 3682

3
[ 446-72-0 ]
[ 572-09-8 ]
[ 529-59-9 ]

Reference： [1] Journal of the Chemical Society - Perkin Transactions 1, 1998, # 16, p. 2481 - 2484

4
[ 572-09-8 ]
[ 578-74-5 ]

Reference： [1] Tetrahedron, 2004, vol. 60, # 9, p. 2025 - 2034

5
[ 520-36-5 ]
[ 572-09-8 ]
[ 578-74-5 ]

Reference： [1] Yakugaku Zasshi, 1940, vol. 60, p. 502,505; engl. Ref. S. 190[2] Chem.Abstr., 1941, p. 4022

6
[ 572-09-8 ]
[ 57817-89-7 ]

Reference： [1] Tetrahedron, 1980, vol. 36, p. 2641 - 2648

7
[ 572-09-8 ]
[ 6044-30-0 ]

Reference： [1] Journal of the Chemical Society, 1930, p. 2729,2732

8
[ 572-09-8 ]
[ 138-52-3 ]

Reference： [1] Synthesis (Germany), 2016, vol. 48, # 20, p. 3575 - 3588

9
[ 572-09-8 ]
[ 618-65-5 ]

Reference： [1] Russian Journal of General Chemistry, 2001, vol. 71, # 11, p. 1811 - 1814
[2] Journal of the Chemical Society, 1930, p. 2729,2732
[3] Yakugaku Zasshi, 1958, vol. 78, p. 939,940[4] Chem.Abstr., 1958, p. 20010

10
[ 572-09-8 ]
[ 494-08-6 ]

Reference： [1] Synthesis (Germany), 2016, vol. 48, # 20, p. 3575 - 3588

11
[ 572-09-8 ]
[ 494-08-6 ]

Reference： [1] Carbohydrate Research, 2018, vol. 460, p. 41 - 46

12
[ 572-09-8 ]
[ 531-75-9 ]

Reference： [1] Archiv der Pharmazie (Weinheim, Germany), 1944, vol. 282, p. 79,88
[2] Bulletin de la Societe Chimique de France, 1948, p. 476,478

13
[ 160227-12-3 ]
[ 4753-07-5 ]
[ 572-09-8 ]
[ 3068-32-4 ]

Reference： [1] Carbohydrate Research, 1996, vol. 295, p. 41 - 55

14
[ 25878-60-8 ]
[ 572-09-8 ]
[ 3068-32-4 ]

Reference： [1] Chemical Biology and Drug Design, 2012, vol. 80, # 5, p. 647 - 656

15
[ 572-09-8 ]
[ 118-34-3 ]

Reference： [1] Synthesis, 1998, # 2, p. 157 - 161
[2] Chemische Berichte, 1929, vol. 62, p. 2279

16
[ 20675-96-1 ]
[ 572-09-8 ]
[ 118-34-3 ]

Reference： [1] Chemische Berichte, 1955, vol. 88, p. 16,20

17
[ 83-46-5 ]
[ 572-09-8 ]
[ 474-58-8 ]

Reference： [1] Journal of the Chemical Society, 1913, vol. 103, p. 1022,1026
[2] Journal of Organic Chemistry, 1953, vol. 18, p. 1473,1476
[3] Collection of Czechoslovak Chemical Communications, 1973, vol. 38, p. 3273 - 3278
[4] Journal of Natural Products, 2001, vol. 64, # 7, p. 993 - 996

18
[ 572-09-8 ]
[ 474-58-8 ]

Reference： [1] Journal of Pharmaceutical Sciences, 1985, vol. 74, # 12, p. 1259 - 1264

19
[ 112-17-4 ]
[ 604-69-3 ]
[ 112-29-8 ]
[ 572-09-8 ]

Yield	Reaction Conditions	Operation in experiment
57%	at 20℃; Irradiation; Green chemistry	General procedure: Bromine (1.5 mmol, 0.08 mL) was added slowly to a magnetic stirring barand perfluorohexanes (4.0 mL) in a test tube (14 mmφ x 105 mm) with a septum and then 1-O-acetylsugar 1a (1 mmol, 392 mg) in ethyl acetate (2.0 mL) wasadded slowly, forming three layers. The test tube was stirring upon irradiationwith 15 W black light (at 352 nm, TOSHIBA EFD15BLB-T) at 30 C. The light source wasplaced away from the test tube. After 23 hours, the bromine layer disappearedand the fluorous layer recovered transparency. The ethyl acetate layer wastaken up with a pipette. Then, additional ethyl acetate (2 mL x 4) was placedon the residual FC-72 layer, followed by decanting off. The combined ethylacetate layer was washed with water (15 mL), aqueous sat. NaHCO₃ (20mL), brine (20 mL) and, dried over Na₂SO₄, andconcentrated. Purification by chromatography on silica gel with hexane/AcOEt = 2/1gave glycosyl bromide 2a (0.91 mmol,374 mg) in 91percent yield

Reference： [1] Tetrahedron Letters, 2013, vol. 54, # 52, p. 7124 - 7126

20
[ 572-09-8 ]
[ 761423-87-4 ]

Reference： [1] Patent: CN108276396, 2018, A,

21
[ 572-09-8 ]
[ 951382-34-6 ]

Reference： [1] Patent: CN108276396, 2018, A,

[ 572-09-8 ] Synthesis Path-Downstream 1~24

1
[ 6100-74-9 ]
[ 572-09-8 ]
[ 102761-95-5 ]

Reference： [1]Canadian Journal of Biochemistry and Physiology,1957,vol. 35,p. 161,164, 166

2
[ 2538-87-6 ]
[ 572-09-8 ]
[ 203179-61-7 ]

Reference： [1]Chemische Berichte,1951,vol. 84,p. 443,450

3
[ 2037-95-8 ]
[ 572-09-8 ]
[ 3325-51-7 ]

Reference： [1]Pharmazie,1965,vol. 20,p. 11 - 15

4
[ 51605-32-4 ]
[ 572-09-8 ]
[ 77421-52-4 ]
[ 77421-53-5 ]

Reference： [1]European Journal of Medicinal Chemistry,1980,vol. 15,p. 551 - 555
[2]European Journal of Medicinal Chemistry,1980,vol. 15,p. 551 - 555

5
[ 939-69-5 ]
[ 572-09-8 ]
[ 131474-31-2 ]

Reference： [1]Carbohydrate Research,1990,vol. 205,p. 225 - 233

6
[ 18362-30-6 ]
[ 572-09-8 ]
[ 159194-03-3 ]

Reference： [1]Journal of the Chemical Society. Chemical communications,1994,p. 1697 - 1698

7
[ 42019-78-3 ]
[ 572-09-8 ]
Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-[4-(4-chloro-benzoyl)-phenoxy]-tetrahydro-pyran-4-yl ester [ No CAS ]

Reference： [1]Journal of Medicinal Chemistry,1993,vol. 36,p. 898 - 903

8
[ 23148-51-8 ]
[ 572-09-8 ]
Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-[6-(4-chloro-phenyl)-3-cyano-2-oxo-2H-pyridin-1-yl]-tetrahydro-pyran-3-yl ester [ No CAS ]

Reference： [1]Nucleosides and Nucleotides,1999,vol. 18,p. 2335 - 2343

9
[ 218600-44-3 ]
[ 572-09-8 ]
(4aS,6aR,6bS,8aR,12aS,14aR,14bS)-11-Cyano-2,2,6a,6b,9,9,12a-heptamethyl-10,14-dioxo-1,3,4,5,6,6a,6b,7,8,8a,9,10,12a,14,14a,14b-hexadecahydro-2H-picene-4a-carboxylic acid (2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yl ester [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	With potassium carbonate;Aliquat 336; In dichloromethane; water;	Dinitrile 1 was synthesized from CDDO by the method as shown in Scheme 1. Oxalyl chloride gave acyl chloride 19 in quantitative yield. Amide 3 was prepared in 91% yield from 19 with ammonia gas in benzene. Dehydration of 3 with thionyl chloride gave 1 in 89% yield (Drefahl and Huneck, 1958). Ester 5 was synthesized in 83% yield from CDDO by a nucleophilic substitution method using an alkyl halide and DBU in toluene (reflux) (Ono et al., 1978) (Method A) Amides including imidazolides were synthesized in good yield by condensation reactions (Method B, scheme 1) between acyl chloride 19 and the corresponding amines and imidazoles. Tetra-O-acetyl-beta-D-glucopyranoside 2 was prepared in 75% yield from tetra-O-acetyl-alpha-D-glucopyranoside bromide (Lemieux, 1963) and CDDO using a phase-transfer catalyst (Bliard et al., 1994) (Scheme 2) (Method C). Because in the 1H-NMR spectrum (300 MHz, CDCl3) of 2 the anomeric proton was observed at delta5.70 ppm (1H, d, J=7.8 Hz) the proton was assigned the beta-configuration.

Reference： [1]Bioorganic and Medicinal Chemistry Letters,2002,vol. 12,p. 1027 - 1030
[2]Patent: US2004/2463,2004,A1 .Location in patent: Page/Page column 9-11

10
[ 572-09-8 ]
[ 58846-77-8 ]

Reference： [1]Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry,2006,vol. 45,p. 461 - 465
[2]Journal of the American Chemical Society,1942,vol. 64,p. 369,372
[3]Journal of the American Chemical Society,1938,vol. 60,p. 2076

11
[ 61439-59-6 ]
[ 572-09-8 ]
C₂₉H₃₄O₁₁ [ No CAS ]

Reference： [1]Chemical and Pharmaceutical Bulletin,2010,vol. 58,p. 1627 - 1629

12
[ 403-01-0 ]
[ 572-09-8 ]
[ 115933-45-4 ]

Reference： [1]Molecules,2013,vol. 18,p. 3789 - 3805

13
[ 392-04-1 ]
[ 572-09-8 ]
ethyl 4-fluoro-2-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-(acetoxymethyl)tetrahydro-2H-pyran-2-yloxy)benzoate [ No CAS ]

Reference： [1]Molecules,2013,vol. 18,p. 3789 - 3805

14
[ 443-87-8 ]
[ 572-09-8 ]
(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(3-fluoro-2-methylphenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate [ No CAS ]

Reference： [1]Molecules,2013,vol. 18,p. 3789 - 3805

15
[ 572-09-8 ]
[ 36062-04-1 ]
C₄₉H₆₀O₂₄ [ No CAS ]

Reference： [1]Archiv der Pharmazie,2014,vol. 347,p. 834 - 839

16
[ 572-09-8 ]
[ 25569-77-1 ]
(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(4-fluorobenzoyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate [ No CAS ]
(2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(4-fluorobenzoyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate [ No CAS ]

Reference： [1]Chemical Communications,2015,vol. 51,p. 10302 - 10305

17
[ 572-09-8 ]
[ 302348-51-2 ]
[(3R,4S,6S)-3,4,5-triacetoxy-6-[[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methoxy]tetrahydropyran-2-yl]methyl acetate [ No CAS ]
[(2R,3aS,6R,7S)-6,7-diacetoxy-2-methyl-2-[[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methoxy]-5,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-b]pyran-5-yl]methyl acetate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With 2,4,6-trimethyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane; toluene; at -78 - 20℃; for 13.17h;	To the solution of 819 mg [4-(4,4,5,5-tetramethyl-l,3,2-dioxaborolan-2-yl)phenyl] methanol (3.50 mmol, 1 eq.), 2015 mg l-bromo-2, 3,4, 6-tetra-0-acetyl-a/p-D- mannopyranose (4.90 mmol, 1.4 eq.), 467 mg s-collidine (3.85 mmol, 1.1 eq.) in 100 mL DCM 1708 mg silver trifluoromethanesulfonate (6.65 mmol, 1.9 eq.) in 15 mL toluene was added dropwise at -78 °C and the mixture was stirred at this temperature for 10 minutes. The mixture was let to warm slowly to r.t. (3 hours), then it was stirred for 10 hours. The mixture was filtered through a Celite pad, the filtrate was concentrated. The residue was purified by flash chromatography on silica gel using heptane and ethyl acetate as eluents to give Preparation 4o as first eluted product 1H NMR (500 MHz, DMSO-d6): 7.69 (m, 2H), 7.39 (m, 2H), 5.15-5.10 (m, 3H), 4.96 (d, 1H), 4.71 (d, 1H), 4.57 (d, 1H), 4.15 (dd, 1H), 4.04 (dd, 1H), 3.96 (m, 1H), 2.12-1.91 (s, 12H), 1.29 (s, 12H); and Preparation 4p as later eluted product. 1H NMR (500 MHz, DMSO-d6): 7.63 (m, 2H), 7.31 (m, 2H), 5.68 (d, 1H), 5.32 (dd, 1H), 5.05 (t, 1H), 4.59 (d, lh) 4.54 (dd, 1H), 4.53 (d, 1H), 4.12 (dd, 1H), 4.03 (dd, 1H), 3.94 (m, 1H), 2.01-1.97 (s, 9H), 1.70 (s, 3H), 1.29 (s, 12H)

Reference： [1]Patent: WO2016/207216,2016,A1 .Location in patent: Page/Page column 47; 48

18
[ 16957-70-3 ]
[ 572-09-8 ]
1-O-((E)-2-methylpent-2-enoyl)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranose [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
96%	With tetraethylammonium bromide; potassium carbonate; In dichloromethane; at 20℃;Molecular sieve;	General procedure: A mixture of glucosyl bromide 1 (1.03 g, 2.5 mmol), acid (5.0 mmol), K2CO3 (0.69 g, 5.0 mmol),TEAB (0.05 g, 0.25 mmol) and 4 A MS (0.25 g) in 35 mL DCM was stirred 24?48 h at room temperature.Next, the insoluble substances, made up of the slightly soluble potassium carboxylate, 4 A MS andother salts, were filtered off. The filtrate was washed with water, and the separated organic layer wasthen washed with 25percent aqueous K2CO3 to removed any remaining potassium carboxylate. After dryingover MgSO4 and concentration in vacuo, the residue was purified via silica gel column chromatographyusing EtOAc/hexane or EtOAc/petroleum ether (1:10 to 1:1) as eluents to yield the desired product.

Reference： [1]Molecules,2017,vol. 22

19
[ 575-03-1 ]
[ 572-09-8 ]
C₂₄H₂₃F₃O₁₂ [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2017,vol. 139,p. 10629 - 10632

20
[ 575-03-1 ]
[ 572-09-8 ]
[ 116981-86-3 ]

Reference： [1]Journal of the American Chemical Society,2017,vol. 139,p. 10629 - 10632

21
[ 461432-23-5 ]
[ 572-09-8 ]
[ 461432-25-7 ]

Yield	Reaction Conditions	Operation in experiment
84%		Method 4) 4-bromo-1-chloro-2-(4-ethoxybenzyl)benzene (4.9 g, 15 mmol) and 20 mL of tetrahydrofuran were added to a 50 mL three-necked flask, and the mixture was stirred and cooled to -5 to 0 C.Slowly add isopropylmagnesium chloride Grignard reagent (8 mL, 2 mol/L).The system was stirred at 0 C for 2 h.In another 100mL three-neck bottle,Add (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-bromotetrahydro-2H-pyran-3,4,5-triacetyl ester (IIa, 4.1 g, 10 mmol) , tetramethylethylenediamine (10wt%),Cobalt dichloride (10 wt%) and 20 mL of 2-methyltetrahydrofuran,The system was cooled to 0 C.Slowly add the Grignard reagent in the previous 50mL bottle and add it in about 30min.After the completion of the system, the system was warmed to 25 to 30 C, and the mixture was stirred for 2 hours. The system was quenched with 1N aqueous hydrochloric acid and the organic phase was extracted with ethyl acetate.concentrate,Column chromatography (PE/EA=3/1),The target product (4.5 g, yield 84%) was obtained.
		Under argon protection conditions,300 mL of dried tetrahydrofuran (THF) was added to a 1 L three-necked flask,5-bromo-2-chloro-4-ethyldiphenylmethane (65.5 g, 200 mmol)The temperature of the reaction system was controlled at -78 C with an acetone /(N-BuLi) 80 mL (2.5 mol / L, 200 mmol, 1 eq) was slowly added dropwise. The temperature of the reaction system was controlled at -78 C or lower, and the reaction was continued at the end of the dropwise addition. hour;Then, 19.1 g (100 mmol) of cuprous iodide was slowly added to the reaction system, and the temperature of the reaction system was controlledIn the -40 ~ -30 reaction 1 hour, then slowly to the reaction system drip2,3,4,6-tetra-O-acetyl-alpha-D-pyran bromoglucoseTHF solution (41.5 g, 100 mmol, THF 100 mL, 0.5 eq) was added and the reaction temperature was controlled at -40 to -30 C during the addition and maintained at that temperature for 1 hour,After the addition was complete, the temperature of the reaction system was gradually returned to room temperature for 3 hours.After the reaction was quenched under ice cooling conditions with a saturated NaHCO3 solution to quench the reaction, extracted with ethyl acetate, and the combined organic phases, the organic phase with saturated brine, dried over anhydrous magnesium sulfate and concentrated under reduced pressure to give a brown crude product was 59.8 g, 300 mL of anhydrous ethanol to give 53.1 g of a white solid (Compound 1:2-chloro-5- (2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl-1-yl)4'-ethoxydiphenylmethane),HPLC detection purity of 98.5% or more, the yield of 93%.

Reference： [1]Patent: CN104059041,2018,B .Location in patent: Paragraph 0023; 0024; 0030; 0032; 0028
[2]Patent: CN104496952,2017,B .Location in patent: Paragraph 0033-0037

22
C₂₉H₃₇N₆NiO₂⁽¹⁺⁾*I^(1-) [ No CAS ]
[ 572-09-8 ]
[ 792-74-5 ]
[ 3366-47-0 ]

Reference： [1]Organic Letters,2018,vol. 20,p. 7991 - 7995

23
C₂₆H₃₁N₂NiO₂⁽¹⁺⁾*I^(1-) [ No CAS ]
[ 572-09-8 ]
[ 792-74-5 ]
[ 3366-47-0 ]

Reference： [1]Organic Letters,2018,vol. 20,p. 7991 - 7995

24
[ 619-44-3 ]
[ 572-09-8 ]
(2R,3R,4R,5S)-2-(acetoxymethyl)-6-(4-(methoxycarbonyl)phenyl)tetrahydro-2H-pyran-3,4,5-triyl triacetate [ No CAS ]
[ 1056028-62-6 ]
[ 792-74-5 ]
[ 3366-47-0 ]

Reference： [1]Organic Letters,2018,vol. 20,p. 7991 - 7995

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P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Purity	Size	Price	VIP Price	USA Stock *0-1 Day	Global Stock *5-7 Days	Quantity
{[ item.p_purity ]}	{[ item.pr_size ]}	{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]}	{[ getRatePrice(item.pr_usd, 1,1) ]}	{[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]}	{[ item.pr_usastock ]}	Inquiry -	{[ item.pr_chinastock ]}	Inquiry -

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 572-09-8 ]

Quality Control of [ 572-09-8 ]

Related Doc. of [ 572-09-8 ]

Product Details of [ 572-09-8 ]

Safety of [ 572-09-8 ]

Application In Synthesis of [ 572-09-8 ]

[ 572-09-8 ] Synthesis Path-Upstream 1~21

[ 572-09-8 ] Synthesis Path-Downstream 1~24

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry