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[ CAS No. 572-09-8 ]

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2D
Chemical Structure| 572-09-8
Chemical Structure| 572-09-8
Structure of 572-09-8 *Storage: {[proInfo.prStorage]}

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Product Details of [ 572-09-8 ]

CAS No. :572-09-8MDL No. :MFCD00063254
Formula : C14H19BrO9 Boiling Point : 412°C at 760 mmHg
Linear Structure Formula :-InChI Key :N/A
M.W :411.20Pubchem ID :-
Synonyms :

Computed Properties of [ 572-09-8 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 572-09-8 ]

Signal Word:WarningClass:N/A
Precautionary Statements:P280-P305+P351+P338UN#:N/A
Hazard Statements:H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 572-09-8 ]

  • Upstream synthesis route of [ 572-09-8 ]
  • Downstream synthetic route of [ 572-09-8 ]

[ 572-09-8 ] Synthesis Path-Upstream   1~7

  • 1
  • [ 773-76-2 ]
  • [ 572-09-8 ]
  • [ 492-61-5 ]
  • [ 130-16-5 ]
Reference: [1] Dalton Transactions, 2013, vol. 42, # 6, p. 2023 - 2034
  • 2
  • [ 572-09-8 ]
  • [ 138-52-3 ]
Reference: [1] Synthesis (Germany), 2016, vol. 48, # 20, p. 3575 - 3588
  • 3
  • [ 160227-12-3 ]
  • [ 4753-07-5 ]
  • [ 572-09-8 ]
  • [ 3068-32-4 ]
Reference: [1] Carbohydrate Research, 1996, vol. 295, p. 41 - 55
  • 4
  • [ 25878-60-8 ]
  • [ 572-09-8 ]
  • [ 3068-32-4 ]
Reference: [1] Chemical Biology and Drug Design, 2012, vol. 80, # 5, p. 647 - 656
  • 5
  • [ 572-09-8 ]
  • [ 118-34-3 ]
Reference: [1] Synthesis, 1998, # 2, p. 157 - 161
[2] Chemische Berichte, 1929, vol. 62, p. 2279
  • 6
  • [ 20675-96-1 ]
  • [ 572-09-8 ]
  • [ 118-34-3 ]
Reference: [1] Chemische Berichte, 1955, vol. 88, p. 16,20
  • 7
  • [ 112-17-4 ]
  • [ 604-69-3 ]
  • [ 112-29-8 ]
  • [ 572-09-8 ]
YieldReaction ConditionsOperation in experiment
57% at 20℃; Irradiation; Green chemistry General procedure: Bromine (1.5 mmol, 0.08 mL) was added slowly to a magnetic stirring barand perfluorohexanes (4.0 mL) in a test tube (14 mmφ x 105 mm) with a septum and then 1-O-acetylsugar 1a (1 mmol, 392 mg) in ethyl acetate (2.0 mL) wasadded slowly, forming three layers. The test tube was stirring upon irradiationwith 15 W black light (at 352 nm, TOSHIBA EFD15BLB-T) at 30 C. The light source wasplaced away from the test tube. After 23 hours, the bromine layer disappearedand the fluorous layer recovered transparency. The ethyl acetate layer wastaken up with a pipette. Then, additional ethyl acetate (2 mL x 4) was placedon the residual FC-72 layer, followed by decanting off. The combined ethylacetate layer was washed with water (15 mL), aqueous sat. NaHCO3 (20mL), brine (20 mL) and, dried over Na2SO4, andconcentrated. Purification by chromatography on silica gel with hexane/AcOEt = 2/1gave glycosyl bromide 2a (0.91 mmol,374 mg) in 91percent yield
Reference: [1] Tetrahedron Letters, 2013, vol. 54, # 52, p. 7124 - 7126
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