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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 6331-00-6 Chemical Structure| 6331-00-6

Structure of 6331-00-6

Chemical Structure| 6331-00-6

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Product Citations

Product Citations

Hern, Morgan ; Foley, Rebecca ; Bacsa, John ; Wallen, Christian M. ;

Abstract: Second-sphere hydrogen bonds are known for playing significant roles in homogeneous catalysis and in biol. processes with metal-containing mols. In this work, the authors highlight a tetradentate asym. ether-sulfonamidate ligand that facilitates second-sphere hydrogen bonding in transition metal complexes. We explored its ability to bind mono-, di-, tri-, and tetra-protic ligands when supporting a cobalt(II) ion. The structures of three such cobalt complexes containing bound water, ammonia, and hydrazine are presented. Addnl., spectroscopic anal. of a strongly bound hydroxide ion complex is presented. A hydrogen-bonding configuration, not yet observed in crystal structures of this type, resulted in a bridging hydrazine complex with the two cobalt ions separated by a distance of 5 Å.

Keywords: Cobalt ; hydrogen-bonding ; second-sphere ; small molecule ; protic ligand

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Product Details of [ 6331-00-6 ]

CAS No. :6331-00-6
Formula : C9H12ClNO2S
M.W : 233.72
SMILES Code : O=S(C1=CC=C(C)C=C1)(NCCCl)=O
MDL No. :MFCD00039369

Safety of [ 6331-00-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301
Precautionary Statements:P264-P270-P301+P310+P330-P405-P501
Class:6.1
UN#:2811
Packing Group:
 

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