6642-30-4|Methyl methylcarbamate| Ambeed

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Structure of 6642-30-4

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Quality Control of [ 6642-30-4 ] Purity: 95% SDS Specification

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Product Details of [ 6642-30-4 ]

CAS No. :	6642-30-4
Formula :	C₃H₇NO₂
M.W :	89.09
SMILES Code :	O=C(OC)NC
MDL No. :	MFCD00082210
InChI Key :	NYXHSRNBKJIQQG-UHFFFAOYSA-N
Pubchem ID :	81151

Safety of [ 6642-30-4 ]

GHS Pictogram:
Signal Word:	Danger
Hazard Statements:	H225-H315-H319-H335
Precautionary Statements:	P210-P261-P305+P351+P338
Class:	3
UN#:	1993
Packing Group:	Ⅲ

Application In Synthesis of [ 6642-30-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 6642-30-4 ]

[ 6642-30-4 ] Synthesis Path-Downstream 1~35

1
[ 186581-53-3 ]
[ 60-29-7 ]
[ 624-83-9 ]
[ 554-70-1 ]
[ 6642-30-4 ]

References: [1]Chemische Berichte,1927,vol. 60,p. 1025.

2
[ 186581-53-3 ]
[ 624-83-9 ]
[ 6642-30-4 ]

References: [1]Chemische Berichte,1927,vol. 60,p. 1025.

3
[ 463-72-9 ]
[ 6642-30-4 ]
[ 89695-55-6 ]

References: [1]Chemische Berichte,1923,vol. 56,p. 1918.
[2]Collection of Czechoslovak Chemical Communications,1961,vol. 26,p. 2519 - 2528.

4
[ 6642-30-4 ]
[ 124-41-4 ]
[ 827-16-7 ]

References: [1]Journal of the American Chemical Society,1956,vol. 78,p. 4358,4360.

5
[ 6642-30-4 ]
[ 827-16-7 ]

References: [1]Journal of the American Chemical Society,1956,vol. 78,p. 4358,4360.
[2]Journal of the American Chemical Society,1956,vol. 78,p. 4358,4360.

6
[ 6642-30-4 ]
[ 10165-17-0 ]

Yield	Reaction Conditions	Operation in experiment
	With phosphoric acid; sodium nitrite; In water; at 10 - 25℃;	Example 2. Preparation of N-nitroso-dimethylurethane in toluene o MeOA N - N Me N-Nitroso-dimethyl urethane H3PO4 50% in water (9.2 g, 48 mmol) is added to dimethylcarbamate (4.9 g, 55 mmol) at 10 - 20 C under stirring. To the colorless 2-phase mixture is added NaN02 30% in water (20.1 g, 67 mmol) at 10 - 15 C over 1 - 1.5 h. Nitrous gases are formed at the end of the addition and the orange solution is stirred for 17 h at 25 C. Nitrogen is bubbled through the reaction mixture to expel remaining nitrous gases. Stirring is stopped and a sample is taken from the orange organic layer for analytical analysis which shows a conversion of 88 - 92% according to GCMS and NMR. The reaction mixture is extracted twice with toluene (15 ml, 10 ml) to give 30 ml of a clear light orange solution which is used as such in the cyclopropanation step. Analytical data of the organic layer before toluene addition: 1H-NMR (CDC13, 400 MHz): 4.1 (s, 3 H), 3.2 (s, 3 H) ppm. 13C-NMR (CDC13, 400 MHz): 154.2 (s), 54.9 (q), 28.0 (q) ppm. GC/MS: 118 (20%, M+), 87 (10%), 59 (100%), 56 (20%), 43 (77%), 42 (26%), 30 (74%), 28 (21%).

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1890,vol. 9,p. 139.
[2]Recueil des Travaux Chimiques des Pays-Bas,1890,vol. 9,p. 139.
[3]Chemische Berichte,1948,vol. 81,p. 378.
[4]Patent: WO2015/59290,2015,A1 .Location in patent: Page/Page column 17-18.

7
[ 6642-30-4 ]
[ 14442-54-7 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1888,vol. 7,p. 354.
[2]Journal of Organic Chemistry,1966,vol. 31,p. 3038 - 3046.

8
[ 6642-30-4 ]
[ 624-83-9 ]

References: [1]Patent: US2409712,1944, .

9
[ 6642-30-4 ]
[ 67-56-1 ]
[ 624-83-9 ]

References: [1]Patent: US2409712,1944, .

10
[ 67-56-1 ]
[ 624-83-9 ]
[ 6642-30-4 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1936,vol. 55,p. 382.

11
[ 593-51-1 ]
[ 79-22-1 ]
[ 6642-30-4 ]

References: [1]Chemische Berichte,1923,vol. 56,p. 1918.

12
[ 79-22-1 ]
[ 74-89-5 ]
[ 6642-30-4 ]

References: [1]Journal of Organic Chemistry,2012,vol. 77,p. 9313 - 9328,16.
[2]Chemische Berichte,1948,vol. 81,p. 378.
[3]Recueil des Travaux Chimiques des Pays-Bas,1888,vol. 7,p. 354.
[4]Journal of Organic Chemistry,1979,vol. 44,p. 4891 - 4896.

13
[ 57-13-6 ]
[ 74-89-5 ]
[ 6642-30-4 ]

References: [1]Patent: US2677698,1950, .

14
[ 38103-95-6 ]
[ 74-89-5 ]
[ 6642-30-4 ]

References: [1]Bulletin de la Societe Chimique de France,1910,vol. <4>7,p. 895,901.
Annales de Chimie (Cachan, France),1912,vol. <8>25,p. 557.

15
[ 124-41-4 ]
[ 79-15-2 ]
[ 6642-30-4 ]

References: [1]American Chemical Journal,1894,vol. 16,p. 372.

16
[ 67-56-1 ]
[ 38951-66-5 ]
[ 6642-30-4 ]

References: [1]Tetrahedron,1976,vol. 32,p. 251 - 256.

17
[ 50-00-0 ]
[ 6642-30-4 ]
[ 613-49-0 ]
[ 20614-93-1 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1970,vol. 89,p. 423 - 441.

18
[ 50-00-0 ]
[ 6642-30-4 ]
[ 20277-69-4 ]
[ 20614-97-5 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1970,vol. 89,p. 423 - 441.

19
[ 50-00-0 ]
[ 6642-30-4 ]
[ 20035-08-9 ]
[ 35145-10-9 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1971,vol. 90,p. 1307 - 1319.

20
[ 50-00-0 ]
[ 6642-30-4 ]
[ 51793-64-7 ]
[ 20614-98-6 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1970,vol. 89,p. 423 - 441.

21
[ 50-00-0 ]
[ 6642-30-4 ]
[ 15959-31-6 ]
[ 28147-87-7 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1970,vol. 89,p. 423 - 441.

22
[ 463-72-9 ]
[ 6642-30-4 ]
[ 91195-79-8 ]

References: [1]Collection of Czechoslovak Chemical Communications,1961,vol. 26,p. 2519 - 2528.

23
[ 6642-30-4 ]
[ 683-16-9 ]
[ 70615-71-3 ]

References: [1]Journal of general chemistry of the USSR,1979,vol. 49,p. 521 - 524.
Zhurnal Obshchei Khimii,1979,vol. 49,p. 596 - 600.

24
[ 6642-30-4 ]
[ 4693-38-3 ]
[ 71171-86-3 ]

References: [1]Journal of Organic Chemistry,1979,vol. 44,p. 3391 - 3396.

25
[ 6642-30-4 ]
[ 14668-82-7 ]
[ 30698-72-7 ]

References: [1]Journal of Organic Chemistry,1971,vol. 36,p. 2876 - 2880.

26
[ 6642-30-4 ]
[ 15586-25-1 ]

References: [1]Journal of general chemistry of the USSR,1966,vol. 36,p. 1448 - 1450.
Zhurnal Obshchei Khimii,1966,vol. 36,p. 1442 - 1444.

27
[ 6642-30-4 ]
[ 70731-33-8 ]

References: [1]Journal of Organic Chemistry USSR (English Translation),1982,p. 1038 - 1040.
Zhurnal Organicheskoi Khimii,1982,vol. 18,p. 1202 - 1205.
[2]Chemistry of Heterocyclic Compounds,1979,vol. 15,p. 1306 - 1309.
Khimiya Geterotsiklicheskikh Soedinenii,1979,vol. 15,p. 1628 - 1630.

28
[ 6642-30-4 ]
[ 70615-77-9 ]

References: [1]Journal of general chemistry of the USSR,1979,vol. 49,p. 521 - 524.
Zhurnal Obshchei Khimii,1979,vol. 49,p. 596 - 600.

29
[ 6092-56-4 ]
[ 6642-30-4 ]

References: [1]Journal of Organic Chemistry,1976,vol. 41,p. 143 - 145.

30
[ 16513-17-0 ]
[ 79-22-1 ]
[ 6642-30-4 ]

References: [1]Journal of general chemistry of the USSR,1972,vol. 42,p. 357 - 360.
Zhurnal Obshchei Khimii,1972,vol. 42,p. 367 - 370.

31
[ 6642-30-4 ]
[ 79-04-9 ]
[ 68559-36-4 ]

References: [1]Journal of the Chemical Society,1960,p. 983 - 989.

32
[ 50-00-0 ]
[ 6642-30-4 ]
[ 106-45-6 ]
[ 20614-95-3 ]

References: [1]Recueil des Travaux Chimiques des Pays-Bas,1970,vol. 89,p. 423 - 441.

33
[ 616-47-7 ]
[ 67-56-1 ]
[ 18197-25-6 ]
[ 6642-30-4 ]

References: [1]Heterocycles,1992,vol. 33,p. 385 - 390.

34
[ 616-47-7 ]
[ 18197-25-6 ]
[ 6642-30-4 ]

References: [1]Heterocycles,1992,vol. 33,p. 385 - 390.

35
[ 67-56-1 ]
[ 70264-96-9 ]
[ 4630-82-4 ]
[ 6642-30-4 ]
[ 71099-00-8 ]

References: [1]Journal of Organic Chemistry,1981,vol. 46,p. 27 - 34.

Historical Records

Technical Information

• Acyl Group Substitution • Bouveault-Blanc Reduction • Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions • Catalytic Hydrogenation • Chan-Lam Coupling Reaction • Complex Metal Hydride Reductions • Ester Cleavage • Heat of Combustion • Hydride Reductions • Leuckart-Wallach Reaction • Mannich Reaction • Petasis Reaction • Preparation of Amines • Reactions of Amines • Reactions with Organometallic Reagents • Specialized Acylation Reagents-Carbodiimides and Related Reagents • Specialized Acylation Reagents-Vilsmeier Reagent • Ugi Reaction

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P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
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Response
Code	Phrase
P301	IF SWALLOWED:
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P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
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P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
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P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
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P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
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P501	Dispose of contents/container to ...
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
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H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
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H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
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H361d	Suspected of damaging the unborn child
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H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

{[proInfo.proName]}

CAS No.: 6642-30-4

{[proInfo.proName]}

CAS No.: 6642-30-4

Alternative Products

Product Details of [ 6642-30-4 ]

Safety of [ 6642-30-4 ]

Application In Synthesis of [ 6642-30-4 ]

[ 6642-30-4 ] Synthesis Path-Downstream 1~35

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Technical Information

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Precautionary Statements-General

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