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[ CAS No. 7149-14-6 ]

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Cat. No.: {[proInfo.prAm]}
2D
Chemical Structure| 7149-14-6
Chemical Structure| 7149-14-6
Structure of 7149-14-6 *Storage: {[proInfo.prStorage]}

Quality Control of [ 7149-14-6 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 7149-14-6 ]

SDS

Product Details of [ 7149-14-6 ]

CAS No. :7149-14-6MDL No. :MFCD09878135
Formula :C6H3BrINO2Boiling Point :332.7°C at 760 mmHg
Linear Structure Formula :-InChI Key :-
M.W :327.90Pubchem ID :-
Synonyms :

Computed Properties of [ 7149-14-6 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 7149-14-6 ]

Signal Word:WarningClassN/A
Precautionary Statements:P261-P301+P312-P302+P352-P304+P340-P305+P351+P338UN#:N/A
Hazard Statements:H302-H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 7149-14-6 ]

  • Upstream synthesis route of [ 7149-14-6 ]

[ 7149-14-6 ] Synthesis Path-Upstream   1~6

  • 1
  • [ 13296-94-1 ]
  • [ 7149-14-6 ]
YieldReaction ConditionsOperation in experiment
77% With potassium iodide; sodium nitrite In water; acetonitrile at 0 - 5℃; for 0.50 h; Ice-cold solution of sodium nitrite (57.2 g, 829 mmol) and potassium iodide (138 g, 829 mmol) in water (25 mL) was added drop wise simultaneously to a stirred suspension of 2-bromo-4-nitroaniline (60 g, 276 mmol) in acetonitrile (250 mL) at 0-5 °C and stirred for 30 minutes. The reaction mixture was then poured on to ice-cold water (1000 mL). The solid obtained was filtered, washed with water and dried to afford the titlecompound.Yield: 70.0 g (77 percent); 1H NMR (300 MHz, CDCI3): O 7.86 (dd, 1H, J= 8.7, 2.4 Hz, Ar), 8.10(d, 1H, J= 8.7 Hz, Ar), 8.45 (d, 1H, J= 2.4 Hz, Ar); MS (El, 70 eV): m/z 328.3 (M+H).
Reference: [1] Patent: WO2015/49629, 2015, A1. Location in patent: Page/Page column 102
[2] Gazzetta Chimica Italiana, 1874, vol. 4, p. 341[3] Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1875, p. 317
[4] Chemistry - A European Journal, 2017, vol. 23, # 11, p. 2660 - 2665
  • 2
  • [ 636-98-6 ]
  • [ 7149-14-6 ]
Reference: [1] Synlett, 2013, vol. 24, # 5, p. 603 - 606
  • 3
  • [ 100-01-6 ]
  • [ 7149-14-6 ]
Reference: [1] Chemistry - A European Journal, 2017, vol. 23, # 11, p. 2660 - 2665
  • 4
  • [ 5411-50-7 ]
  • [ 7149-14-6 ]
Reference: [1] Gazzetta Chimica Italiana, 1874, vol. 4, p. 341[2] Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1875, p. 317
  • 5
  • [ 614-76-6 ]
  • [ 7149-14-6 ]
Reference: [1] Gazzetta Chimica Italiana, 1874, vol. 4, p. 341[2] Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1875, p. 317
  • 6
  • [ 615-36-1 ]
  • [ 7149-14-6 ]
Reference: [1] Gazzetta Chimica Italiana, 1874, vol. 4, p. 341[2] Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, 1875, p. 317
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