82410-79-5|1,4-Bis((2-methyl-1H-imidazol-1-yl)methyl)benzene| Ambeed

CAS No. :	82410-79-5
Formula :	C₁₆H₁₈N₄
M.W :	266.34
SMILES Code :	CC1=NC=CN1CC2=CC=C(CN3C=CN=C3C)C=C2
MDL No. :	N/A
InChI Key :	WMDWZOFWBUXBRI-UHFFFAOYSA-N
Pubchem ID :	71418705

Safety of [ 82410-79-5 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 82410-79-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 82410-79-5 ]

[ 82410-79-5 ] Synthesis Path-Downstream 1~54

1
[ 693-98-1 ]
[ 623-25-6 ]
[ 82410-79-5 ]

References: [1]Inorganic Chemistry,2018,vol. 57,p. 12331 - 12337.
[2]Chemical Communications,2018,vol. 54,p. 6975 - 6978.
[3]Journal of Molecular Structure,2006,vol. 796,p. 107 - 113.

2
[ 82410-79-5 ]
copper(II) choride dihydrate [ No CAS ]
[ 67-64-1 ]
[Cu₂Cl₄(1,4-bis[(2-methylimidazolyl)methyl]benzene)2]*2(acetone) [ No CAS ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.

3
[ 82410-79-5 ]
copper(II) choride dihydrate [ No CAS ]
[ 67-64-1 ]
(1,4-bis((2-methylimidazol-1-yl)methyl)benzene)2(CuCl₂)2 *2(acetone) [ No CAS ]

References: [1]Angewandte Chemie - International Edition,2006,vol. 45,p. 5856 - 5859.

4
[ 82410-79-5 ]
[ 2923-28-6 ]
Ag(CF₃SO₃)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene) [ No CAS ]

References: [1]Journal of Molecular Structure,2006,vol. 796,p. 107 - 113.

5
[ 82410-79-5 ]
copper(II) nitrate trihydrate [ No CAS ]
Cu(NO₃)2(H₂O)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)1.5*4H₂O [ No CAS ]

References: [1]Journal of Molecular Structure,2006,vol. 796,p. 107 - 113.

6
[ 82410-79-5 ]
[ 6046-93-1 ]
Cu(CH₃CO₂)2(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)2 [ No CAS ]

References: [1]Journal of Molecular Structure,2006,vol. 796,p. 107 - 113.

7
[ 82410-79-5 ]
[ 67-56-1 ]
cobalt(II) chloride hexahydrate [ No CAS ]
[ 333-20-0 ]
Co(SCN)2(CH₃OH)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)1.5 [ No CAS ]

References: [1]Journal of Molecular Structure,2006,vol. 796,p. 107 - 113.

8
[ 82410-79-5 ]
[ 14104-20-2 ]
[ 75-05-8 ]
[Ag₂(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)2](BF₄)2*2(acetonitrile) [ No CAS ]

References: [1]Journal of the American Chemical Society,2005,vol. 127,p. 13134 - 13135.

9
[ 82410-79-5 ]
[ 14104-20-2 ]
[Ag₂(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)3](BF₄)2 [ No CAS ]

References: [1]Chemical Communications,2005,p. 5050 - 5052.

10
[ 82410-79-5 ]
[ 499-83-2 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[zinc(II)(dipicolinate)(1,4-bis(2-methylimidazole-1-ylmethyl)benzene)0.5] [ No CAS ]

References: [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2011,vol. 637,p. 148 - 153.

11
[ 82410-79-5 ]
[ 499-83-2 ]
lead(II) nitrate [ No CAS ]
[lead(II)(dipicolinate)(1,4-bis(2-methylimidazole-1-ylmethyl)benzene)0.5] [ No CAS ]

References: [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2011,vol. 637,p. 148 - 153.

12
[ 82410-79-5 ]
[Ag₂(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)2](BF₄)2 [ No CAS ]

References: [1]Journal of the American Chemical Society,2005,vol. 127,p. 13134 - 13135.

13
[ 82410-79-5 ]
[Cu₂Cl₄(1,4-bis[(2-methylimidazolyl)methyl]benzene)2]*2(acetonitrile) [ No CAS ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.
[2]Chemical Communications,2018,vol. 54,p. 6975 - 6978.

14
[ 82410-79-5 ]
[Cu₂Cl₄(1,4-bis[(2-methylimidazolyl)methyl]benzene)2]*2(dichloromethane) [ No CAS ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.

15
[ 82410-79-5 ]
[Cu₂Cl₄(1,4-bis[(2-methylimidazolyl)methyl]benzene)2]*3CHCl₃ [ No CAS ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.

16
[ 82410-79-5 ]
[ 943326-65-6 ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.

17
[ 82410-79-5 ]
[Cu₂Cl₄(1,4-bis[(2-methylimidazolyl)methyl]benzene)2]*2(THF) [ No CAS ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.
[2]Chemical Communications,2018,vol. 54,p. 6975 - 6978.

18
[ 82410-79-5 ]
2[Cu₂Cl₄(1,4-bis[(2-methylimidazolyl)methyl]benzene)2]*3(dioxane) [ No CAS ]

References: [1]New Journal of Chemistry,2007,vol. 31,p. 669 - 676.

19
[ 82410-79-5 ]
[ 605-70-9 ]
[ 7732-18-5 ]
[ 20667-12-3 ]
([Ag₃(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)2(naphthalene-1,4-dicarboxylate)1.5]*H₂O)(n) [ No CAS ]

References: [1]Journal of Molecular Structure,2012,vol. 1014,p. 70 - 73.

20
[ 82410-79-5 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 99-31-0 ]
[ 7732-18-5 ]
[Zn2(1,4-bis[(2-methylimidazol-1-yl)methyl]benzene)(5-aminoisophthalate)2]·2H2O}n [ No CAS ]

References: [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2013,vol. 639,p. 187 - 192.

21
[ 82410-79-5 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 618-88-2 ]
[ 7732-18-5 ]
[ 1428229-57-5 ]

References: [1]Zeitschrift fur Anorganische und Allgemeine Chemie,2013,vol. 639,p. 187 - 192.

22
[ 82410-79-5 ]
[ 171820-04-5 ]
cobalt(II) chloride hexahydrate [ No CAS ]
[Co(bcpb)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)_0.5]·H2O}_n [ No CAS ]

References: [1]CrystEngComm,2014,vol. 16,p. 2144 - 2157.

23
[ 82410-79-5 ]
[ 171820-04-5 ]
copper(ll) sulfate pentahydrate [ No CAS ]
[Cu(bcpb)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)_0.5]_n [ No CAS ]

References: [1]CrystEngComm,2014,vol. 16,p. 2144 - 2157.

24
[ 82410-79-5 ]
[ 171820-04-5 ]
nickel(II) sulfate hexahydrate [ No CAS ]
[Ni(bcpb)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)_0.5]_n [ No CAS ]

References: [1]CrystEngComm,2014,vol. 16,p. 2144 - 2157.

25
[ 82410-79-5 ]
nickel(II) sulfate hexahydrate [ No CAS ]
[ 1365548-77-1 ]
[nickel(II)(terphenyl-2,5,2’,5’-tetracarboxylate)0.5(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)]*0.25H2O [ No CAS ]

References: [1]Dalton Transactions,2014,vol. 43,p. 6701 - 6710.

26
[ 82410-79-5 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
biphenyl-2,2'-dicarboxylate [ No CAS ]
Cd⁽²⁺⁾*C₁₄H₈O₄^(2-)*0.5C₁₆H₁₈N₄*H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide; In water; at 160.0℃; for 96h;Autoclave;	The mixtures of Cd(NO3)2·4H2O (0.5 mmol, 0.145 g), 2,2-bpdc (0.5 mmol, 0.121 g), bmib (0.5 mmol, 0.133 g), NaOH(1 mmol, 0.04 g) and 12 mL of water were placed in a 25 mLTeflon reactor, the mixtures were heated to 160C for four days,and then cooled to room temperature. The colorless crystalswere obtained in pure phase, washed with water and ethanol,and dried at room temperature. Anal. Calcd. for C22H19CdN2O5,C, 52.45; H, 3.80; N, 5.56. Found: C,52.49; H,3.82; N, 5.57.IR/cm-1(KBr): 3103 br,1604 s,1526 s, 1407 s,1322 m, 1237 m,1047 m,917 m, 820 m, 766 m.

References: [1]Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry,2014,vol. 44,p. 498 - 502.

27
[ 82410-79-5 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
biphenyl-3,4'-dicarboxylate [ No CAS ]
2Cd⁽²⁺⁾*2C₁₄H₈O₄^(2-)*C₁₆H₁₈N₄*H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide; In water; at 160.0℃; for 96h;Autoclave;	The preparation of complex 2 was similar to that of complex1 except that 3,4-bpdc (0.5 mmol) was used in place of 2,2-bpdc. Colorless crystals of 2 were obtained. Anal. Calcd. forC44H36Cd2N4O9 : C:53.40; H. 3.67; N, 5.66. Found: C, 53.42;H,3.68; N, 5.65. IR/cm-1 (KBr): 1626 s, 1534 s, 1472 m, 1301 m,1255 m, 1136 m, 1082 m, 937 m, 846 m, 705 m, 642 m.

References: [1]Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry,2014,vol. 44,p. 498 - 502.

28
[ 82410-79-5 ]
zinc nitrate tetrahydrate [ No CAS ]
[ 121-91-5 ]
[Zn(1,3-benzenedicarboxylate)(1,4-bis(2-methyl-1H-imidazol-1-ylmethyl)benzene)_0.5]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide; In water; at 160.0℃; for 96h;High pressure;	The mixture of Zn(NO3)2·4H2O (0.198 g, 1 mmol), H2BDC (0.166 g, 1 mmol),NaOH (0.08 g, 2 mmol), bmib (0.266 g,1 mmol) and distillated water (15 mL) washeated to 160 C for 96 h in a 25-mL stainless steel reactor with a Teflonliner. Colorless block crystals of 1 were obtained. Elemental Anal. Calcd.(%)for C16H13ZnN2O4: C, 52.99; H, 3.61;N, 7.72. Found: C,52.97; H, 3.60; N, 7.74.IR: 1631 s, 1422 s, 1355 m, 1278 s,1197 w, 1007 m, 958 w, 869 w, 746 m.

References: [1]Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry,2014,vol. 44,p. 1154 - 1157.

29
[ 82410-79-5 ]
[ 652-36-8 ]
2C₈HF₄O₄^(1-)*C₁₆H₂₀N₄⁽²⁺⁾ [ No CAS ]

References: [1]CrystEngComm,2014,vol. 16,p. 4142 - 4161.

30
[ 82410-79-5 ]
[ 110-94-1 ]
aqueous cadmium chloride [ No CAS ]
[Cd₂(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)(glutarate)₂]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
46%	With sodium hydroxide; In ethanol; at 110.0℃; for 72h;pH 7.0;Autoclave;	General procedure: A solution of H2fum (0.2 mmol) or H2glu (0.2 mmol) in 5 mL H2O was adjusted to pH7 with dilute NaOH. Then bix (0.2 mmol) in 5 mL EtOH and CdCl2·2.5H2O (0.2 mmol) in 5 mL H2O were added. The mixture was added to a 30 mL Teflon-lined stainless autoclave and this was sealed and heated to 110C for 3days and then cooled to room temperature to give the colorless crystals 1 in 38% yield based on Cd(II) (0.036 g) or 2 in 46% yield based on Cd(II) (0.035 g). Anal. calcd. for C36H39Cd2Cl2N8O4.50 (1) C, 45.45; H, 4.13; N, 11.78. Found: C, 45.39%; H, 4.08%; N, 11.74%. Anal. calcd. for C26H30Cd2N4O8 (2) C, 41.56; H, 4.02; N, 7.46. Found: C, 41.53%; H, 3.97%; N,7.44 %.

References: [1]Inorganic Chemistry Communications,2014,vol. 46,p. 24 - 28.

31
[ 82410-79-5 ]
aqueous cadmium chloride [ No CAS ]
[ 7732-18-5 ]
[ 6915-18-0 ]
[Cd₂(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)₂(fumarate)Cl₂]*0.5H₂O}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
38%	With sodium hydroxide; In ethanol; at 110.0℃; for 72h;pH 7.0;Autoclave;	General procedure: A solution of H2fum (0.2 mmol) or H2glu (0.2 mmol) in 5 mL H2O was adjusted to pH7 with dilute NaOH. Then bix (0.2 mmol) in 5 mL EtOH and CdCl2·2.5H2O (0.2 mmol) in 5 mL H2O were added. The mixture was added to a 30 mL Teflon-lined stainless autoclave and this was sealed and heated to 110C for 3days and then cooled to room temperature to give the colorless crystals 1 in 38% yield based on Cd(II) (0.036 g) or 2 in 46% yield based on Cd(II) (0.035 g). Anal. calcd. for C36H39Cd2Cl2N8O4.50 (1) C, 45.45; H, 4.13; N, 11.78. Found: C, 45.39%; H, 4.08%; N, 11.74%. Anal. calcd. for C26H30Cd2N4O8 (2) C, 41.56; H, 4.02; N, 7.46. Found: C, 41.53%; H, 3.97%; N,7.44 %.

References: [1]Inorganic Chemistry Communications,2014,vol. 46,p. 24 - 28.

32
[ 82410-79-5 ]
cobalt(II) chloride hexahydrate [ No CAS ]
[ 92152-01-7 ]
[ 7732-18-5 ]
[(4,4′-bis(2-methylimidazol-1-ylmethyl)benzene)(biphenyl-3,4′-dicarboxylato)cobalt]_n·H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
76%	With sodium hydroxide; at 170.0℃; for 72h;Autoclave;	The synthesis is performed in a 25-mLTeflon-lined stainless steel vessel. A mixture of H2bpda (0.20 mmol, 0.052 g), bmib (0.22mmol, 0.060 g), cobalt chloride hexahydrate (0.20 mmol, 0.048 g), NaOH (0.30mmol,0.012 g), and 10 mL H2O was heated to 170 C for 3 days, followed by slow cooling (a descent rate of 10 C/h) to room temperature, giving purple block crystals.

References: [1]Journal of Coordination Chemistry,2013,vol. 66,p. 763 - 771.

33
[ 82410-79-5 ]
nickel(II) chloride hexahydrate [ No CAS ]
[ 92152-01-7 ]
[(4,4′-bis(2-methylimidazol-1-ylmethyl)benzene)(biphenyl-3,4′-dicarboxylato)nickel]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	With sodium hydroxide; In water; at 170.0℃; for 72h;Autoclave;	The synthesis is also performed in a 25-mL Teflon-lined stainless steel vessel. A mixture of H2bpda (0.20 mmol, 0.052 g), bmib (0.22mmol, 0.060 g), nickel chloride hexahydrate (0.20 mmol, 0.048 g), NaOH (0.40mmol,0.016 g), and 10 mL H2O was heated to 170 C for 3 days, followed by slow cooling (a descent rate of 10 C/h) to room temperature, giving green block crystals.

References: [1]Journal of Coordination Chemistry,2013,vol. 66,p. 763 - 771.

34
[ 82410-79-5 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[ 6915-18-0 ]
[Zn(fumarate)(1,4-bis(2-methylimidazol-1-ylmethyl)benzene)_0.5]·0.5H₂O}_n [ No CAS ]

References: [1]Crystal Growth and Design,2014,vol. 14,p. 1047 - 1056.

35
[ 82410-79-5 ]
manganese (II) sulfate monohydrate [ No CAS ]
[ 365549-33-3 ]
[ 7732-18-5 ]
[Mn1.5(Oabtc)(H2O)2]·(1,4-bis-(2-methylimidazol-1-ylmethyl)benzene+2H)0.5·H2O}n [ No CAS ]

References: [1]Dalton Transactions,2015,vol. 44,p. 2380 - 2389.

36
[ 82410-79-5 ]
cadmium(II) sulfate octahydrate [ No CAS ]
[ 365549-33-3 ]
[ 7732-18-5 ]
[Cd1.5(O2abtc)]·(1,4-bis-(2-methylimidazol-1-ylmethyl)benzene+2H)0.5·2H2O}n [ No CAS ]

References: [1]Dalton Transactions,2015,vol. 44,p. 2380 - 2389.

37
[ 82410-79-5 ]
[ 632-58-6 ]
C₁₆H₁₈N₄*2C₈H₂Cl₄O₄ [ No CAS ]

References: [1]RSC Advances,2015,vol. 5,p. 10275 - 10289.

38
[ 82410-79-5 ]
potassiumhexacyanoferrate(II) trihydrate [ No CAS ]
copper(II) nitrate trihydrate [ No CAS ]
Cu<SUB>2</SUB>(CN)<SUB>2</SUB>(1,4-bis(2-methylimidazol-1-ylmethyl)benzene) [ No CAS ]

References: [1]RSC Advances,2014,vol. 4,p. 61200 - 61209.

39
[ 82410-79-5 ]
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 1141-38-4 ]
[Cd(1,4-bis((2-methyl-1H-imidazol-1-yl)methyl)benzene)0.5(naphthalene-2,6-dicarboxylate)] [ No CAS ]

References: [1]RSC Advances,2015,vol. 5,p. 16190 - 16198.

40
[ 82410-79-5 ]
4'-((2-carboxyphenoxy)methyl)biphenyl-2-carboxylic acid [ No CAS ]
[ 5743-04-4 ]
C₂₁H₁₄O₅^(2-)*Cd⁽²⁺⁾*C₁₆H₁₈N₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
37%	In ethanol; N,N-dimethyl-formamide; at 120.0℃; for 72h;Autoclave;	General procedure: A mixture of H2L (35mg, 0.1mmol), Cd(CH3COO)2·2H2O (27mg, 0.1mmol), die (16mg, 0.1mmol), DMF (6mL) and ethanol (3mL) was sealed in a Teflon-lined stainless steel autoclave reactor (15mL) and heated at 120C for 3days. Colorless crystals of 1 were obtained in a 24% yield based on Cd(CH3COO)2·2H2O.

References: [1]Polyhedron,2015,vol. 99,p. 156 - 169.

41
[ 82410-79-5 ]
[ 4282-31-9 ]
zinc(II) nitrate hexahydrate [ No CAS ]
[Zn(μ₄-(thiophene-2,5-dicarboxylic acid(-2H)))(μ-(1,4-bis((2-methyl-1H-imidazol-1-yl)methyl)benzene))0.5]n [ No CAS ]

References: [1]Crystal Growth and Design,2015,vol. 15,p. 3201 - 3211.

42
[ 82410-79-5 ]
[ 643074-78-6 ]
[ 5970-45-6 ]
potassium hydroxide [ No CAS ]
[Zn2(μ2-OH)(C11H7O8)(1,4-bis((2-methyl-1H-imidazol-1-yl)methyl)benzene)]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62%	In water; at 120.0℃; for 72h;High pressure; Sealed tube;	General procedure: Synthesis of [Zn2(u2-OH)(boaba)(<strong>[82410-79-5]1,4-bmimb</strong>)]n (1) A mixture of Zn(CH3COO)2·2H2O (10.9 mg, 0.05 mmol), <strong>[82410-79-5]1,4-bmimb</strong> (10.6 mg, 0.035 mmol), H3boaba (13.2 mg, 0.05 mmol), KOH (1.2 M, 0.05 ml), and H2O (1 ml) was sealed in a glass tube, which was heated at 120 C for 3 days and then cooled to room temperature at a rate of 5 C/h. Colorless crystals of 1 were obtained and picked out, washed with acetone, then dried in air. Yield: 62%. Anal. calcd for C27H26Zn2N4O9 (%): C 47.61, H 3.76, N 8.15. Found: C 47.56, H 3.82, N 8.22. IR (KBr): v(cm-1)=3458 (m), 3138 (s), 3030 (s), 2926 (s), 1645 (w), 1622 (w) 1516 (m), 1429 (w), 1344 (m), 1286 (m), 1163 (w), 1076 (m), 1014 (s), 953 (m), 880 (s), 842 (m), 680 (m), 665 (m), 600 (m).

References: [1]Journal of Solid State Chemistry,2016,vol. 238,p. 284 - 290.

43
[ 82410-79-5 ]
[ 110-94-1 ]
cobalt(II) nitrate hexahydrate [ No CAS ]
[Co₂(1,4-bis(2-methylimidazol-1-methyl)benzene)(glutarate)₂]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
53%	With sodium hydroxide; In ethanol; water; at 90.0℃; for 72h;pH 7.0;Autoclave;	General procedure: A solution of H2ndc (0.2mmol) in 8mL H2O was adjusted to pH 7 with dilute NaOH. Then bix (0.2mmol) in 7mL EtOH and Co(NO3)2·6H2O (0.2mmol) in 7mL H2O were added. The mixture was added to a 30mL Teflon-lined stainless autoclave and it was sealed and heated to 90C for 3days, then cooled to room temperature to give red crystals of 1 in 56% yield (0.060g).