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Type HazMat fee for 500 gram (Estimated)
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Limited Quantity USD 15-60
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Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 872-31-1 Chemical Structure| 872-31-1
Chemical Structure| 872-31-1

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Product Citations

Product Citations

Lim, Taeho ; Ryoo, Jeong Yup ; Han, Min Su ;

Abstract: In this study, we developed a simple transition-metal-free borylation reaction of aryl bromides. Bis-boronic acid (BBA), was used, and the borylation reaction was performed using a simple procedure at a mild temperature. Under mild conditions, aryl bromides were converted to arylboronic acids directly without any deprotection steps and purified by conversion to trifluoroborate salts. The functional group tolerance was considerably high. The mechanism study suggested that this borylation reaction proceeds via a radical pathway.

Alternative Products

Product Details of 3-Bromothiophene

CAS No. :872-31-1
Formula : C4H3BrS
M.W : 163.04
SMILES Code : BrC1=CSC=C1
MDL No. :MFCD00005464
InChI Key :XCMISAPCWHTVNG-UHFFFAOYSA-N
Pubchem ID :13383

Safety of 3-Bromothiophene

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H225-H301+H311+H331-H411
Precautionary Statements:P210-P233-P280-P301+P310-P303+P361+P353-P304+P340+P311-P273
Class:3(6.1)
UN#:1992
Packing Group:

Application In Synthesis of 3-Bromothiophene

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 872-31-1 ]
  • Downstream synthetic route of [ 872-31-1 ]

[ 872-31-1 ] Synthesis Path-Upstream   1~7

  • 1
  • [ 872-31-1 ]
  • [ 24430-27-1 ]
References: [1] Patent: WO2019/6025, 2019, A1, . Location in patent: Paragraph 0008.
[2] Journal of Medicinal Chemistry, 2017, vol. 60, # 5, p. 1673 - 1692.
[3] Justus Liebigs Annalen der Chemie, 1934, vol. 512, p. 136,156.
[4] Nippon Kagaku Zasshi, 1957, vol. 78, p. 950,962[5] Chemisches Zentralblatt, 1958, vol. 129, p. 13204.
[6] Patent: US6583138, 2003, B1, .
  • 2
  • [ 872-31-1 ]
  • [ 67-56-1 ]
  • [ 70260-17-2 ]
References: [1] European Journal of Organic Chemistry, 2017, vol. 2017, # 18, p. 2661 - 2668.
  • 3
  • [ 872-31-1 ]
  • [ 544-77-4 ]
  • [ 119269-24-8 ]
References: [1] European Journal of Organic Chemistry, 2015, vol. 2015, # 24, p. 5448 - 5452.
  • 4
  • [ 872-31-1 ]
  • [ 112-82-3 ]
  • [ 119269-24-8 ]
References: [1] Dalton Transactions, 2003, # 24, p. 4762 - 4769.
  • 5
  • [ 872-31-1 ]
  • [ 872-26-4 ]
  • [ 119269-24-8 ]
References: [1] New Journal of Chemistry, 2011, vol. 35, # 3, p. 558 - 567.
[2] Soft Matter, 2012, vol. 8, # 42, p. 10921 - 10931,11.
[3] Chemical Science, 2013, vol. 4, # 8, p. 3317 - 3331.
  • 6
  • [ 60404-24-2 ]
  • [ 872-31-1 ]
  • [ 73882-41-4 ]
  • [ 73882-40-3 ]
References: [1] Journal of Heterocyclic Chemistry, 1980, vol. 17, # 1, p. 171 - 174.
  • 7
  • [ 73882-40-3 ]
  • [ 872-31-1 ]
  • [ 60404-24-2 ]
  • [ 73882-41-4 ]
References: [1] Journal of Heterocyclic Chemistry, 1980, vol. 17, # 1, p. 171 - 174.
 

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