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CAS No. : | 103-29-7 | MDL No. : | MFCD00004796 |
Formula : | C14H14 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | QWUWMCYKGHVNAV-UHFFFAOYSA-N |
M.W : | 182.26 | Pubchem ID : | 7647 |
Synonyms : |
|
Num. heavy atoms : | 14 |
Num. arom. heavy atoms : | 12 |
Fraction Csp3 : | 0.14 |
Num. rotatable bonds : | 3 |
Num. H-bond acceptors : | 0.0 |
Num. H-bond donors : | 0.0 |
Molar Refractivity : | 60.7 |
TPSA : | 0.0 Ų |
GI absorption : | Low |
BBB permeant : | Yes |
P-gp substrate : | No |
CYP1A2 inhibitor : | Yes |
CYP2C19 inhibitor : | Yes |
CYP2C9 inhibitor : | No |
CYP2D6 inhibitor : | Yes |
CYP3A4 inhibitor : | No |
Log Kp (skin permeation) : | -4.01 cm/s |
Log Po/w (iLOGP) : | 2.71 |
Log Po/w (XLOGP3) : | 4.79 |
Log Po/w (WLOGP) : | 3.47 |
Log Po/w (MLOGP) : | 5.32 |
Log Po/w (SILICOS-IT) : | 4.28 |
Consensus Log Po/w : | 4.11 |
Lipinski : | 1.0 |
Ghose : | None |
Veber : | 0.0 |
Egan : | 0.0 |
Muegge : | 2.0 |
Bioavailability Score : | 0.55 |
Log S (ESOL) : | -4.42 |
Solubility : | 0.00687 mg/ml ; 0.0000377 mol/l |
Class : | Moderately soluble |
Log S (Ali) : | -4.52 |
Solubility : | 0.00548 mg/ml ; 0.0000301 mol/l |
Class : | Moderately soluble |
Log S (SILICOS-IT) : | -5.72 |
Solubility : | 0.000345 mg/ml ; 0.00000189 mol/l |
Class : | Moderately soluble |
PAINS : | 0.0 alert |
Brenk : | 0.0 alert |
Leadlikeness : | 2.0 |
Synthetic accessibility : | 1.05 |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P301+P312-P302+P352-P304+P340-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
100% | With hydrogen; cetyltrimethylammonim bromide; potassium carbonate; In propan-1-ol; water; at 60℃; under 825.0830000000001 Torr; | General procedure: The Heck coupling, epoxidation and tandem reactions were performed in a double-walled, stirred glass reactor with a reflux condenser. The hydrogenation reactions were performed in 100 mL of methanol or an aqueous microemulsion at an 800rpm stirring rate and 1.1×105Pa H2 in a stirred tank reactor. The cumulative hydrogen consumption and the pressure during the reaction were measured using a Bronkhorst flow meter and pressure controller (Bronkhorst Maettig GmbH, Kamen/Germany) and recorded on a PC. From these results the substrate concentration csubstrate and the conversion X were calculated. All reactions were conducted in one phase aqueous microemulsions, consisting of 1.510g CTAB as the surfactant (5.235 mmol, 3.3 wt.%), 3.020 g 1-propanol (50.250 mmol, 6.6 wt.%) as the cosurfactant, 40.855 g of H2O (2269.722 mmol, 89.3 wt.%) and reactants (2.84 mmol, 0.8 wt.%). For Heck coupling, 1.34 mmol alkene and 1.50 mmol aryl halide were dissolved in a 46 mL microemulsion with 0.276g K2CO3 (2.00 mmol) as the base. For epoxidation, 0.2415 g trans-<strong>[103-30-0]stilben</strong>e (1.34 mmol) and 0.34 g H2O2 (10 mmol) or 0.573 g NaIO4 (2.68 mmol) as the oxidizing agent were added to the 46 mL microemulsion. The hydrogenation reaction was carried out with 0.483 g of trans-<strong>[103-30-0]stilben</strong>e (2.368 mmol). |
>= 99% | With C40H56N2RuSi4; hydrogen; In toluene; at 25℃; under 760.051 Torr; for 6h;Schlenk technique; | A magnetic stirrer was placed in a 20 mE Schlenk tubeand the tube was dried by heating under a reduced pressureof 5 Pa, after which the tube interior was purged with argon. Ruthenium Complex C (2.3 mg, 0.003 mmol) was added as the catalyst to this Schlenk tube and dissolved in toluene (2 mE). To this solution was added trans-<strong>[103-30-0]stilben</strong>e (180 mg, 1.0 mmol). The resulting solution was freeze-pump-thawdegassed, the interior of the Schlenk tube was purged with hydrogen, and the solution was stirred at room temperature for 6 hours. Anisole was added as an internal reference, the ?H-NMR spectrum was measured, and the structure and yield of the product were determined. The structure of the resulting compound was confirmed from the ?H and ?3C- NMR spectra. These results are shown as Entry 5 in Table6.?H-NMR (400 MHz, CDC13) oe=2.93 (s, 4H, CH2), 7.12- 7.23 (m, 6H, C6H5), 7.24-7.32 (m, 4H, C6H5).?3C-NMR (100 MHz, CDC13) oe=37.9, 125.9, 128.3, 128.5, 141.8. |
> 99% | With C40H56FeN2Si4(2-); hydrogen; In 1,2-dimethoxyethane; at 80℃; under 7600.51 Torr; for 2h;Schlenk technique; Autoclave; | A 20-mL Schlenk tube equipped with a magnetic stirrer was heat dried while pumping to a vacuum of 5 Pa before its interior was purged with argon atmosphere. Into the Schlenk tube, iron complex A (7.3 mg, 0.01 mmol) was admitted as catalyst and dissolved in dimethoxyethane (2 mL). To the solution, trans-<strong>[103-30-0]stilben</strong>e (180 mg, 1.0 mmol) was added. The solution was transferred into an autoclave, whose interior was purged with hydrogen. In a hydrogen atmosphere of 10 atm., the solution was stirred at 80 C. for 2 hours. With anisole (108 mg, 1.0 mmol) added as internal standard, the geometry and yield of the product were determined by 1H-NMR spectroscopy. The resulting compound was identified for geometry by 1H and 13C-NMR spectroscopy. The results are shown as Entry 2 in Table 4. H-NMR (CDCl3, 400 MHz) delta=2.93 (s, 4H, CH2), 7.12-7.23 (m, 6H, C6H5), 7.24-7.32 (m, 4H, C6H5) C-NMR (CDCl3, 100 MHz) delta=37.9, 125.9, 128.3, 128.5, 141.8 |
96% | With hydrogen; In tetrahydrofuran; at 20℃; under 760.051 Torr; for 7h; | General procedure: A solution of the substrate (1.00 mmol) in anhydrous THF (15 ml) was transferred into a two-neck round bottom flask containing the purified catalyst (1 g). Reactions were carried out by stirring under atmospheric pressure of H2 at room temperature. The reaction mixture was filtered and the filtrate was evaporated under vacuo. The products were obtained pure. The extent of conversion of the alkenes was determined by 1H NMR spectroscopy. |
95% | With hydrogen; In ethanol; at 20℃; under 760.051 Torr; for 1.5h; | General procedure: In a typical reaction, 0.015 g of catalyst and 2 mmol of the reactant were taken in 10 mL of ethanol under hydrogen atmosphere. The reaction was monitored by thin-layer chromatography (TLC). After complete disappearance of the starting material, the catalyst was separated by simple filtration and the solvent was removed under reduced pressure to obtain the pure product. |
95% | With bis(2-hydroxyethyl)ammonium formate; palladium dichloride; at 20℃; for 24h;Inert atmosphere; | To a solution of nitrobenzene (9) (123 mg, 1.00 mmol) in [BHEA][HCO2] (5.00 mL, 39.7 mmol)was added PdCl2 (1.80 mg, 1.00 mol %) at rt and the reaction mixture was stirred at the same temperature for 12 h under argon atmosphere. The mixture was poured into brine (10 mL) and extracted with EtOAc (10 10 mL). The organic layer was washed with brine (150 mL) and dried with MgSO4. To a solution was added acetic anhydride (2.84 mL, 30 mmol) at rt and the reaction mixturewas stirred at the same temperature for 30 min under argon atmosphere. The mixture was washed with a saturated solution of sodium carbonate (80 mL), brine (150 mL), and dried with MgSO4. After removal of the solvent, the residue was subjected to column chromatography (Merck Kieselgel 60, Phi=2.0 cm, l=11.5 cm; EtOAc-hexane, 1:3) to give acetanilide (22); yield: 130 mg (96%). |
95% | With C22H34FeO2Si4; hydrogen; In toluene; at 20℃; for 6h;Inert atmosphere; Schlenk technique; | A magnetic stirrer was added to a 20 mL shrink tube and heated and dried under reduced pressure to 5 Pa. Then, the inside of the shrink tube was filled with argonIt replaced the crisis. The iron complex A (25 mg, 0.05 mmol) was added as a catalyst to the Schlenk tube, and toluene (2 mL) was added. To this solution was added trans-<strong>[103-30-0]stilben</strong>e (180 mg, 1.0 mmol). The obtained solution was subjected to freeze-thawing,After replacing the inside with a hydrogen atmosphere, the solution was stirred at room temperature for 6 hours. Applying anisole as an internal standard,OneH-NMRThe spectrum was measured to determine the structure and yield of the product. The solvent was distilled off under reduced pressure to obtain a solid. The crude product was purified by silica gel column chromatography using high heptane as a developing solvent to obtain 173 mg (0.95 mmol, 95%). The obtained compoundOneH,13Its structure was confirmed by C-NMR spectrum. The results of these are shown in entry 2As shown in Table 4. |
95% | With hydrogen; In methanol; at 30℃; under 760.051 Torr; | General procedure: In a 25 mL round bottom flask equipped with Teflon coated magnetic needle, olefin (1 equiv.) was dissolved in 4 mL of methanol. Then, H2 was introduced in the flask followed by flushing it twice and the resulting mixture was stirred at room temperature under H2 atmosphere for 15 h. The solvent was then evaporated under reduced pressure and water (5 mL) was added to the residue to dissolve inorganic impurities.The product was then extracted using ethyl acetate (3 × 5 mL). The organic layer was dried over sodium sulphate and the solvent was evaporated under reduced pressure. The mixture was purified using column chromatography on silica gel (Petroleum ether/Ethyl acetate). |
93% | With water; palladium diacetate; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; In dichloromethane; at 25℃; for 12h;Schlenk technique; Inert atmosphere; | Replace the gas environment in the Shrek tube with a nitrogen environment, add cis 1,2-diphenylethylene 0.25 mmol, palladium acetate 0.00125 mmol, methylene chloride 0.5 mL, methanol 0.275 mmol, add pinacol borane with stirring 0.275mmol, reaction at room temperature for 12h. After completion of the reaction, the obtained reaction solution was subjected to column chromatography. The target product obtained in 97% yield was a white solid; Trans 1,2-diphenylethylene 0.25 mmol, palladium acetate 0.00125 mmol, dichloromethane 0.5 mL, water 0.275 mmol, pinacol borane 0.275 mmol was added under stirring, and the reaction was carried out at room temperature for 12 h. The reaction solution was subjected to column chromatography, and the target product obtained in 93% yield was a white solid. |
92% | With silica supported bromine; In ethyl acetate; for 0.333333h; | A stir-bar, trans-<strong>[103-30-0]stilben</strong>e 1 (0.450 g;2.5 mmol) and ethyl acetate (15 mL) were placed into a 50-mL round bottom flask. A PTFE vial containing bromine adsorbed on silica was inserted (0.20 mL; 4.0 mmol of bromine; 1.0 g of silica) into the vapour phase above the solution. After 20 min the solid product was collected by vacuum filtration. meso-Dibromo<strong>[103-30-0]stilben</strong>e 2 (0.782 g) wasisolated in 92% yield. The melting point was 237-237.5 C (dec.) (lit.25237-239 C). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
60%; Ca. 10% | To a stirring solution of <strong>[1131-40-4]1-bromo-2,4,6-trimethoxybenzene</strong> 8 (0.32 g, 1.29 mmol) in anhydrous THF (4 mL) at -78 C, n-BuLi (1.00 mL, 1.40 M, 1.40 mmol) was added dropwise over 1 min and stirring was continued until a white precipitate formed (ca. 10-15 min). To this mixture, a solution of ZnCl2 (1.40 mL, 1.00 M in THF, 1.40 mmol), was added dropwise and the resulting clear, colourless solution was stirred at -78 C for 15 min and then slowly warmed to 0 C over 30 min. Neat BnBr (100 muL, 0.84 mmol) was added at 0 C, followed immediately by solid Pd(PPh3)2Cl2 (6 mg, 1 mol %) and the resulting mixture was warmed to 70 C and stirred for 20 h. The mixture was cooled to room temperature and dilute HCl (2 M, 10 mL) was added, followed by CH2Cl2 (20 mL) and the mixture was rapidly stirred for 10 min. The phases were then separated and the aqueous phase was extracted with CH2Cl2 (2×10 mL). The combined organics were dried (Na2SO4), filtered and concentrated in vacuo. Purification of the yellow residue by silica gel chromatography (CH2Cl2/hexanes 1:1) provided 131 mg (60%) of the title compound as a white powdery solid. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
61%; Ca. 10% | General procedure: To a stirring solution of <strong>[1131-40-4]1-bromo-2,4,6-trimethoxybenzene</strong> 8 (0.32 g, 1.29 mmol) in anhydrous THF (4 mL) at -78 C, n-BuLi (1.00 mL, 1.40 M, 1.40 mmol) was added dropwise over 1 min and stirring was continued until a white precipitate formed (ca. 10-15 min). To this mixture, a solution of ZnCl2 (1.40 mL, 1.00 M in THF, 1.40 mmol), was added dropwise and the resulting clear, colourless solution was stirred at -78 C for 15 min and then slowly warmed to 0 C over 30 min. Neat BnBr (100 muL, 0.84 mmol) was added at 0 C, followed immediately by solid Pd(PPh3)2Cl2 (6 mg, 1 mol %) and the resulting mixture was warmed to 70 C and stirred for 20 h. The mixture was cooled to room temperature and dilute HCl (2 M, 10 mL) was added, followed by CH2Cl2 (20 mL) and the mixture was rapidly stirred for 10 min. The phases were then separated and the aqueous phase was extracted with CH2Cl2 (2×10 mL). The combined organics were dried (Na2SO4), filtered and concentrated in vacuo. Purification of the yellow residue by silica gel chromatography (CH2Cl2/hexanes 1:1) provided 131 mg (60%) of the title compound as a white powdery solid. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
91%Chromat. | With FeCl(THF)L1; In diethyl ether; at 20℃; for 0.5h;Schlenk technique; Inert atmosphere;Catalytic behavior; | General procedure: [00283] Catalyst 20 (0.10 mmol) in CH2C12 (3 mL) was added to a 30 mL Schlenk flask and the solvent removed in vacuo. Et20 (5 mL) and the alkyl halide (2.0 mmol) were added to the catalyst under dry nitrogen. A solution of Grignard reagent (4.0 mmol) was added dropwise under vigorous stirring. The resulting mixture was stirred at roomtemperature for 30 min and the reaction was quenched with HC1 (2.0 M, 5 mL). The organic phase was extracted with Et20 (5 mL) and dried over MgSC>4. The organic phase was then passed through a plug of silica and the diethyl ether was removed in vacuo. The resulting products were then analyzed by GC-MS (using dodecane as internal standard) and NMR spectroscopy (using acetophenone as internal standard). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
49%Chromat. | With FeCl(THF)L1; In diethyl ether; at 20℃; for 0.5h;Schlenk technique; Inert atmosphere;Catalytic behavior; | General procedure: [00283] Catalyst 20 (0.10 mmol) in CH2C12 (3 mL) was added to a 30 mL Schlenk flask and the solvent removed in vacuo. Et20 (5 mL) and the alkyl halide (2.0 mmol) were added to the catalyst under dry nitrogen. A solution of Grignard reagent (4.0 mmol) was added dropwise under vigorous stirring. The resulting mixture was stirred at roomtemperature for 30 min and the reaction was quenched with HC1 (2.0 M, 5 mL). The organic phase was extracted with Et20 (5 mL) and dried over MgSC>4. The organic phase was then passed through a plug of silica and the diethyl ether was removed in vacuo. The resulting products were then analyzed by GC-MS (using dodecane as internal standard) and NMR spectroscopy (using acetophenone as internal standard). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hydrogen; In Hexadecane; at 250℃; under 7500.75 Torr; for 3h;Autoclave; | General procedure: etherCatalytic decomposition of phenethyl phenyl ether (PPE) to aro-matics was carried out in a stainless steel autoclave reactor (25 mL)under hydrogen atmosphere. Prior to the reaction, each catalystwas reduced using an ex-situ reduction system at 450C for 4 hunder 5% H2/N2flow (50 mL/min). 50 mg of reduced catalyst, 0.25 gof phenethyl phenyl ether (Frinton Laboratory, a reactant), and 9 mLof hexadecane (Sigma-Aldrich, a solvent) were charged into thereactor at room temperature. The reactor was purged with nitro-gen several times in order to remove air. The catalytic reaction wasperformed at 250C and 10 bar (H2) for 3 h with agitation speed of250 rpm. After the reaction, reaction products were analyzed usinga gas chromatograph (Younglin, YL6100) equipped with a DB-1 col-umn and a flame ionization detector (FID). Conversion of phenethylphenyl ether and selectivity for aromatic product (benzene, phe-nol, or ethylbenzene) were calculated according to the followingequations on the basis of mole balance. Yield for aromatic product(benzene, phenol, or ethylbenzene) was calculated by multiplyingconversion of phenethyl phenyl ether and corresponding productselectivity |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hydrogen; In Hexadecane; at 250℃; under 7500.75 Torr; for 3h;Autoclave; | General procedure: etherCatalytic decomposition of phenethyl phenyl ether (PPE) to aro-matics was carried out in a stainless steel autoclave reactor (25 mL)under hydrogen atmosphere. Prior to the reaction, each catalystwas reduced using an ex-situ reduction system at 450C for 4 hunder 5% H2/N2flow (50 mL/min). 50 mg of reduced catalyst, 0.25 gof phenethyl phenyl ether (Frinton Laboratory, a reactant), and 9 mLof hexadecane (Sigma-Aldrich, a solvent) were charged into thereactor at room temperature. The reactor was purged with nitro-gen several times in order to remove air. The catalytic reaction wasperformed at 250C and 10 bar (H2) for 3 h with agitation speed of250 rpm. After the reaction, reaction products were analyzed usinga gas chromatograph (Younglin, YL6100) equipped with a DB-1 col-umn and a flame ionization detector (FID). Conversion of phenethylphenyl ether and selectivity for aromatic product (benzene, phe-nol, or ethylbenzene) were calculated according to the followingequations on the basis of mole balance. Yield for aromatic product(benzene, phenol, or ethylbenzene) was calculated by multiplyingconversion of phenethyl phenyl ether and corresponding productselectivity |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
67% | With magnesium; In neat (no solvent); at 110℃; for 6h; | General procedure: A mixture of MeSi(OEt)3 (445 g, 2.5 mol) and BnCl (126.5 g, 1 mol) was added to Mg (36 g, 1.5 mol) with reflux and stirred for 6 h at 150 C. After addition of toluene (600 mL), the mixture was filtered, toluene and MeSi(OEt)3 were evaporated. The product was isolated by distillation in vacuo. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
33% | General procedure: Arylboronic acid (0.5 mmol), KF (1.0 mmol) were added to a Schlenk tube. The tube was charged with nitrogen and then DCE (2 mL) and benzyl esters (0.75 mmol) were added. The mixture was stirred at 70 C for 10-24 h. After the mixture was cooled down to room temperature, solvent was removed to give a crude product, which was purified by column chromatography on silica gel, eluted with petroleum ether or petroleum ether:ethyl acetate 30:1 to afford the product. In some cases, the reaction was carried out at 100 C with LiOtBu as the base, as indicated in Scheme 4. | |
33% | With lithium tert-butoxide; at 100℃; for 24h;Sealed tube; | To a 10 mL reaction tube equipped with a magnet was added phenylboronic acid (122 mg, 1.0 mmol)Lithium tert-butoxide (80 mg, 1.0 mmol).Dichloroethane (2 mL)And <strong>[20020-27-3]phenethyl methanesulfonate</strong> (100 mg, 0.75 mmol).Stuffed rubber stopper,The reaction was performed on a 100 C electromagnetic heating stirrer for about 24 hours.After the reaction,Cool to room temperature,The organic solvent is removed using a rotary evaporator,And purified by column chromatography to give 1,2-diphenylethylene (30 mg, 33%).The compound is a white solid, |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
at 10 - 20℃;Inert atmosphere; Reflux; Electric arc; | General procedure: 1 A 250 mL three-necked flask was charged with a magnetic stirrer and 30 mL of chlorobenzene was added,Then connect the reaction device as shown in Figure 1.2 reaction device placed in an oil bath, the reaction system was purged with inert gas,Exclude the air in the reaction system, and then open the oil bath and stir to reflux chlorobenzene,At the same time the ball condenser cooling water.3) Open the high-voltage power generator, the resulting strong arc through the metal electrode into the three-necked flask,Chlorobenzene vapor is ionized to form a biphenyl mixture.4) the coupling product is continuously enriched into the flask, stop the ionization and heating when the chlorobenzene reflux slows down,Stop the reaction.The above ionization products were detected by GC / MS, and the products contained biphenyl, 2-chlorobiphenyl,4-chlorobiphenyl and other coupling products. |
Tags: 103-29-7 synthesis path| 103-29-7 SDS| 103-29-7 COA| 103-29-7 purity| 103-29-7 application| 103-29-7 NMR| 103-29-7 COA| 103-29-7 structure
[ 1680-51-9 ]
6-Methyl-1,2,3,4-tetrahydronaphthalene
Similarity: 0.94
[ 824-22-6 ]
4-Methyl-2,3-dihydro-1H-indene
Similarity: 0.94
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P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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