Alternatived Products of [ 5932-68-3 ]
Product Details of [ 5932-68-3 ]
CAS No. : | 5932-68-3 |
MDL No. : | MFCD00009285 |
Formula : |
C10H12O2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
164.20
|
Pubchem ID : | - |
Synonyms : |
|
Application In Synthesis of [ 5932-68-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 5932-68-3 ]
- Downstream synthetic route of [ 5932-68-3 ]
- 1
-
[ 574-84-5 ]
-
[ 5932-68-3 ]
-
propacin
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
87.2% |
With Na,K-phosphate buffer; dihydrogen peroxide; horseradish peroxidase at 37℃; for 336h; |
|
10.8% |
With 2,3-dicyano-5,6-dichloro-p-benzoquinone for 28h; Ambient temperature; |
|
Reference:
[1]Lin, Lee-Juian; Cordell, Geoffrey A.
[Journal of Chemical Research, Miniprint, 1988, # 12, p. 3052 - 3080]
[2]Lin, Lee-Juian; Cordell, Geoffrey A.
[Journal of the Chemical Society. Chemical communications, 1984, # 3, p. 160 - 161]
- 2
-
[ 5932-68-3 ]
-
[ 59893-87-7 ]
-
[ 89067-52-7 ]
- 3
-
[ 574-84-5 ]
-
[ 5932-68-3 ]
-
compound-B
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
10.8% |
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,4-dioxane for 28h; Ambient temperature; |
|
- 4
-
[ 5932-68-3 ]
-
[ 486-35-1 ]
-
(2R,3R)-2-(4-Hydroxy-3-methoxy-phenyl)-3-methyl-2,3-dihydro-1,4,5-trioxa-phenanthren-6-one
[ No CAS ]
- 5
-
forest plant material
[ No CAS ]
-
[ 97-53-0 ]
-
[ 5912-86-7 ]
-
[ 7786-61-0 ]
-
[ 5932-68-3 ]
- 6
-
[ 5932-68-3 ]
-
[ 2785-87-7 ]
Yield | Reaction Conditions | Operation in experiment |
90% |
With hydrogen In methanol at 40℃; for 24h; |
|
93.9 %Chromat. |
With 5% active carbon-supported ruthenium; ethylene glycol at 185℃; for 0.5h; |
|
Reference:
[1]Ruffin, Brigitte; Grelier, Stephane; Nourmamode, Aziz; Castellan, Alain
[Canadian Journal of Chemistry, 2002, vol. 80, # 9, p. 1223 - 1231]
[2]Ren, Tianyu; You, Shengping; Zhang, Zhaofeng; Wang, Yuefei; Qi, Wei; Su, Rongxin; He, Zhimin
[Green Chemistry, 2021, vol. 23, # 4, p. 1648 - 1657]
- 7
-
[ 5932-68-3 ]
-
[ 5912-87-8 ]
Yield | Reaction Conditions | Operation in experiment |
|
With acetic anhydride In pyridine; ice-water |
3.a Step (a):
Step (a): Preparation of Acetyl Isoeugenol To a solution of isoeugenol (344 g., 2.1 moles) in 420 ml. of pyridine under nitrogen atmosphere is added 428 ml. of acetic anhydride over a period of 30 minutes. The resulting solution is stirred at room temperature overnight followed by treatment with ice-water (1400 ml.). After stirring for three hours, the resulting precipitate is filtered, washed with water (3*500 ml.) and dried in vacuo to give 381.7 g. of crude product. |
- 8
-
[ 97-53-0 ]
-
[ 13444-93-4 ]
-
[ 5912-86-7 ]
-
[ 5932-68-3 ]
Yield | Reaction Conditions | Operation in experiment |
85.2% |
|
16 EXAMPLE 16
EXAMPLE 16 A mixture of 73 g. of eugenol and 5.7 mg. of osmium trichloride is brought for 4 hours 25 minutes to 130° C. After distillation, 65.2 g. of a mixture, containing (as measured by gas-liquid chromatography) 13.8% of eugenol, 6.8% of cis-isoeugenol and 79.4% of trans-isoeugenol are obtained. The conversion rate is 88% and the yield is 85.2%, based on the converted eugenol. |
- 9
-
[ 50-00-0 ]
-
[ 5405-15-2 ]
-
[ 5932-68-3 ]
-
trans-N-benzyl-3,6-dimethyl-4-(4-hydroxy-3-methoxyphenyl)-1,2,3,4-tetrahydroquinoline
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
76% |
Stage #1: formaldehyd; N-benzyl-N-(4-methylphenyl)amine In methanol; acetonitrile at 20℃; for 0.166667h;
Stage #2: With boron trifluoride diethyl etherate In methanol; acetonitrile at 0℃; for 0.5h;
Stage #3: (E)-2-methoxy-4-(1-propenyl)phenol In methanol; acetonitrile at 70℃; for 8h; |
|
- 10
-
[ 5932-68-3 ]
-
[ 114046-25-2 ]
-
[ 1381866-24-5 ]
- 11
-
lignin, softwood Kraft black liquor
[ No CAS ]
-
[ 95-87-4 ]
-
[ 6380-23-0 ]
-
[ 106-44-5 ]
-
[ 620-17-7 ]
-
[ 93-51-6 ]
-
[ 2785-87-7 ]
-
[ 4463-33-6 ]
-
[ 3209-13-0 ]
-
[ 2896-67-5 ]
-
[ 7786-61-0 ]
-
[ 2785-89-9 ]
-
[ 24599-58-4 ]
-
[ 5932-68-3 ]
-
[ 2503-46-0 ]
-
[ 14059-92-8 ]
-
[ 121-33-5 ]
-
[ 95-48-7 ]
-
[ 90-05-1 ]
-
[ 498-02-2 ]
-
[ 108-95-2 ]
- 12
-
[ 5932-68-3 ]
-
[ 5912-87-8 ]
-
C18H18O5
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride at 90℃; for 0.5h; Inert atmosphere; |
3 Example 3: Compound 5
Isoeugenol (1.0 g, 6.1 mmol, 1 equiv.) and isoeugenyl acetate (1.3 g, 6.1 mmol 1 equiv.) are introduced into a round-bottomed flask. The Grubbs catalyst (2’ generation, 5mg, 0.006 mmol, 0.00 1 equiv.) is added at ambient temperature. The reaction mixture is thenstirred at 90°C under an argon stream for 30 minutes. During the reaction, solidification isobserved.After purification of the reaction crude dissolved in acetone, by preparative thin layer chromatography on a silica support, compound 5 is isolated in the form of a white powder. The ‘H NMR spectrum complies with the expected structure. |
- 13
-
[ 97-53-0 ]
-
[ 2785-87-7 ]
-
[ 5932-68-3 ]
Yield | Reaction Conditions | Operation in experiment |
1: 74%
2: 25% |
With Fe3Co7; hydrogen In dodecane at 250℃; for 8h; Autoclave; |
|
|
With palladium nanoparticles-decorated TiO2 In methanol at 20℃; for 42h; UV-irradiation; Inert atmosphere; |
|
Reference:
[1]Liu, Xiaohao; Wang, Chenguang; Zhang, Ying; Qiao, Yan; Pan, Yang; Ma, Longlong
[ChemSusChem, 2019, vol. 12, # 21, p. 4791 - 4798]
[2]Elhage, Ayda; Lanterna, Anabel E.; Scaiano, Juan C.
[ACS Catalysis, 2017, vol. 7, # 1, p. 250 - 255]