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Chemical Structure| 7635-54-3 Chemical Structure| 7635-54-3

Structure of (1S)-(+)-Menthyl chloroformate
CAS No.: 7635-54-3

Chemical Structure| 7635-54-3

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Product Details of [ 7635-54-3 ]

CAS No. :7635-54-3
Formula : C11H19ClO2
M.W : 218.72
SMILES Code : O=C(Cl)O[C@@H]1[C@@H](C(C)C)CC[C@H](C)C1
MDL No. :MFCD00134483
InChI Key :KIUPCUCGVCGPPA-AEJSXWLSSA-N
Pubchem ID :2733329

Safety of [ 7635-54-3 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314-H331
Precautionary Statements:P261-P280-P305+P351+P338-P310
Class:6.1(8)
UN#:3277
Packing Group:

Application In Synthesis of [ 7635-54-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 7635-54-3 ]

[ 7635-54-3 ] Synthesis Path-Downstream   1~35

  • 1
  • [ 135-16-0 ]
  • [ 7635-54-3 ]
  • (S)-2-(4-[2-Amino-5-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyl)-4-oxo-3,4,5,6,7,8-hexahydro-pteridin-6-ylmethyl]-amino}-benzoylamino)-pentanedioic acid [ No CAS ]
  • 2
  • [ 620-08-6 ]
  • [ 7635-54-3 ]
  • 1-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxycarbonyl)-4-methoxy-pyridinium; chloride [ No CAS ]
  • 4
  • [ 22191-05-5 ]
  • [ 7635-54-3 ]
  • (R)-2-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-hexanedioic acid dimethyl ester [ No CAS ]
  • (S)-2-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-hexanedioic acid dimethyl ester [ No CAS ]
  • 5
  • [ 7635-54-3 ]
  • [ 151-50-8 ]
  • [ 104461-84-9 ]
  • 6
  • [ 7635-54-3 ]
  • [ 78037-99-7 ]
  • (6E,8Z,11Z,14Z)-(S)-5-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-icosa-6,8,11,14-tetraenoic acid methyl ester [ No CAS ]
  • 7
  • [ 7635-54-3 ]
  • [ 112266-45-2 ]
  • 1-((1S,2R,5S)-2-Isopropyl-5-methyl-cyclohexyloxycarbonyl)-4-methoxy-3-trimethylsilanyl-pyridinium; chloride [ No CAS ]
  • 8
  • [ 7635-54-3 ]
  • [ 126378-42-5 ]
  • [ 135365-65-0 ]
  • 9
  • [ 7635-54-3 ]
  • [ 100-47-0 ]
  • N-(r-1,t-2,c-5-2-Isopropyl-5-methylcyclohexyl)benzamide [ No CAS ]
  • N-<1-Methyl-1-(4-methylcyclohexyl)ethyl>benzamide [ No CAS ]
  • 11
  • [ 102555-71-5 ]
  • [ 7635-54-3 ]
  • Thiocarbonic acid O-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester S-[2'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonylsulfanyl)-[1,1']binaphthalenyl-2-yl] ester [ No CAS ]
  • Thiocarbonic acid O-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester S-[2'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonylsulfanyl)-[1,1']binaphthalenyl-2-yl] ester [ No CAS ]
  • 12
  • [ 7635-54-3 ]
  • [ 602-09-5 ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 2'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-[1,1']binaphthalenyl-2-yl ester [ No CAS ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 2'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-[1,1']binaphthalenyl-2-yl ester [ No CAS ]
  • 13
  • [ 7635-54-3 ]
  • [ 156286-12-3 ]
  • C71H19NO2 [ No CAS ]
  • 14
  • [ 7635-54-3 ]
  • [ 57182-15-7 ]
  • (3R,4S)-4-(2,6-Dimethyl-phenylamino)-2,2,5,5-tetramethyl-hexan-3-ol [ No CAS ]
  • 2-(2,6-Dimethyl-phenylamino)-3,3-dimethyl-butyric acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester [ No CAS ]
  • 15
  • [ 7635-54-3 ]
  • (3aR,4R,5R,5aS,8aR,8bR)-5-Benzyloxy-2,2,7,7-tetramethyl-hexahydro-benzo[1,2-d;3,4-d']bis[1,3]dioxol-4-ol [ No CAS ]
  • [ 207131-20-2 ]
  • Carbonic acid (3aS,4R,5S,5aS,8aR,8bS)-5-benzyloxy-2,2,7,7-tetramethyl-hexahydro-benzo[1,2-d;3,4-d']bis[1,3]dioxol-4-yl ester (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester [ No CAS ]
  • 16
  • [ 7635-54-3 ]
  • [ 230309-18-9 ]
  • 3-methoxycarbonyl-4-phenylpiperidine-1-carboxylic acid menthyl ester [ No CAS ]
  • 17
  • [ 5724-81-2 ]
  • [ 7635-54-3 ]
  • 2,3-Dihydro-pyrrole-1-carboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester [ No CAS ]
  • 18
  • [ 32315-10-9 ]
  • [ 15356-60-2 ]
  • [ 7635-54-3 ]
YieldReaction ConditionsOperation in experiment
99% With pyridine; In dichloromethane; at -5 - 25℃; for 13h; General procedure: In a jacketed reactor equipped with a mechanical stirrer, a thermometer, a constant pressure dropping funnel and an exhaust gas absorber,Add 7L dichloromethane, the first reaction phase, temperature -5 C,780 g (5 mol) of L-menthol and 1187 g (4 mol) of triphosgene were added in portions and sufficiently stirred to dissolve them.-5 CDrop under the drop1215 g (12mo 1) triethylamine in methylene chloride (1.8 L) was added dropwise over 1 to 2 h,Insulation reaction 3h after the natural temperature rise to the second reaction stage, temperature control 25 C, stirring about 10h.After completion of the reaction, the reaction mixture was separated by filtration under filtration, and the mother liquor was washed successively with 3 L of water, 3 L of dilute hydrochloric acid (5%), 0.5 L of sodium carbonate (5%) and 0.5 L of saturated brine ,After drying over anhydrous sodium sulfate, the solvent was removed by steaming and distilled under reduced pressure to collect 108 to 109 C / 1 ImmHg fraction,1063 g of a colorless liquid was obtained in a yield of 97.2%.
  • 19
  • [ 7635-54-3 ]
  • [ 121-44-8 ]
  • [ 250716-74-6 ]
  • N,N-diethyl (-)-(1R)-menthyl carbamate [ No CAS ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 8'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-2,2'-dimethyl-[1,1']binaphthalenyl-8-yl ester [ No CAS ]
  • 20
  • [ 110-91-8 ]
  • [ 7635-54-3 ]
  • [ 333-20-0 ]
  • [ 331823-17-7 ]
  • 21
  • [ 7635-54-3 ]
  • [ 333-20-0 ]
  • [ 109-89-7 ]
  • [ 331823-15-5 ]
  • 22
  • [ 7635-54-3 ]
  • [ 494-52-0 ]
  • (2'S)-[(1S,2R,5S)-menthoxycarbonyl]anabasine [ No CAS ]
  • 23
  • [ 7635-54-3 ]
  • [ 13078-04-1 ]
  • (2'S)-[(1S,2R,5S)-menthoxycarbonyl]anabasine [ No CAS ]
  • (2'R)-[(1S,2R,5S)-menthoxycarbonyl]anabasine [ No CAS ]
  • 24
  • [ 7635-54-3 ]
  • [ 1049019-27-3 ]
  • (Z)-(-)-menthyl 5-oxo-2-phenyloxazol-4-methylenecarbonate [ No CAS ]
  • 25
  • [ 7635-54-3 ]
  • [ 259253-00-4 ]
  • Ethanesulfonic acid 5-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonylamino)-1,3-dioxo-1,3-dihydro-isoindol-2-yl ester [ No CAS ]
  • 26
  • [ 7635-54-3 ]
  • cis-2-(hydroxymethyl)-5-(N4-acetylcytosin-1'-yl)-1,3-oxathiolane [ No CAS ]
  • Carbonic acid (2S,5R)-5-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-[1,3]oxathiolan-2-ylmethyl ester (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester [ No CAS ]
  • Carbonic acid (2R,5S)-5-(4-acetylamino-2-oxo-2H-pyrimidin-1-yl)-[1,3]oxathiolan-2-ylmethyl ester (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester [ No CAS ]
  • 27
  • [ 7635-54-3 ]
  • (S)-tert-butyl(methyl)phosphine-borane [ No CAS ]
  • t-butyl[(1S)-menthyloxycarbonyl]methylphosphine-borane [ No CAS ]
  • 28
  • [ 7635-54-3 ]
  • t-butylphosphine-borane [ No CAS ]
  • C26H50BO4P [ No CAS ]
  • 29
  • [ 7635-54-3 ]
  • [ 475273-53-1 ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 3'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-9H,9'H-[4,4']bicarbazolyl-3-yl ester [ No CAS ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 3'-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-9H,9'H-[4,4']bicarbazolyl-3-yl ester [ No CAS ]
  • 30
  • [ 7635-54-3 ]
  • (S)-(S)-1-(Tetrahydro-furan-2-yl)-tridecan-1-ol [ No CAS ]
  • [ 612084-67-0 ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (S)-(R)-1-(tetrahydro-furan-2-yl)-tridecyl ester [ No CAS ]
  • 31
  • [ 7635-54-3 ]
  • [ 849340-81-4 ]
  • (2-Iodo-benzyl)-prop-2-ynyl-carbamic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester [ No CAS ]
  • 32
  • [ 863491-46-7 ]
  • [ 7635-54-3 ]
  • [ 874304-95-7 ]
  • 33
  • [ 863491-46-7 ]
  • [ 7635-54-3 ]
  • 2,6-bis-(1-((1S,2R,5S)-2-isopropyl-5-methylcyclohexyloxycarbonyl)-[4R,5R]-4,5-diphenyl-4,5-dihydro-1H-imidazol-2-yl)-pyridine [ No CAS ]
  • 34
  • 1-((4R,5R)-4,5-dihydro-2-(6-((4R,5R)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl)pyridin-2-yl)-4,5-diphenylimidazol-1-yl)(mesityl)methanone [ No CAS ]
  • [ 7635-54-3 ]
  • 2-(1-(2,4,6-trimethyl-benzoyl)-[4R,5R]-4,5-diphenyl-4,5-dihydro-1H-imidazol-2-yl)-6-(1-((1S,2R,5S)-2-iso-propyl-5-methylcyclohexyl-3-oxycarbonyl)-[4R,5R]-4,5-diphenyl-4,5-dihydro-1H-imidazol-2-yl)pyridine [ No CAS ]
  • 35
  • [ 7635-54-3 ]
  • [ 275822-20-3 ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (1S,2S)-2-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-1,2-bis-(4-methoxy-phenyl)-acenaphthen-1-yl ester [ No CAS ]
  • Carbonic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (1R,2R)-2-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyloxycarbonyloxy)-1,2-bis-(4-methoxy-phenyl)-acenaphthen-1-yl ester [ No CAS ]
 

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