There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
Structure of 12093-10-6
*Storage: {[sel_prStorage]}
*Shipping: {[sel_prShipping]}
The BI-3802 was designed by Boehringer Ingelheim and could be obtained free of charge through the Boehringer Ingelheim open innovation portal opnMe.com, associated with its negative control.
4.5
*For Research Use Only !
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Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
Search for reports by entering the product batch number.
Batch number can be found on the product's label following the word 'Batch'.
CAS No. : | 12093-10-6 |
Formula : | C11H10FeO |
M.W : | 214.04 |
SMILES Code : | O=C[C-]12[CH]3=[CH]4[CH]5=[CH]1[Fe+2]67894532[CH]=%10[CH]9=[CH]8[CH-]7[CH]%106 |
MDL No. : | MFCD00001429 |
GHS Pictogram: |
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Signal Word: | Danger |
Hazard Statements: | H301 |
Precautionary Statements: | P264-P270-P301+P310-P330-P405-P501 |
Class: | 6.1 |
UN#: | 3467 |
Packing Group: | Ⅱ |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With sodium tetrahydroborate; potassium carbonate; In chloroform; for 1.5h;Reflux; Inert atmosphere; Schlenk technique; | General procedure: Ferrocenecarboxaldehyde (856 mg, 4.0 mmol) and amino alcohol(4.2 mmol) were dissolved in previously dried chloroform(40 mL; dried over K2CO3) and the resulting solution was heated at reflux under argon for 90 min. Then, the solution was cooled to room temperature, the solvent was removed under reduced pressure and the red?brown residue immediately re-dissolved indry methanol (40 mL; distilled from a MeONa solution). The methanol\ic solution was cooled in an ice bath and treated slowly with solid NaBH4 (756 mg, 20 mmol over 30 min). After adding all the NaBH4, the mixture was stirred at 0°C for 1 h and at room temperature for further 90 min. Then, the cooled mixture was quenched with an aqueous solution of NaOH (10percent, 40 mL) and extracted withCH2Cl2 (2 40 mL). The combined organic layer was washed withbrine (2 40 mL), dried over anhydrous MgSO4, and evaporated,leaving the crude product as a yellow?brown solid. Subsequentpurification by column chromatography (silica gel, dichloromethane?methanol 10:1) led to the development of two bands: the first(minor) one containing mostly ferrocenyl methanol, followed by the major band of the amino alcohol. Careful evaporation of the second fraction afforded pure ferrocene based amino alcohol as an amber oil, which slowly solidifies to a brown solid. |