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Chemical Structure| 12093-10-6 Chemical Structure| 12093-10-6

Structure of 12093-10-6

Chemical Structure| 12093-10-6

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Product Details of [ 12093-10-6 ]

CAS No. :12093-10-6
Formula : C11H10FeO
M.W : 214.04
SMILES Code : O=C[C-]12[CH]3=[CH]4[CH]5=[CH]1[Fe+2]67894532[CH]=%10[CH]9=[CH]8[CH-]7[CH]%106
MDL No. :MFCD00001429

Safety of [ 12093-10-6 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H301
Precautionary Statements:P264-P270-P301+P310-P330-P405-P501
Class:6.1
UN#:3467
Packing Group:

Application In Synthesis of [ 12093-10-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 12093-10-6 ]

[ 12093-10-6 ] Synthesis Path-Downstream   1~12

  • 3
  • [ 12093-10-6 ]
  • [ 24629-25-2 ]
  • (2S,3S)-2-[(ferrocenylidene)-amino]-3-methyl-pentan-1-ol [ No CAS ]
  • 4
  • [ 1293-65-8 ]
  • [ 112939-59-0 ]
  • [ 12093-10-6 ]
  • 1,1''-biferrocene [ No CAS ]
  • [ 864370-86-5 ]
  • [ 864371-01-7 ]
  • 5
  • [ 12093-10-6 ]
  • [ 784-04-3 ]
  • Anth-Fe [ No CAS ]
  • 6
  • [ 12093-10-6 ]
  • [ 7732-18-5 ]
  • [ 1671-88-1 ]
  • N-4-[3,5-di-(2-pyridyl)-1,2,4-triazoyl]ferrocene carbimine [ No CAS ]
  • 7
  • [ 12093-10-6 ]
  • [ 4506-66-5 ]
  • [ 1204425-72-8 ]
  • 8
  • [ 12093-10-6 ]
  • [ 24629-25-2 ]
  • (2S,3S)-2-[(ferrocenylmethyl)amino]-3-methylpentan-1-ol [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With sodium tetrahydroborate; potassium carbonate; In chloroform; for 1.5h;Reflux; Inert atmosphere; Schlenk technique; General procedure: Ferrocenecarboxaldehyde (856 mg, 4.0 mmol) and amino alcohol(4.2 mmol) were dissolved in previously dried chloroform(40 mL; dried over K2CO3) and the resulting solution was heated at reflux under argon for 90 min. Then, the solution was cooled to room temperature, the solvent was removed under reduced pressure and the red?brown residue immediately re-dissolved indry methanol (40 mL; distilled from a MeONa solution). The methanol\ic solution was cooled in an ice bath and treated slowly with solid NaBH4 (756 mg, 20 mmol over 30 min). After adding all the NaBH4, the mixture was stirred at 0°C for 1 h and at room temperature for further 90 min. Then, the cooled mixture was quenched with an aqueous solution of NaOH (10percent, 40 mL) and extracted withCH2Cl2 (2 40 mL). The combined organic layer was washed withbrine (2 40 mL), dried over anhydrous MgSO4, and evaporated,leaving the crude product as a yellow?brown solid. Subsequentpurification by column chromatography (silica gel, dichloromethane?methanol 10:1) led to the development of two bands: the first(minor) one containing mostly ferrocenyl methanol, followed by the major band of the amino alcohol. Careful evaporation of the second fraction afforded pure ferrocene based amino alcohol as an amber oil, which slowly solidifies to a brown solid.
  • 9
  • [ 12093-10-6 ]
  • [ 4985-46-0 ]
  • C20H22FeN2O2 [ No CAS ]
  • 10
  • [ 12093-10-6 ]
  • [ 1080-12-2 ]
  • (1E,4E)-1-ferrocenyl-5-(4-hydroxy-3-methoxyphenyl)penta-1,4-dien-3-one [ No CAS ]
  • 11
  • [ 12093-10-6 ]
  • [ 1986-47-6 ]
  • C20H19FeN [ No CAS ]
  • 12
  • [ 12093-10-6 ]
  • [ 525-03-1 ]
  • C24H19FeN [ No CAS ]
 

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