2-Ethylpyrazine | Pyrazines

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2-Ethylpyrazine is an endogenous metabolite.

4.5 *For Research Use Only !

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Quality Control of 2-Ethylpyrazine Purity: 98% SDS Specification

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Product Details of 2-Ethylpyrazine

CAS No. :	13925-00-3
Formula :	C₆H₈N₂
M.W :	108.14
SMILES Code :	CCC1=NC=CN=C1
MDL No. :	MFCD00006149
InChI Key :	KVFIJIWMDBAGDP-UHFFFAOYSA-N
Pubchem ID :	26331

Safety of 2-Ethylpyrazine

GHS Pictogram:
Signal Word:	Danger
Hazard Statements:	H225-H302
Precautionary Statements:	P210-P233-P240-P241-P242-P301+P312
Class:	3
UN#:	1993
Packing Group:	Ⅲ

Application In Synthesis of 2-Ethylpyrazine

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 13925-00-3 ]

[ 13925-00-3 ] Synthesis Path-Downstream 1~35

1
[ 13925-00-3 ]
[ 98-97-5 ]

References: [1]Journal of Organic Chemistry,1959,vol. 24,p. 691.
[2]Journal of Chemical Thermodynamics,2005,vol. 37,p. 49 - 53.

2
[ 13961-37-0 ]
[ 13925-00-3 ]

References: [1]Journal of Organic Chemistry,1959,vol. 24,p. 691.

3
[ 110-85-0 ]
[ 290-37-9 ]
[ 109-08-0 ]
[ 13925-00-3 ]
[ 109-97-7 ]

References: [1]Chemistry of Heterocyclic Compounds,1993,vol. 29,p. 1308 - 1315.
    Khimiya Geterotsiklicheskikh Soedinenii,1993,p. 1516 - 1525.
[2]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1990,vol. 39,p. 1340 - 1345.
    Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya,1990,p. 1483 - 1488.
[3]Chemistry of Heterocyclic Compounds,1993,vol. 29,p. 1308 - 1315.
    Khimiya Geterotsiklicheskikh Soedinenii,1993,p. 1516 - 1525.

4
[ 110-85-0 ]
[ 288-32-4 ]
[ 290-37-9 ]
[ 616-47-7 ]
[ 109-08-0 ]
[ 13925-00-3 ]
[ 693-98-1 ]

References: [1]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1990,vol. 39,p. 1340 - 1345.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya,1990,p. 1483 - 1488.

5
[ 13925-00-3 ]
[ 100-52-7 ]
[ 109243-30-3 ]
[ 109243-29-0 ]

References: [1]Journal of Organic Chemistry,1987,vol. 52,p. 3971 - 3974.

6
[ 13925-00-3 ]
2-(1'-bromoethyl)pyrazine [ No CAS ]

References: [1]Agricultural and Biological Chemistry,1983,vol. 47,p. 729 - 738.

7
[ 123-84-2 ]
[ 109-08-0 ]
[ 13925-00-3 ]

References: [1]Chemistry of Heterocyclic Compounds,1993,vol. 29,p. 1308 - 1315.
Khimiya Geterotsiklicheskikh Soedinenii,1993,p. 1516 - 1525.

8
[ 123-84-2 ]
[ 290-37-9 ]
[ 109-08-0 ]
[ 123-32-0 ]
[ 13925-00-3 ]
[ 693-98-1 ]
[ 15707-23-0 ]

References: [1]Chemistry of Heterocyclic Compounds,1993,vol. 29,p. 1308 - 1315.
Khimiya Geterotsiklicheskikh Soedinenii,1993,p. 1516 - 1525.

9
[ 107-15-3 ]
[ 290-37-9 ]
[ 109-08-0 ]
[ 13925-00-3 ]

References: [1]Chemistry of Heterocyclic Compounds,1993,vol. 29,p. 1308 - 1315.
Khimiya Geterotsiklicheskikh Soedinenii,1993,p. 1516 - 1525.
[2]Chemistry of Heterocyclic Compounds,1993,vol. 29,p. 1308 - 1315.
Khimiya Geterotsiklicheskikh Soedinenii,1993,p. 1516 - 1525.

10
[ 56-45-1 ]
[ 290-37-9 ]
[ 109-08-0 ]
[ 13925-00-3 ]
[ 13925-03-6 ]

References: [1]Journal of Agricultural and Food Chemistry,1999,vol. 47,p. 4332 - 4335.

Yield	Reaction Conditions	Operation in experiment
		EXAMPLE 3 With the same catalyst and reaction conditions as those of Example 1, 15.8 grams of ethylpyrazine were obtained by the feeding of 20 grams of N-(2-butylhydroxy)ethylenediamine for 1 hour. Gas chromatographic analysis gave ca. 100percent conversion and 96.4percent selectivity on ethylpyrazine.
		...ethylthiazoline, 2-isobutyl-4,5-dimethyl-3-thiazoline, 4-methylthiazole, 2-methylthiazole, 2-acetyl-2-thiazole, 2,4,5-trimethylthiazole, 2,4-dimethyl-5-ethylthiazole, 5-hydroxyethyl-4-methylthiazole, 1,3-benzothiazole, 1,3-thiazolidine, 2-methyl-1,3- thiazolidine, 2-isopropyl-1,3-thiazolidine,2-methylpyrazine, 2-ethylpyrazine, 2-propylpyrazine, 2-isopropylpyrazine, 2-methoxypyrazine, 2,3-dimethylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, 2,3,5,6-tetramethylpyrazine, 2-methyl-3-ethylpyrazine 2-ethyl-3,5-dimethylpyrazine, 2-ethyl-3,6-dimethylpyrazine, 3-ethyl-2,5-dimethylpyrazine, 2,3-diethyl-5-methylpyrazine, 3-isobutyl-2-methoxypyrazine, 3-isopropyl-2-methoxypyrazine, 2-acetylpyrazine, 2-acetyl-3-methylpyrazine, 5-acetyl-2-methylpyrazine, 6-acetyl-2-ethylpyrazine,2-methylpropanal, 2-methybutanal, 3-methylbutanal, 4-pentenal, (E)-2-nonenal, hexanal, (E)-2-hexenal, 2,4-hexadienal, heptanal, 4-heptenal, octanal, (E)-2-octenal, octadienal, nonanal, (E,E)-2,4-nonadienal, (2E,6Z)-nonadienal, (E,E)-2,4-decadienal, (E,Z)-2,4-decadienal, (E)-2-undecenal, 12-methyl-tridecanal,3-methyl-1-butanol, 1-pentanol, 1-penten-3-ol, 3-cis-hexenol, 3-methyl-2-hexen-1-ol, 1-heptanol, 3-octanol, 1-octene-3-ol,3-hydroxy-2-butanone, 2-butanone, 2,3-butanedione, 2-pentanone, methyl isobutyl ketone, 1-pentene-3-one, 2-hexanone, oct-1-en-3-one, 2,3-octanedione, 2-nonanone, 2-decanone, 4-undecanone, 2-tridecanone, 3-methylcyclopentanone, 3-methylcyclopentenone, methyl cyclopentenolone, dimethyl cyclopentenolone, ethyl cyclopentenolone,gamma-hexalactone, gamma-octalactone, gamma-decalactone, gamma-dodecalactone, delta-nonalactone,butyric acid, isobutyric acid, isovaleric acid, pentanoic acid, hexanoic acid, isocaproic acid, heptanoic acid,
		...line, 2-isobutyl-4,5-dimethyl-3-thiazoline, 4-methylthiazole, 2-methylthiazole, 2-acetyl-2-thiazole, 2,4,5-trimethylthiazole, 2,4-dimethyl-5-ethylthiazole, 5-hydroxyethyl-4-methylthiazole (sulfurol), 1,3-benzothiazole, 1,3-thiazolidine, 2-methyl-1,3- thiazolidine, 2-isopropyl-1,3-thiazolidine,2-methylpyrazine, 2-ethylpyrazine, 2-propylpyrazine, 2-isopropylpyrazine, 2-methoxypyrazine, 2,3-dimethylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, 2,3,5,6-tetramethylpyrazine, 2-methyl-3-ethylpyrazine 2-ethyl-3,5-dimethylpyrazine, 2-ethyl-3,6-dimethylpyrazine, 3-ethyl-2,5-dimethylpyrazine, 2,3-diethyl-5-methylpyrazine, 3-isobutyl-2-methoxypyrazine, 3-isopropyl-2-methoxypyrazine, 2-acetylpyrazine, 2-acetyl-3-methylpyrazine, 5-acetyl-2-methylpyrazine, 6-acetyl-2-ethylpyrazine,2-methylpropanal, 2-methybutanal, 3-methylbutanal, 4-pentenal, (E)-2-nonenal, hexanal, (E)-2-hexenal, 2,4-hexadienal, heptanal, 4-heptenal, octanal, (E)-2-octenal, octadienal, nonanal, (E,E)-2,4-nonadienal, (2E,6Z)-nonadienal, (E,E)-2,4-decadienal, (E,Z)-2,4-decadienal, (E)-2-undecenal, 12-methyl-tridecanal,3-methyl-1-butanol, 1-pentanol, 1-penten-3-ol, 3-cis-hexenol, 3-methyl-2-hexen-1-ol, 1-heptanol, 3-octanol, 1-octene-3-ol,3-hydroxy-2-butanone (acetoin), 2-butanone, 2,3-butanedione (diacetyl), 2-pentanone, methyl isobutyl ketone, 1-pentene-3-one, 2-hexanone, oct-1-en-3-one, 2,3-octanedione, 2-nonanone, 2-decanone, 4-undecanone, 2-tridecanone, 3-methylcyclopentanone, 3-methylcyclopentenone, methyl cyclopentenolone (3-methyl-1,2-cyclopentanedione), dimethyl cyclopentenolone (3,4-dimethyl-1,2-cyclopentanedione, 3,5-dimethyl-1,2-cyclopentanedione), ethyl cyclopentenolone (3-ethyl-1,2-cyclopentanedione),gamma-hexalactone, gamma-octalactone, gamma-decalactone, gamma-dodecalactone, delta-nonalactone,butyric acid, isobutyric acid, isovaleric acid, pentanoic acid, hexanoic acid, isocaproic acid, heptanoic acid,

...line, 2-isobutyl-4,5-dimethyl-3-thiazoline, 4-methylthiazole, 2-methylthiazole, 2-acetyl-2-thiazole, 2,4,5-trimethylthiazole, 2,4-dimethyl-5-ethylthiazole, 5-hydroxyethyl-4-methylthiazole (sulfurol), 1,3-benzothiazole, 1,3-thiazolidine, 2-methyl-1,3- thiazolidine, 2-isopropyl-1,3-thiazolidine,2-methylpyrazine, 2-ethylpyrazine, 2-propylpyrazine, 2-isopropylpyrazine, 2-methoxypyrazine, 2,3-dimethylpyrazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,3,5-trimethylpyrazine, ...

13
[ 623-03-0 ]
[ 13925-00-3 ]
6-(4-chlorophenyl)-7-methyl-[5H]pyrrolo[2,3-b]pyrazine [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2003,vol. 46,p. 222 - 236.

14
[ 13925-00-3 ]
[ 2024-83-1 ]
6-(3,4-methoxyphenyl)-7-methyl-[5H]pyrrolo[2,3-b]pyrazine [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2003,vol. 46,p. 222 - 236.

15
[ 13925-00-3 ]
[ 874-90-8 ]
6-(4-methoxyphenyl)-7-methyl[5H]pyrrolo[2,3-b]-pyrazine [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2003,vol. 46,p. 222 - 236.

16
[ 13925-00-3 ]
2-(4-chlorophenyl)cyclopropane-1-carbonitrile [ No CAS ]
6-[1-(4-chloro-phenyl)-cyclopropyl]-7-methyl-5<i>H</i>-pyrrolo[2,3-<i>b</i>]pyrazine [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2003,vol. 46,p. 222 - 236.

17
[ 13925-00-3 ]
4-cyanophenyl dimethylsulfamate [ No CAS ]
6-(4-dimethylaminosulfamoyloxyphenyl)-7-methyl-[5H]pyrrolo[2,3-b]pyrazine [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2003,vol. 46,p. 222 - 236.

18
[ 13925-00-3 ]
[ 354-65-4 ]
1,1,2,2-tetrafluoro-1,2-diiodo-ethane; compound with 2-ethyl-pyrazine [ No CAS ]

References: [1]New Journal of Chemistry,2003,vol. 27,p. 1522 - 1527.

19
[ 13925-00-3 ]
[ 98-96-4 ]

References: [1]Journal of Chemical Thermodynamics,2005,vol. 37,p. 49 - 53.

20
[ 13925-00-3 ]
[ 6164-79-0 ]

References: [1]Journal of Chemical Thermodynamics,2005,vol. 37,p. 49 - 53.

21
[ 13925-00-3 ]
6-(4-hydroxyphenyl)-7-methyl[5H]pyrrolo[2,3-b]pyrazine hydrobromide [ No CAS ]

References: [1]Journal of Medicinal Chemistry,2003,vol. 46,p. 222 - 236.

22
[ 13925-00-3 ]
2-(1'-ethoxyethyl)pyrazine [ No CAS ]

References: [1]Agricultural and Biological Chemistry,1983,vol. 47,p. 729 - 738.

23
[ 13925-00-3 ]
16,17,18,19,28,29-hexahydro-4-O-acetyl-11-acetoxy-3-[2-ethyl-4-(2,4,6-trimethylbenzyl)-piperazin-1-yl]-8-O-pivaloyl-1-deoxy-11,15-dideoxo-1,15-oxy-rifamycin [ No CAS ]
[ 13961-37-0 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; acetic acid; In ethanol; dichloromethane;	EXAMPLE 41 In the same manner as outlined in Examples 15 and 20, 3-[2-ethyl-4-(2,4,6-tri-methylbenzyl)-piperazin-1-yl]-8-O-pivaloyl-1-deoxy-15-deoxo-1,15-oxy-rifamycin SV, (isomer A), mp 125°-128°, is converted to 16,17,18,19,28,29-hexahydro-4-O-acetyl-11-acetoxy-3-[2-ethyl-4-(2,4,6-trimethylbenzyl)-piperazin-1-yl]-8-O-pivaloyl-1-deoxy-11,15-dideoxo-1,15-oxy-rifamycin SV, mp 152°-155°, MW: 1100 (found: MS); C62 H89 N3 O14. The starting material can be prepared, for example, in the following way: A mixture of <strong>[13925-00-3]2-<strong>[13925-00-3]ethylpyrazine</strong></strong> (15 g), platinum oxide (800 mg), ethanol (150 ml) and acetic acid (1.5 g) is hydrogenated at 45 psi for 8 hours at room temperature. It is filtered and the filtrate concentrated to an oil which is taken up in methylene chloride, treated with sodium carbonate for 0.5 hour, filtered and concentrated to dryness to white solid 2-ethylpiperazine, mp 56°-57°.

References: [1]Patent: US5180718,1993,A .

24
[ 13925-00-3 ]
[ 1126-46-1 ]
[ 83227-47-8 ]

Yield	Reaction Conditions	Operation in experiment
		from <strong>[13925-00-3]2-<strong>[13925-00-3]ethylpyrazine</strong></strong> and methyl 4-chlorobenzoate there is obtained 4'-chloro-2-(2-pyrazinyl)-propiophenone, m.p. 85°;

References: [1]Patent: US4605656,1986,A .

25
[ 13925-00-3 ]
[ 35112-28-8 ]
[ 83227-48-9 ]

Yield	Reaction Conditions	Operation in experiment
		from <strong>[13925-00-3]2-<strong>[13925-00-3]ethylpyrazine</strong></strong> and methyl 2,4-dichlorobenzoate there is obtained 2',4'-dichloro-2-(2-pyrazinyl)-propiophenone as an oil.

References: [1]Patent: US4605656,1986,A .

26
[ 13925-00-3 ]
[ 94777-52-3 ]

Yield	Reaction Conditions	Operation in experiment
	With N-Bromosuccinimide; potassium carbonate; dibenzoyl peroxide; In tetrachloromethane;	EXAMPLE 1 2-(1-Hydroxyethyl)pyrazine (100) 21.6 g of <strong>[13925-00-3]2-<strong>[13925-00-3]ethylpyrazine</strong></strong> (101) was dissolved in 300 ml of carbon tetrachloride and 35.6 g of N-bromosuccinimide added; J. Org. Chem., 37, 511(1972). The mixture was heated to 75° C. and 1.5 g of dibenzoyl peroxide was added in one portion. Heating was continued for 4 hours after which the mixture was cooled and filtered into 500 ml of a 10percent potassium carbonate solution. This mixture was rapidly stirred until no 2-(1-bromoethyl)pyrazine remained (TLC silica gel/1:1 ethyl aqueous solution was acidified to pH 6, concentrated to 200 ml and continuously extracted with ethyl acetate for two days. The ethyl acetate was removed at reduced pressure and the residue distilled, giving 18.6 g of product (100). b.p. 112°-3° (13 mm). UV H2 O max: 264 (3.85), 268 (3.82). 13 C NMR: 159.75, S(C2); 144.52, D, 143.99, D, 142.51, D (C3, C5, C6); 69.20, D (CHOH); 23.11, Q (CH3).

References: [1]Patent: US4638005,1987,A .

27
[ 13925-00-3 ]
2-(1-sulfonylethyl)pyrazine sodium salt [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With N-Bromosuccinimide; sodium sulfite; dibenzoyl peroxide; In methanol; tetrachloromethane; water;	EXAMPLE 23 2-(1-Sulfonylethyl)pyrazine sodium salt (2300) 5.4 g of <strong>[13925-00-3]2-<strong>[13925-00-3]ethylpyrazine</strong></strong> was dissolved in 100 ml of carbon tetrachloride and 8.9 g of N-bromosuccinimide added. This mixture was heated to 70°-5° C., 0.5 g dibenzoyl peroxide added and the mixture refluxed for 3 hours. It was then cooled, filtered and the filtrate concentrated in vacuo. To the resultant oil was added 10 g of sodium sulfite/100ml of water and the mixture refluxed for 3 days. It was then cooled, washed with chloroform and freeze-dried. The resultant solid was taken up in 200 ml of methanol, filtered and the filtrate concentrated. It was purified by gel permeation chromatography (Biogel P-2/water) and freeze-dried to give 9.2 g product (2300). It was recrystallized from methanol, m.p. 258°-62°. UV H2 O max: 203 (3.90), 267 (3.87), 272 (3.85). 13 C NMR: 153.54, S (C2); 145.76, D, 144.97, D, 144.14, D (C3, C5, C6); 61.14, D (--CH--); 15.18, Q (CH3).

References: [1]Patent: US4638005,1987,A .

28
[ 13925-00-3 ]
[ 132-16-1 ]
[ 86502-89-8 ]

References: [1]Chemische Berichte,1983,vol. 116,p. 2088 - 2108.

29
[ 13925-00-3 ]
[ 27636-56-2 ]
[ 99547-54-3 ]

References: [1]Inorganic Chemistry,1986,vol. 25,p. 103 - 107.

30
[ 13925-00-3 ]
silver hexafluoroantimonate [ No CAS ]
[ 321699-42-7 ]
[Ag₂(2-ethpyz)3][SbF₆]2 [ No CAS ]

References: [1]Journal of the Chemical Society, Dalton Transactions,2000,p. 3821 - 3827.

31
[ 13925-00-3 ]
potassium cyanide [ No CAS ]
copper(l) cyanide [ No CAS ]
Cu₂(cyanide)2(ethylpyrazine) [ No CAS ]

References: [1]Journal of the Chemical Society, Dalton Transactions,2001,p. 2567 - 2580.

32
[ 13925-00-3 ]
[ 7787-70-4 ]
[Cu3Br3(μ2-2-ethylpyrazine-N,N')2] [ No CAS ]

References: [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2002,vol. 57,p. 1133 - 1140.

33
[ 13925-00-3 ]
[ 7787-70-4 ]
[Cu2Br2(μ2-2-ethylpyrazine-N,N')] [ No CAS ]

References: [1]Zeitschrift fur Naturforschung, B: Chemical Sciences,2002,vol. 57,p. 1133 - 1140.

34
[ 13925-00-3 ]
copper(l) chloride [ No CAS ]
catena[Cu3Cl3(μ2-2-ethylpyrazine-N,N')2] [ No CAS ]

References: [1]Journal of Solid State Chemistry,2002,vol. 169,p. 103 - 112.
[2]Zeitschrift fur Anorganische und Allgemeine Chemie,.
Zeitschrift fuer Anorganische und Allgemeine Chemie,2002,vol. 628,p. 2228 - 2228.

35
[ 13925-00-3 ]
copper(l) chloride [ No CAS ]
catena[Cu3Cl3(μ2-2-ethylpyrazine-N,N')2] [ No CAS ]
poly[Cu2Cl2(μ2-2-ethylpyrazine-N,N')] [ No CAS ]

References: [1]Journal of Solid State Chemistry,2002,vol. 169,p. 103 - 112.

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P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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CAS No.: 13925-00-3

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CAS No.: 13925-00-3

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[ 13925-00-3 ] Synthesis Path-Downstream 1~35

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